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Fundamental mechanisms and biological applications of DNA mediated charge transport

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Figure

Figure 1.1. The structure of the DNA double helix (top). The polyanionic sugar phosphate backbone is indicated in black, while the inner core of stacked aromatic bases is delineated in grey
Figure 1.2.charge transport. Superexchange occurs when the donor and acceptor are lower in energy
Figure 1.3. Probes used to monitor charge transport through DNA. [Rh(phi)(2(bpy’)]3+ A), [Ru(phen)(dppz)(bpy’)]2+ (B), a modified anthraquinone (C), 2-aminopurine (D), 1-N6-ethenoadenine (E), deazaguanine (F), N2-cyclopropylguanine (G), naphthalene diimide
Figure 1.4. Crystal structure of intercalated effectively acting as an additional base pair with minimal perturbation to the overall Δ−α-[Rh[(R,R)Me2trien]phi]3+ in the major groove of 5'-G-dIU-TGCAAC-3'
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