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Post-polymerisation modification of bio-derived unsaturated polyester resins via Michael additions of 1,3-dicarbonyls

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Academic year: 2019

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Figure

Fig. 1 Typical bio-derived diacids and used for unsaturated polyester synthesis. 1itaconic acid (IA); = maleic acid (via butane oxidation);  �2 = fumaric acid (FA); 3 = succinic acid (SA); 4 = cis,cis-muconic acid; 5 6 = adipic acid
Fig. 2 Previously reported post-polymerisation modifications of bio-derived UPEs
Fig. 5 Isomerisation to dimethyl mesaconate or dimethyl citraconate
Fig. 8 13carbons in keto- form, uppercase signals for diketone carbons in enol- form. ~150 mg cmC NMR spectrum of PBI-acac in CDCl3
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