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A study of the relationship between water and anions of the Hofmeister series using pressure perturbation calorimetry

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Figure

Fig. 1(a–c) Show the raw data from a pressure perturbation scan of 1000 mM disodium hydrogen phosphate, sodium chloride and sodium thiocyanatein pure water at pH 7 respectively
Fig. 2(a) Heat changes for pressure increase (1 to 5 bar) from 7–92 1C for (a) 100 mM and (b) 1000 mM disodium hydrogen phosphate (), disodiumsulphate (), sodium fluoride (), sodium chloride (), sodium bromide (), sodium iodide (), sodium thiocyanate (–) a
Fig. 6Experimental values for the DQ for 100 mM NaCl fitted againstvalues for DQ calculated using eqn (10) using the assumptions that n is 13.3and the molar expansivity of the hydration layer is 0.55 that of pure water.

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