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Reactivity and structural studies of metal complexes bound to DNA

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Figure

Figure 1.1. have the identical flanking sequence 5'-AXT-3'.  Sixteen combinations of the base pairs and mispairs are possible, and all the corresponding assemblies were constructed
Table 1.1. [Ru(bpy')(dppz)(phen)]Containing Intervening Mismatch (XY) with the Appended The Distal/Proximal Guanine Oxidation Dataa for Duplexes Shown below ∆-Isomer of 2+
Table 1.2. Measurement of the Imino Proton Exchange at the Mismatch Site (XMelting Temperatures (Tm) and the Base-Pair Lifetimes (τex) Based on 5) and Its Flanking Bases of the Duplexes Containing Single Intervening Mismatch
Figure 1.5. Correlation plot of the free energies of helix destabilization at 37 °C and the distal/proximal ratios of long-range guanine oxidation in duplexes containing intervening mismatch
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