Using microanalysis of minerals to track geochemical processes during metamorphism: examples from the Mary Kathleen fold belt, Queensland, and the Eastern Mt. Lofty Ranges, South Australia
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(2) 1 2 3 4 5. A EPMA analyses Scapolite (Na,Ca,K)4[Al3(Al,Si)3Si6O24](Cl,CO3,SO4) sample no.. J. K. MKS9_11. L. M. N. O. P. Q. MKS9_4_norm MKS9_3_norm MKS9_1_dark MKS9_3_dark1MKS9_3_dark2MKS9_6_dark1MKS9_6_dark2. SiO2. 48.396. 48.565. 48.19. 48.275. 50.774. 48.62. 48.513. 48.449. 6 7 8 9 10 11. Al2O3. 25.835. 25.666. 25.491. 25.717. 25.29. 25.866. 25.861. 25.949. FeO CaO MnO MgO Na2O. 0.098 15.197 0.018 0.003 4.833. 0.16 15.301 0.012 0 4.916. 0.138 15.065 0.008 0 4.731. 0.256 15.237 0 0.023 4.699. 0.18 13.241 0.022 0.062 4.046. 0.166 15.012 0.013 0.121 4.552. 0.119 15.089 0.005 0.019 4.842. 0.147 15.132 0.036 0.016 4.757. 12 13 14 15. K2 O. 0.555. 0.579. 0.66. 0.619. 0.551. 0.67. 0.679. 0.667. Cl SO3. 0.853 1.932. 0.846 1.887. 0.856 1.911. 0.833 1.984. 0.695 1.521. 0.835 1.645. 0.929 1.708. 0.846 2.049. Total. 97.72. 97.932. 97.05. 97.643. 96.382. 97.5. 97.764. 98.048.
(3) 1 2 3 4 5. A EPMA analyses Scapolite (Na,Ca,K)4[Al3(Al,Si)3Si6O24](Cl,CO3,SO4) sample no.. R. S. T. V. MKS9_9_dark1MKS9_9_dark2MKS9_4_dark CFM8_Sca1. SiO2. 48.729. 48.595. 6 7 8 9 10 11. Al2O3. 25.736. FeO CaO MnO MgO Na2O. 0.125 15.373 0.032 0.017 4.854. 12 13 14 15. K2 O Cl SO3 Total. U. 48.657. 49.45. 25.627. 25.9. 0.087 15.115 0.015 0.006 4.675. 0.168 15.301 0.025 0.013 4.837. 0.601. 0.656. 0.849 2.103 98.419. W. CFM8_Sca2. X. CFM8_Sca4. Y. CFM8_Sca5. CFM8_Sca6. 48.381. 49.188. 48.865. 48.988. 25.428. 25.32. 25.547. 25.619. 25.31. 0.008 14.116 0.046 0 5.56. 0.044 14.633 0.011 0 5.374. 0.089 14.315 0.065 0 5.426. 0.086 14.868 0.03 0 5.245. 0.09 14.495 0.008 0 5.473. 0.56. 0.461. 0.367. 0.394. 0.351. 0.46. 0.846 1.905. 0.821 2.004. 1.111 0.414. 0.825 1.362. 0.942 0.969. 0.829 1.072. 1.078 0.423. 97.527. 98.286. 96.594. 96.317. 96.935. 96.965. 96.325.
