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Ultrasonic exfoliation of hydrophobic and hydrophilic metal-organic frameworks to form nanosheets

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Figure

Figure 1. Structure of ligands H21 (a) and H22 (b). c) Paddlewheel SBU, with DMF coordinated in the axial positions
Figure 2. Cu(1)(DMF) and Cu(2)(DMF) are represented with blue and red data, respectively
Figure 3. Experimental powder diffraction patterns of Cu(1)(DMF) and Cu(2)(DMF) as-synthesised (dark blue), and of post-exfoliation solids recollected through centrifugation for 1 hr at 1500 rpm, in DMF, NMP, MeCN, diethyl ether and water
Figure 4. DFT calculations showing optimised structures for (a) Cu2(1**)4(DMF)2, (b) Cu2(1**)4(H2O)2, (c) Cu2(1**)4 where 1** is 2,5-Bis(3-
+3

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