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Synthesis and Characterisation of Fused-Heterocyclic Molecular Rods: A Combined Experimental and Theoretical Study on Diethynyl-Dithienothiophenyl Derivatives

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Figure

Fig. 1. Modification and application of alkyne substrates; [A] core, [B]  end-capping and [C] fine-tuning derivative units
Figure 2. Leading examples of heterocyclic �physical properties of compounds -extended molecular rods with ethylene spacer units and fused-ring thiophenyl cores
Figure 4.  Single crystal X-ray ORTEP plots with thermal ellipsoids at the 50 % level showing an inflection of curvature across 7 and a large out-of-plane bending distortion with 8
Figure 5. Single crystal packing of a pure DTT molecule and the compounds central and outer thiophene rings between the adjacent molecules; presented as single crystal X-ray ORTEP plots with thermal ellipsoids at the 50 % level
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