(4) 1 2 3 4 5. A EPMA analyses Scapolite (Na,Ca,K)4[Al3(Al,Si)3Si6O24](Cl,CO3,SO4) sample no.. Z. AA. CFM8_Sca7. SiO2. 49.397. 6 7 8 9 10 11. Al2O3 FeO CaO MnO MgO Na2O. 12 13 14 15. CFM8_Sca8. AB. AC. CFM8_Sca9. CFM8_Sca10. 48.462. 48.851. 50.153. 25.552. 25.59. 25.583. 0.055 14.542 0.062 0 5.409. 0.049 14.867 0.073 0 5.152. 0.09 14.872 0.048 0.012 5.174. K2 O. 0.357. 0.392. Cl SO3. 0.984 0.798 97.156. Total. AD. CFM8_Sca11. AE. CFM8_Sca12. AF. CFM8_Sca13. AG. CFM8_Sca14. 49.36. 48.98. 48.996. 49.602. 25.309. 25.55. 25.255. 25.512. 25.25. 0.07 13.563 0.062 0 6.079. 0.028 14.671 0.045 0 5.44. 0.038 14.83 0.037 0 5.177. 0.022 14.144 0.022 0 5.446. 0.059 14.463 0.04 0 5.496. 0.37. 0.502. 0.366. 0.364. 0.389. 0.386. 0.85 0.869. 0.839 0.96. 1.298 0.036. 0.867 1.211. 0.808 1.379. 1.004 0.707. 0.984 0.923. 96.304. 96.799. 97.072. 97.538. 96.868. 96.242. 97.203.
(5) 1 2 3 4 5. A EPMA analyses Scapolite (Na,Ca,K)4[Al3(Al,Si)3Si6O24](Cl,CO3,SO4) sample no.. AH. CFM8_Sca15. AI. AJ. AK. AM. MKS8_bright1 MKS8_bright2 MKS8_bright3 MKS8_bright4 MKS8_dark1. SiO2. 48.806. 57.994. 58.27. 56.507. 6 7 8 9 10 11. Al2O3. 25.161. 22.312. 22.344. FeO CaO MnO MgO Na2O. 0.062 15.123 0.045 0 5.173. 0.057 5.559 0 0 10.237. 0.081 5.353 0.042 0 10.179. 12 13 14 15. K2 O. 0.367. 1.02. Cl SO3. 0.798 1.141 96.676. Total. AL. AN. MKS8_dark2. AO. MKS8_dark4. 55.918. 56.434. 53.161. 52.048. 23.354. 23.4. 22.562. 23.924. 24.25. 0.013 6.064 0 0 9.448. 0.005 7.068 0.008 0 9.506. 0.065 7.016 0.004 0 9.453. 0.022 9.705 0 0 8.261. 0.041 10.725 0 0 7.492. 1.247. 0.854. 0.917. 1.095. 0.774. 0.555. 3.431 0.157. 3.632 0.22. 3.048 0.055. 3.304 0.047. 3.304 0.335. 2.564 0.875. 2.189 1.667. 100.767. 101.368. 99.343. 100.173. 100.268. 99.286. 98.967.
(6) 1 2 3 4 5. A EPMA analyses Scapolite (Na,Ca,K)4[Al3(Al,Si)3Si6O24](Cl,CO3,SO4) sample no.. AP. AQ. MKS8_dark5. SiO2. 53.243. 6 7 8 9 10 11. Al2O3 FeO CaO MnO MgO Na2O. 12 13 14 15. AR. AS. AT. AU. AV. AW. MKS8_normal1MKS8_normal2MKS8_normal3MKS8_normal4MKS8_normal5MKS8_normal6MKS8_normal7 58.952. 58.566. 56.809. 57.4. 57.937. 57.137. 24.131. 21.96. 22.341. 22.564. 22.086. 21.891. 22.336. 22.2. 0.025 9.803 0.005 0 8.267. 0.079 5.121 0.002 0 10.512. 0.152 5.19 0.039 0 10.403. 0.068 6.525 0 0 9.837. 0.025 6.039 0 0 10.128. 0.022 5.606 0.004 0 10.138. 0.095 6.045 0.013 0 9.678. 0.041 5.304 0.021 0 10.493. K2 O. 0.59. 1.231. 1.123. 1.098. 1.128. 1.243. 0.954. 1.31. Cl SO3. 2.505 1.059. 3.733 0.146. 3.678 0.16. 3.436 0.169. 3.493 0.253. 3.621 0.197. 3.43 0.389. 3.678 0.163. 99.628. 101.736. 101.652. 100.506. 100.552. 100.659. 100.077. 101.76. Total. 58.55.
