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Order-disorder morphologies in rapidly solidified ε/ε′-Ni₅Ge₃ intermetallic

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Figure

Figure 1: X-Ray diffraction analysis of rapidly solidified drop-tube processed samples,  850 m size(black), 850 -500 m size range (red) and 150 -106 m size range (blue) respectively
Figure 2(a) shows an SEM micrograph of a polished and HF etched sample in a powder from the500 - 300surrounded by � segregates
Figure 3: (a) TEM bright field image of a plate & lath structure and surrounding matrix material in a 500 –300 µm size fraction, (b and c) selected area diffraction patterns from regions (i) with zone axis [2, 1, 2] and(ii) with zone axis [0, 0, 1] identified in the bright field image (i) matrix materials well away from the plate& lath structure, (ii) inside the structure.
Figure 4: (a) DSC trace from a Nicycle indicated by green & blue respectively, two vertical black line shows the transition temperature at 320to 4605Ge3 drop-tube particle from the 150 – 106 µm size fraction, 1st & 2nd °C and (b) TEM (In-situ) SAD pattern taken from Figure 2(b) at room temperature (ordered) and (c)SAD of the same area but at 485 °C (disordered).

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