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X=Y–ZH compounds as potential 1,3-dipoles. Part 64: Synthesis of highly substituted conformationally restricted and spiro nitropyrrolidines via Ag(I) catalysed azomethine ylide cycloadditions

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Figure

Table 1: Silver salt/NEt3 catalysed cycloaddition of 6a-f  with  E - nitroolefins 7a-f.a
Figure 1 We extended our studies to spiro nitropyrrolidines employing metallo-azomethine ylide formation from
Table 2: Catalysed cycloaddition of imines 12a-c with E-nitrostyrene using AgOAc in MeCNa
Table 3: Catalysed cycloaddition of imines 12d-j with E-nitrostyrenes using Ag2O/NEt3 in toluenea
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