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Observation of a New Channel, the Production of CH3, in the Abstraction Reaction of OH Radicals with Acetaldehyde

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Figure

Figure 1. Overlaid plots of acetyl (�) and methyl (×) signal from the same experiment (1.5 Torr He, N2O/H2O as the OH source, [CH3CHO] = 4 × 1013 molecule cm-3) showing that they are produced on the same timescale
Figure 2. Methyl:acetyl signal ratios following the reaction of OH with acetaldehyde (AcH) and Cl with acetaldehyde
Figure 3. Behavior of acetyl, methyl and lactone signals in an OH/CH3CHO/O2 system. The solid points are the experimental data and the lines are a numerical simulation based on a kinetic model
Figure 4. Bimolecular plots of (a) OH + CH3CHO, (b) Cl + CH3CHO monitoring acetyl production
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