(7) 1 2 3 4 5. A EPMA analyses Scapolite (Na,Ca,K)4[Al3(Al,Si)3Si6O24](Cl,CO3,SO4) sample no. SiO2. AX. AY. MKE021 Core. AZ. MKE021 Zone 1 55.47. MKE021 Zone 2 54.82. MKE021 6_2d1. BB MKE021 6_2d2. BC MKE021 6_2d3. MKE021 6_2d4. MKE021 6_3a_1. 22.6. 22.99. 22.69. 22.69. 22.03. 22.45. 22.44. 0.1023 8.87. 0.0677 8.38. 9.39. 0.052 8.98 0 0 8.69. 0.1269 8.66 0 0.0732 8.88. 0.1122 7.99 0 0 9.5. 0.0571 7.95 0.0206 0 9.33. 0.0469 8.39 0.0187 0 9.14. 0.7387. 0.8323. 0.5457. 0.5521. 0.6508. 0.736. 0.6412. 2.9 0.1042. 2.58 0.8065. 2.89 0.1038. 2.48 0.4016. 2.61 0.2915. 2.75 0.3374. 2.85 0.3299. 2.68 0.3948. 99.3355. 99.5875. 100.3538. 98.0593. 98.6037. 98.1904. 99.2036. 98.9416. 22.68. FeO CaO MnO MgO Na2O. 0.0226 8.19. 9.14. 9.07. 12 13 14 15. K2 O. 0.8287. Cl SO3. 54.82. BE. 54.22. 6 7 8 9 10 11. 54.72. BD. 55.7. Al2O3. Total. BA. 55.48. 55.19.
(8) 1 2 3 4 5. A EPMA analyses Scapolite (Na,Ca,K)4[Al3(Al,Si)3Si6O24](Cl,CO3,SO4) sample no. SiO2. BF MKE021 6_3a_2. BG. BH. MKE021 6_3a_3 52.63. MKE021 6_6_1 55.7. 55.73. BI. BJ. MKE021 6_6_2. MKE021 6_4_1 55.08. BL. MKE021 6_4_2 54.89. MKE021 6_4_3. MKE021 6_8_1 54.32. 22.97. 22.65. 22.96. 0.0883 8.19 0 0 9.15. 0.0486 8.05 0 0 9.32. 0.104 8.7 0 0 8.93. 0.6453. 0.5741. 0.5966. 2.38 0.7387. 2.72 0.3399. 2.67 0.3814. 2.52 0.3804. 100.4633. 100.5035. 98.8241. 98.511. 6 7 8 9 10 11. 23.49. 22.61. 22.08. 22.55. 23.76. FeO CaO MnO MgO Na2O. 0.0191 10.82 0 0 7.82. 0.0312 8.03 0 0 9.3. 0.0485 7.93 0.0107 0 9.63. 0.0607 8.17 0.0382 0 9.3. 0.0642 9.72 0 0 8.56. 12 13 14 15. K2 O. 0.4293. 0.7558. 0.6651. 0.6849. 0.3504. Cl SO3. 1.97 1.228. 2.79 0.3185. 2.83 0.2725. 2.75 0.3694. 98.4064. 99.5355. 99.1968. 99.0032. 56.4. BM. 55.13. Al2O3. Total. BK.
(9) 1 2 3 4 5. A EPMA analyses Scapolite (Na,Ca,K)4[Al3(Al,Si)3Si6O24](Cl,CO3,SO4) sample no. SiO2. BN MKE021 6_8_2. BO. BP. MKE021 6b_3_4 54.77. MKE021 6b_3_3 55.7. BQ. BR. MKE021 6b_3_2 55.47. BS. MKE021 6b_3_1 55.84. MKE021 6b_3_5 54.82. BT MKE021 6b_6_1. 55.51. BU. MKS3_Sc1 56.53. 55.51. 6 7 8 9 10 11. Al2O3. 23.56. 22.99. 22.68. 23.1. 22.6. 22.85. 22.93. 22.66. FeO CaO MnO MgO Na2O. 0.0418 9.8 0.0312 0.167 8.24. 0.0677 8.38 0 0 9.39. 0.0226 8.19 0.0061 0 9.14. 0.0607 8.7 0 0 9.18. 0.1023 8.87 0.0109 0 9.07. 0.1063 8.7 0 0 9.33. 0.0906 8.02 0 0 9.44. 0.0691 6.92. 12 13 14 15. K2 O. 0.4448. 0.8323. 0.8287. 0.6507. 0.7387. 0.7714. 0.8445. 0.9956. Cl SO3. 2.2 0.9702. 2.78 0.1038. 2.8 0.1042. 2.54 0.8059. 2.9 0.8065. 2.65 0.8023. 2.98 0.1618. 3.79 0.0209. 100.225. 100.2438. 99.2416. 100.8773. 99.9184. 100.72. 100.9969. 99.7556. Total. 0 9.79.
