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Selectivity of C-H activation and competition between C-H and C-F bond activation at fluorocarbons

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Figure

Table 1 Experimental bond dissociation enthalpy (kJ/mol) in gas phase
Figure 1. Plots of the best fit to the trends in DFT(BP86) calculated C-F (left) and C-H (right) bond
Figure 2.  pKa values of fluorinated benzenes. Experimental (red) for cyclohexylamine CyNH2
Figure 3. Calculated hydride and fluoride affinities (kcal/mol) of a series of carbenium and silylium
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