Lecture Hours. 16 hrs

(1)

Government of Karnataka Department of Collegiate Education

Government Science College(Autonomous), Hassan

UNITWISE LESSON PLAN FOR THE ACADEMIC YEAR 2020-21

Programe: M.Sc Chemistry

Course/Paper Name: Analytical Chemistry – I, Unit - I Semester: First Sem MSc

Name of the Faculty: Total Hours: 16

Sl.

No.

Topic Covered No. of

Lecture Hours

Methodology/

pedagogy

Date Initial

1. Fundamentals of Analytical Chemistry - 2hrs Black board/

Lecture PPT

Last week of Jan 2021

Sd/- 2. Language of analytical chemistry -.

Selecting an analytical method - Making the final choice

5 hrs Black board/

Lecture PPT

1^st, 2^nd week of February 2021

Sd/-

3. Propagation of errors:

Standardization and calibration:

Importance of sampling, Type of sample to collect- grab and composite samples.

2 hr Seminar 17-02-2021 Sd/-

4. Errors and treatment of analytical data: Limitations of analytical methods – Error:

Characterizing experimental error:

Statistical treatment of finite samples -, Comparison of an experimental mean and a true mean.

Criteria for the rejection of an observation - Q-test.

Figures of merit of analytical methods -

6 hrs Black board/

Lecture PPT

3^rd, 4^th week of February 2021 1^st Week of March 2021

Sd/-

5. Obtaining sample for analysis:

designing a sample plan-random, judgment, systematic-judgment, stratified and convenience sampling. Insitu sampling.

1hr Assignment By the end of April 2021

Sd/-

Total Teaching hours ^{16 hrs}

6. Internal Assessment Test-1 (C1) ^1hr ^{IA test} ¹^st week March 2021

Sd/- 7. Internal Assessment -02 (C2) 1hr IA test 4^th week of April

2021

Sd/- 8. Date of submission of IA Marks to the department: April 2021

Signature of Faculty Signature of HOD Principal

(2)

Government of Karnataka Department of Collegiate Education

Government Science College, Hassan

LESSON PLAN FOR THE ACADEMIC YEAR 2020-21

Programe: M.Sc Chemistry

Course/Paper Name: Analytical Chemistry - I UNIT 2 Semester: First Sem MSc

Name of the Faculty: Total Hours: 16 Sl.

No.

Topic covered No. of

Methodolog y/

pedagogy

Date Initials

1. Titrimetric analysis: An overview of titrimetry.

Neutralization titrations - Selecting and evaluating the end point. Finding the end point by:

4 hrs Black board/

Lecture PPT

2^nd Week of March 2021

2. Applications of neutralization titration 2 hrs Black board/

Lecture PPT

3^rd week of March 2021 3. Complexometric titrations: stepwise

formation constants, chelating agents,

1hr 4^th week of march 2021

4. EDTA - acidic properties, complexes with metal ions, equilibrium calculations involving EDTA, conditional formation constants,

2 hrs Black board/

Lecture PPT

1^st week of April2021

5. effect of other complexing agents, factors affecting the shape of titration curves -

2hrs 2^nd week of April 2021

6. alkalinity, acidity and free CO2 in water and waste waters,

Titration methods employing EDTA - direct, back and displacement titrations, indirect determinations, titration of mixtures.

1 hrs Seminar April 2021

7. Precipitation titrations:, factors affecting shape - titrants and standards, indicators for precipitation titrations involving silver nitrate, The Volhard,

3 hrs 3^rd week of April 2021

8. the Mohr and the Fajan’s methods and their applications.

1 hr 4^th week of April 2021

Total hours:16 Internal Assessment

Test/Quiz/Assignment – 01

4^th week of March2021 Internal Assessment

4^th week of March 2021

(3)

Government of Karnataka Department of Collegiate Education

Government Science College(Autonomous), Hassan

UNITWISE LESSON PLAN FOR THE ACADEMIC YEAR 2020-21

Course/Paper Name: Inorganic Chemistry-I – UNIT 1 Semester: First Sem MSc

Name of the Faculty: xxxxxxxxxxxxx Total Hours: 16

Sl.

No.

Methodology/

pedagogy

1 Ionic bond: properties of ionic substances, coordination number of an ion, Lattice energy- Born Lande equation, Born-Haber cycle, Uses of Born-Haber type of calculations.

