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Week 9_Energy Changes in Reactions

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Energy in food

Energy is measured in joules.

One joule is the energy needed to lift a weight of one newton (N) one metre.

A small apple has a weight of about 1N. How many apples would you need to lift one metre to use up all the energy in this chocolate bar?

Energy (kJ) 1075 Energy (kcal) 255 Protein 3.7g

Carbohydrate 27.9g Fat 14.6g

Fibre 0.3g

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Energy in food

Energy in food is usually measured in calories. This comes from calor, the Latin word for heat.

1 calorie = 4.2 joules

1 kilocalorie (kcal) = 1000 calories

How many joules of energy does this cheeseburger contain?

Energy (kJ) ?

Energy (kcal) 295 Protein 16g

Carbohydrate 31g Fat 12g

Fibre 2g

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Calorimetry involves burning a known mass of food and

measuring the energy released.

Calorimetry

The energy content of food is measured using a technique called calorimetry.

Knowing the temperature change and the specific heat capacity of water, it is possible to calculate the energy released by the burning food.

This is done by transferring the energy to a measured volume of water and working out the

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Making and breaking chemical bonds

Most chemicals will break up (decompose) if they are

heated strongly enough. This means that energy is needed to break chemical bonds – an endothermic process.

energy absorbed

Because bond-breaking is endothermic, bond-making must therefore be exothermic. This means that energy is

released when chemical bonds are made.

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All reactions need a certain amount of energy to get started. This is called the activation energy (Ea).

Activation energy is needed to start breaking the bonds of the reactants. In most chemical reactions, some existing bonds need to be broken (an endothermic process) before new bonds can be made (an exothermic process).

What is activation energy?

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In some reactions, the bonds are easily broken and a low activation energy is needed; for example, the

reaction between sodium hydroxide and water starts at room temperature.

In other reactions, the bonds are strong and not easily broken.

These reactions have a high activation energy.

Do different reactions need different E

a

?

An example is the

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Bond energies

The energy changes in a reaction can be calculated from the bond energies of the reactants and the products.

The amount of energy needed to break or make a bond is called the bond energy.

Different chemical bonds have different bond energies. For example:

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H–H

Cl–Cl

H–Cl

bond bond

energy (kJ)

Bond energies are given per mole.

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en er g y (k J)

What are catalysts?

Catalysts are substances that change the rate of a reaction without being used up in the reaction.

Catalysts never produce more product – they just produce the same amount more quickly.

Different catalysts work in different ways, but most lower the reaction’s

activation energy (Ea).

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Catalysts in industry

Some industrial processes, like making paper, use biological catalysts called enzymes.

Why are catalysts so important for industry?

 Products can be made more quickly, saving time and money.

 Catalysts reduce the need for high temperatures, saving fuel and reducing pollution.

References

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