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Solubilised bright blue emitting iridium complexes for solution processed OLEDs

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Figure

Fig. 1Biimidazole complexes previously studied by our group.11b A green arrow connotes free rotation about the C–C bond, while the red arrowconnotes the opposite
Fig. 4X-ray crystal structures of complexes 1–3. Hydrogen atoms, solvent molecules and counterions have been removed for clarity.
Fig. 5X-ray packing of 3 crystal viewed along the plane of the N4N ligand (left) and from above the cyclometalating ligand N–Ir–N axes (right)
Fig. 7UV-vis absorption spectra of complexes 1–3 in MeCN solution. Inset: zoomed region of absorption spectra.
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