2hrs Black board/

Lecture PPT

Sd/-

2 Ionic radii, factors affecting ionic radii, radius ratio rule,

3 hrs Black board/

Lecture PPT

1^st and 2^nd week of Feb 2021

Sd/- 3 Structures of crystal lattices- NaCl, CsCl,

ZnS and rutile.

1Hr Seminar 19-2-2021

4 Covalent character in ionic bonds,. ^1Hr ^Seminar ^19-2-2021

5 Metallic bond-band theory ^1hr ^Seminar ^19-2-2021

6 Covalent bond: valence bond theory, resonance, hybridization, Bent’s rules and energetics of hybridization, Deduction of molecular shapes – VSEPR theory. M.O. theory, application to homo- and hetero-diatomic and triatomic molecules. Covalent bonding- concept of hybridization , Bents Rules and energetics of hybridization , Hydrogen bonding

4 Hrs Black board/

Lecture PPT

3^rd and 4^th week of Feb 2021

Sd/-

7 Secondary bonds(Hydrogen bonding, Vanderwaal’s force etc),

3 hrs Black board/

Lecture PPT

1^st and 2^nd week of March 2021

Sd/- 8 Hydration energy and solubility of ionic

solids

1hr Assignment By the end of Feb 2021

Sd/-

Total Teaching hours ^{16 hrs}

9 Internal Assessment Test-1 (C1) ^1hr ^{IA test} ²^nd^{week of} March 2021

Sd/- 10 Internal Assessment -02 (C2) 1hr IA test 3^rd week of April

2021

Sd/- Date of submission of IA Marks to the department: 15-12-2019

(4)

Government of Karnataka Department of Collegiate Education

Government Science College, Hassan

UNITWISE LESSON PLAN FOR THE ACADEMIC YEAR 2020-21

Course/Paper Name: Inorganic Chemistry-I UNIT 2 Semester: First Sem MSc

Name of the Faculty: xxxxxxxxxxx Total Hours: 16 Sl.

No.

Methodology/

pedagogy

9. Theories of acids and bases – Bronsted acids and bases

10. Lewis acids and bases, , Lux-Flood theory, gas phase vs. solution acidity, solvent leveling effects,

2hrs Black board/

Lecture PPT

3^rd week of March 2021

11. Hardness and softness, HSAB concept.

Symbiosis. Applications of HSAB concept.

2 hrs Black board/

Lecture PPT

4^th week of March 2021

12. Reactions in non-aqueous media: Liquid ammonia, anhydrous sulphuric acid,

13. Reactions in glacial acetic acid, anhydrous HF, bromine trifluoride, liquid sulphur dioxide and dinitrogen tetroxide.

4Hr Black board/

Lecture PPT

1^st week of April 2021

14. Halogens and Noble gas chemistry – interhalogens, psuedohalogens, polyhalide ions, oxyhalogen species, xenon oxides

4 hrs Black board/

Lecture PPT

2^nd and 3^rd week of April 2021

7 Xenon fluorides. 1hr Seminar 05-03-2021

Total ^{16 Hrs}

8 Internal Assessment Test/Quiz/Assignment – 01

1hr IA test 2^nd week of March 2021

9 Internal Assessment Test/Quiz/Assignment – 02

1hr IA test 3^rd week of April 2021

(5)

Department of Collegiate Education

Government Science College, Hassan

UNITWISE LESSON PLAN FOR THE ACADEMIC YEAR 2020-21

Course/Paper Name: Inorganic Chemistry-I UNIT 3 Semester: First Sem MSc

Name of the Faculty: xxxxxxxxxxx Total Hours: 16 Sl.

No.