(10) 1 2 3 4 5. A EPMA analyses Scapolite (Na,Ca,K)4[Al3(Al,Si)3Si6O24](Cl,CO3,SO4) sample no. SiO2. BV. BW. MKS3_Sc2 55.4. MKS3_Sc3 55.68. BY. MKS3_Sc4. MKS3_Sc5. CA. MKS3_Sc6. CB. MKS3_Sc7. MKS3_Sc8. 22.29. 22.6. 22.37. 22.63. 22.5. 23.38. 0.0531 6.54. 0.037 6.11. 0.0516 6.5. 0.0676 6.47. 0.0612 7.63. 0 8.71. 0 9.93. 0 10.71. 0 10.1. 0 10.23. 0 9.49. 1.181. 0.7981. 1.1306. 0.8662. 0.964. 1.1922. 1.0173. 3.75 0.0364. 3.94 0.0024. 3 0.0088. 3.82 0.0107. 3.82 0.0141. 3.9 0.0214. 3.91 0.0175. 3.58 0.0287. 99.7285. 100.0565. 96.9518. 100.1544. 100.8273. 100.337. 100.6073. 100.3072. 22.54. 0.0386 6.9. 0.0531 6.37. 0 9.77. 0 10.29. 12 13 14 15. K2 O. 1.0635. Cl SO3. 56.22. MKS3_Sc9. 0.0549 5.53. 22.77. FeO CaO MnO MgO Na2O. 56.17. CC. 56.9. 6 7 8 9 10 11. 56.56. BZ. 56.07. Al2O3. Total. BX. 55.12.
(11) 1 2 3 4 5. A EPMA analyses Scapolite (Na,Ca,K)4[Al3(Al,Si)3Si6O24](Cl,CO3,SO4) sample no. SiO2. CD. CE. MKS3_Sc10. CF. MKS3_Sc11. CG. MKS3_Sca12. CI. CJ. CK. MKS1A_Sca1 MKS1A_Sca2 MKS1A_Sca3 MKS1A_Sca4 MKS1A_Sca5. 54.99. 55.06. 6 7 8 9 10 11. Al2O3. 23.51. 23.43. 22.4. 22.44. 22.33. 22.27. 22.32. 22.45. FeO CaO MnO MgO Na2O. 0.0386 7.47. 0.071 7.67. 0.1036 6.14. 0.1233 6.56. 0.1152 6.39. 0.1136 6.23. 0.1136 6.11. 0.0731 6.39. 0 9.72. 0 9.69. 0 10.27. 0 10.39. 0 10.19. 0 10.5. 0 10.57. 0 10.34. 12 13 14 15. K2 O. 0.9538. 1.0011. 1.21. 0.9582. 1.0699. 1.1069. 0.9479. 0.9732. Cl SO3. 3.66 0.0165. 3.66 0.0252. 3.98 0.0063. 3.77 0. 3.87 0. 3.9 0. 3.94 0. 3.84 0.0122. 100.3589. 100.6073. 100.8599. 100.7615. 100.5651. 100.8605. 101.0815. 100.3585. Total. 56.75. CH. 56.52. 56.6. 56.74. 57.08. 56.28.
