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Insights into mechanism and selectivity in ruthenium(II)-catalysed ortho-arylation reactions directed by Lewis basic groups

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Figure

Figure 1. Ruthenium-catalysed C-H activation and selectivity.
Figure 3. Plot of experimental versus calculated values of κ.
Figure 4. Free energy surface for the arylation of 2-phenylpyridine with chlorobenzene, catalysed by [Ru(OAc)2(p-cymene)], in a mechanism where p-cymene remains bound to the metal centre throughout
Figure 5. Free energy surface for the arylation of 2-phenylpyridine with chlorobenzene, catalysed by [Ru(OAc)2(p-cymene)], in a mechanism where p-cymene is not bound to the metal centre
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