Methodology/

pedagogy

1. Chemistry of higher boranes, classification, structure and bonding, Wades rules styx number carboranes and metallocarboranes

3 Black board/

Lecture PPT

Jan 2021 and 1^st week of Feb 2021

2. Cyclophospazenes 1hr Seminar 05-03-2021

3. P-O and P-S cage compounds. 2 hrs Black board/

Lecture PPT

2^nd and 3^rd week of Feb 2021

4. S-N Compounds 2Hr Black board/

Lecture PPT

4^th week of Feb 2021and 1^st week of March 2021

5. Borazines and Boron nitrides ^2Hr Black board/

Lecture PPT

2^nd and 3^rd week of March 2021

6. Silicates 1hr Seminar 12-03-2021

7. Intercalation compounds of graphite 1hr Seminar 12-03-2021 8. The transition elements: EC, oxidation

states, magnetic properties, complexation, Isopoly and heteropoly acid of transition elements

4 Black board/

Lecture PPT

4^th week of March 2021 1^st and 2^nd week of April 2021

Total 16 Hrs

Internal Assessment Test/Quiz/Assignment – 01 Internal Assessment Test/Quiz/Assignment – 02

(6)

Department of Collegiate Education

Government Science College(Autonomous), Hassan UNITWISE LESSON PLAN FOR THE ACADEMIC YEAR 2020-21 Programe: M.Sc Chemistry

Course/Paper Name: Organic Chemistry-I – UNIT I Semester: First Sem MSc

Name of the Faculty: xxxxxxxxxx Total Hours: 16

Sl.

No.

Methodology/

pedagogy

9. Basics of organic reactions: Meaning and importance of reaction mechanism, classification and examples for each class.

2hrs Black board/

Lecture PPT

Sd/-

10. Bonding in organic systems: Theories of bonding-molecular orbital approaches.

Huckel molecular orbital theory and its application to simple π-systems:

Calculation of the total π -energy, and M.O. coefficients of the systems

3 hrs Black board/

Lecture PPT

Sd/-

11. Aromaticity: Concept of aromaticity, Huckel’s rule, Polygon rule, annulenes, heteroannulenes and polycyclic systems.

4 Hrs Black board/

Lecture PPT

3^rd, 4^th week of February 2021

Sd/-

12. Structure and reactivity: resonance, inductive and hyperconjugation on strengths of acids and bases.

1hr Seminar 1^st Week of March 2021

Sd/-

13. Acids and Bases: Introduction to acids and bases, Bronsted-Lowry and Lewis acid- bases concept, organic acids and bases, effect of structure of organic compound on acid and base strength

1hr Seminar 1^st week March 2021

Sd/-

14. Brief discussion on effects of hydrogen bonding,

1hr Seminar By the end of April 2021

Sd/- 15. Methods of determining organic

reaction mechanism:

3 hrs Black board/

Lecture PPT

4^th week of April 2021

Sd/- 16. Determination of reaction intermediates,

isotope labeling,

1hr Assignment Last week of Jan 2021

Sd/-

Total Teaching hours 16 hrs

17. Internal Assessment Test-1 (C1) 1hr IA test 2^nd week of March 2021

Sd/- 18. Internal Assessment -02 (C2) 1hr IA test Last week of

April 2021

Sd/- 19. Date of submission of IA Marks to the department: 30-04-2021

(7)

Course/Paper Name: Organic Chemistry-I – UNIT II Semester: First Sem MSc

Sl.

No.

Methodology/

pedagogy

1. Reaction Intermediates: Formation, structure, stability, detection and reactions of carbocations,carbanions, carbenes, nitrenes, arynes and ylides.

2hrs Black board/

Lecture PPT

Sd/-

2. Nucleophilic substitution reactions – SN1, SN2, SRNi, SNi, SN1', SN2’, SN1ⁱ and SRN1 reactions, Neighbouring group participation.

3 hrs Black board/

Lecture PPT

Sd/-

3. Electrophilic substitution reactions – Kinetics, mechanism and stereochemical factor affecting the rate of SE1 & SE2 reaction

2 Hrs Black board/

Lecture PPT

Sd/-

4. Formation, structure, stability, detection and reactions of Free radicals

1hr Seminar 1^st Week of March 2021

Sd/- 5. Decarboxylation Reaction 1hr Seminar 1^st week March

2021

Sd/- 6. BAC2 mechanism of Ester hydrolysis 1hr Seminar By the end of

April 2021

Sd/- 7. Aromatic electrophilic substitution

reactions: nitration, halogenation, sulphonation, Friedel-Crafts alkylation and acylation, Mannich reaction, chloromethylation, Vilsmeier Haack reaction,

3 hrs Black board/

Lecture PPT

4^th week of April 2021

Sd/-

8. Aromatic nucleophilic substitution reactions: SN1, SN2 and benzyne mechanism, Bucherer reaction, von Richter reaction.

