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Reactions of Oxygen Containing Ligands in the Coordination Sphere of Permethylhafnocene and Permethyltantalocene

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Figure

Figure 1 and depicts the pseudotetrahedral coordination or •bent sandwich" configuration
Table 1. 1 H NMR Chemical Shifts for the Hydride Resonance of Cp*2Hf(X)H.
Figure 3. ~H* a) Kinetics at 60°C for the transformation of Cp*2Hf(CH2CHa)(OOCMe3) to Cp*2Hf(OCH2CH3)(0CMe3); ln[C] vs
Figure 3 shows a typical example of a kinetics run for Cp*2Hf{CH2CH3)(00CMe3}. The
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