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Picosecond time-resolved infrared spectroscopy of rhodium and iridium azides

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Figure

Figure 1. UV/vis absorption spectra of complex 1.
Figure 2. TRIR difference spectra (2 ps – 800 ps) of Rh(Cp*)(N3)2(PPh3) (1) in CH3CN, exc = 400 nm (top); bleached parent bands (a), transient bands (b) and hot bands (c); FTIR spectrum (bottom panel)
Table 1. Band positions of ground state bleaches and transient absorptions obtained from fits of the TRIR spectra usingLifetimes of vibrational relaxation ( pseudo Voigt profiles (see Fig
Figure 5. Normalised kinetic traces at 1953 cm1 (black), 1985 and 2014 cm1 (red) and 2038 cm1 (blue) of Ir(Cp*)(N3)2(PPh3) (2) in CH3CN, exc = 400 nm; TRIR spectra shown in Fig
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