Sd/-

9. Elimination reactions: - E1, E2, E1cB.

Cis elimination, Hofmann and Saytzeff.

Chugaev reaction.

Ester hydrolysis-AAC2, AAC1 & AAL1 mechanism.

2hrs Black board/

Lecture PPT

April 2021

(8)

Course/Paper Name: Organic Chemistry-I – UNIT III Semester: First Sem MSc

Sl.

No.

Methodology/

pedagogy

1. Stereoisomerism: Projection formulae , DL and RS configurational notations.

2hrs Black board/

Lecture PPT

Sd/- 2. Optical isomerism:: Elements of

symmetry- Optical isomerism in allenes, criteria for optical purity

2 hrs Black board/

Lecture PPT

Sd/-

3. Geometrical isomerism:, E, Z conventions, determination of configuration by physical and chemical methods.

2hrs Black board/

Lecture PPT

Sd/

4. Conformational analysis: ethane, butane and cyclohexane. Conformation of cyclic compounds Effect of conformation on the course and rate of reactions

3 Hrs Black board/

Lecture PPT

1^st Week of March 2021

Sd/-

5. Racemic Mixture and their resolution 1hr Seminar ¹^st week March 2021

Sd/- 6. Optical Activity of biphenyl compounds 1hr Seminar By the end of

April 2021

Sd/- 7. Geometric Isomerism in cyclic

compounds

1hr Seminar 4^th week of April 2021

Sd/- 8. Stereoselectivity: Meaning and

examples.

3 hrs Black board/

Lecture PPT

Sd/- 9. Enantiomers, diastereoisomers,

mesomers

Sd/-

April 2021

(9)

Government of Karnataka Department of Collegiate Education

Government Science College(Autonomous), Hassan

UNITWISE LESSON PLAN FOR THE ACADEMIC YEAR 2020-21

Course/Paper Name: Physical Chemistry-I – UNIT I Semester: First Sem MSc

Name of the Faculty: XXXXXXX Total Hours: 16

Sl.

No.

Methodology/

pedagogy

20. Concepts of Entropy and Free energy:

First andsecond laws.

2hrs Black board/

Lecture PPT

Sd/- 21. Helmholtz and Gibbs free energies.

Thermodynamic criteria of equilibrium and spontaneity. Variation of free energy with temperature and pressure.

2 hrs Black board/

Lecture PPT

Sd/-

22. Maxwell’s relations. Third law of thermodynamics - Nernst heat theorem &

its applications.

2 Hrs Black board/

Lecture PPT

17-02-2021 Sd/-

23. Thermodynamics of simple mixtures:

Partial molar volumes Chemical potential and its significance. Variation chemical potential. Gibbs-Duhem equation.

4hr Seminar 3^rd, 4^th week of February 2021 1^st Week of March 2021

Sd/-

24. Derive Duhem-Margules

equation.Chemical potential, Raoult’s law and Henry’s law.

1hr Seminar By the end of

April 2021

Sd/-

25. Thermodynamic properties of Ideal and Real solutions.

1hr Seminar

26. Fugacity: fugacity of gases and variation, Activity and activity coefficients and Variation Determination of activity

4 hrs Black board/

Lecture PPT

1^st week March 2021

Sd/-

27. 1hr Assignment 4^th week of April

2021

Sd/-

Total Teaching hours 16 hrs Last week of Jan

2021

Sd/- 28. Internal Assessment Test-1 (C1) 1hr IA test 1^st, 2^nd week of

February 2021

Sd/-

29. Internal Assessment-02 (C2) 1hr IA test 17-02-2021 Sd/-

30. Date of submission of IA Marks to the department: 15-12-2019

(10)

Government of Karnataka Department of Collegiate Education

Government Science College(Autonomous), Hassan

UNITWISE LESSON PLAN FOR THE ACADEMIC YEAR 2020-21

Course/Paper Name: Physical Chemistry-I – UNIT II Semester: First Sem MSc

Sl.

No.