(12) 1 2 3 4 5. A EPMA analyses Scapolite (Na,Ca,K)4[Al3(Al,Si)3Si6O24](Cl,CO3,SO4) sample no. SiO2. CL. CM. CN. MKS1A_Sca6 MKS1A_Sca7 CFM2_3. CO. CP. CFM2_3_middlCFM2_3_3. CQ. CR. CS. CFM2_4_dark1CFM2_4_dark2CFM2_5_dark. 56.52. 56.91. 50.234. 50.043. 49.673. 49.999. 49.533. 49.414. 6 7 8 9 10 11. Al2O3. 22.55. 22.42. 25.725. 25.964. 25.949. 25.671. 25.948. 26.095. FeO CaO MnO MgO Na2O. 0.1137 6.55. 0.078 6.29. 0 10.27. 0 10.35. 0.036 14.54 0.019 0 5.583. 0.049 14.58 0.008 0 5.587. 0.07 14.591 0.005 0.004 5.345. 0.073 14.583 0.023 0 5.374. 0.137 14.909 0.036 0 5.269. 0.074 15.11 0.035 0 5.152. 12 13 14 15. K2 O. 1.0498. 1.0475. 0.407. 0.43. 0.431. 0.478. 0.494. 0.487. Cl SO3. 3.8 0.0122. 3.88 0.0064. 1.108 0.354. 1.028 0.52. 0.94 0.876. 1.06 0.282. 0.927 1.12. 0.914 0.653. 100.8657. 100.9819. 98.006. 98.209. 97.884. 97.543. 98.373. 97.934. Total.
(13) 1 2 3 4 5. A EPMA analyses Scapolite (Na,Ca,K)4[Al3(Al,Si)3Si6O24](Cl,CO3,SO4) sample no.. CT. CU. CV. CW. CX. CY. CZ. DA. CFM2_4_brightCFM2_5_brightCFM2_random CFM2_random CFM2_random CFM2_random CFM2_random CFM2_random. SiO2. 50.019. 49.934. 49.675. 50.098. 49.738. 49.346. 50.239. 49.851. 6 7 8 9 10 11. Al2O3. 25.975. 25.966. 25.962. 25.715. 25.649. 25.898. 26.115. 25.886. FeO CaO MnO MgO Na2O. 0.052 14.747 0.027 0 5.49. 0.063 14.502 0.022 0 5.47. 0.047 14.976 0.026 0 5.298. 0.014 14.104 0 0 5.618. 0.095 14.678 0.041 0 5.183. 0.041 15.049 0.043 0 4.942. 0.017 14.595 0.022 0 5.646. 0.024 14.799 0 0 5.263. 12 13 14 15. K2 O. 0.496. 0.424. 0.428. 0.468. 0.488. 0.557. 0.471. 0.495. Cl SO3. 1.02 0.329. 1.072 0.343. 0.97 0.705. 1.068 0.561. 1.049 0.318. 0.959 0.522. 1.079 0.252. 1.044 0.248. 98.155. 97.796. 98.087. 97.646. 97.239. 97.357. 98.436. 97.61. Total.
(14) 1 2 3 4 5. A EPMA analyses Scapolite (Na,Ca,K)4[Al3(Al,Si)3Si6O24](Cl,CO3,SO4) sample no.. DB. BB1. DC. BB1. DD. BB1. DE. BB1. DF. BB1. SiO2. 55.803. 56.297. 56.214. 55.914. 6 7 8 9 10 11. Al2O3. 22.301. 22.272. 22.102. 22.125. 22.25. FeO CaO MnO MgO Na2O. 0.095 7.041 0.01 0 9.053. 0.112 6.938 0.006 0 9.107. 0.132 7.044 0.03 0 9.001. 0.116 7.026 0.008 0 9.023. 0.138 6.93 0.019 0 9.15. 12 13 14 15. K2 O. 1.627. 1.586. 1.546. 1.612. 1.528. Cl SO3. 3.084 0.761. 3.067 0.8. 3.088 0.7. 3.071 0.82. 3.06 0.89. 99.775. 100.185. 99.857. 99.715. 99.897. Total. 55.932.
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