Methodology/

pedagogy

13. Chemical KineticsBasic kinetic concepts: Scope, Stoichiometry, Rate, Order and Rate constant Determination of rates and orders

2hrs Black board/

Lecture PPT

Sd/-

14. Kinetics of complex reactions: Parallel, Consecutive and Reversible Reactions Effect of Temperature; Arrhenius Equation, energy of activation Potential energy surfaces

3 hrs Black board/

Lecture PPT

Sd/-

15. Kinetic theory of Collision

Elementary Gas-Phase reactions:

Unimolecular, Marcus’s Extension of the RRK Treatment(RRKM). Lindemann- Christainsen Hypothesis,

4 Hrs Black board/

Lecture PPT

17-02-2021 Sd/-

16. Hinshelwood’s Treatment, Rice- Ramsperger-Kassel(RRK) Treatment

1hr Seminar 3^rd, 4^th week of February 2021

Sd/-

17. Calculations- London Equation Method 1hr Seminar By the end of April 2021

Sd/- 18. London-Eyring-Polanyi method. 1hr Seminar

19. Kinetics of reaction in solution- Salt effects, Solvent effects, effect of pressure,

3 hrs Black board/

Lecture PPT

Sd/-

20. Fast Reaction Techniques – ^1hr Assignment 4^th week of April 2021

Sd/-

Total Teaching hours ^{16 hrs} Last week of Jan

2021

February 2021

Sd/-

22. Internal Assessment-02 (C2) ^1hr ^{IA test} 17-02-2021 Sd/-

(11)

Government of Karnataka Department of Collegiate Education

Government Science College(Autonomous), Hassan

UNITWISE LESSON PLAN FOR THE ACADEMIC YEAR 2020-21

Course/Paper Name: Physical Chemistry-I – UNIT III Semester: First Sem MSc

Sl.

No.

Methodology/

pedagogy

1. Electrochemistry: Ionics.

Arrhenius theory, Debye-Huckel theory of strong electrolytes, Bjerrum theory, Walden`s rule and its application.

2hrs Black board/

Lecture PPT

Sd/-

2. Electrical Double layer Theories : A brief survey of Helmholtz-Perrin, Gouy- Chapman, Stern electrical double layer,

3 hrs Black board/

Lecture PPT

Sd/-

3. Transport Number: transport number.

Abnormal transport numbers,

4 Hrs Black board/

Lecture PPT

17-02-2021 Sd/- 4. concentration over voltage activation

over voltage, experimental determination

Sd/- 5. Energy barrier and electrode kinetics,

Butler-Volmer equation, Tafel equation.

April 2021

Sd/- 6. Hydrogen over voltage and Oxygen over

voltage. Effect of temperature, current density and pH on over voltage.

1hr Seminar

7. Irrversible electrode process: reversible and irreversible electrodes, Polarization, over voltage, diffusion current,diffusion controlled current

3 hrs Black board/

Lecture PPT

Sd/-

8. polarography, half wave potential, application in qualitative and quantitative analysis.

1hr Assignment 4^th week of April 2021

Sd/-

Total Teaching hours 16 hrs Last week of Jan

2021

February 2021

Sd/-

(12)

Government of Karnataka Department of Collegiate Education

Government Science College(Autonomous), Hassan

UNITWISE LESSON PLAN FOR THE ACADEMIC YEAR 2020-21

Course/Paper Name: Chemical spectroscopy -I – UNIT I Semester: First Sem MSc

Sl.

No.

Methodology/

pedagogy

1. Molecular symmetry: Symmetry elements and symmetry operations, Products of symmetry operations.

2hrs Black board/

Lecture PPT

Sd/-

2. General relations among symmetry elements and symmetry operations. Group theory:

2 hrs Black board/

Lecture PPT

Sd/-

3. Concept of a group, definition of a point group, procedure for classification of molecules into point groups.

2 Hrs Black board/

Lecture PPT

17-02-2021 Sd/-

4. Subgroups. Schoenflies and Hermann- Maugin symbols for point groups.

Multiplication tables for the symmetry operations of simple molecules.

Sd/-

5. Assigning point group to molecules 1hr Seminar By the end of April 2021

Sd/- 6. : Symmetry elements and symmetry

operations,

1hr Seminar

7. Matrix notation for the symmetry elements and for geometric transformations. Class of a group and similarity transformation.

4 hrs Black board/

Lecture PPT

Sd/-

8. Hermann-Maugin symbols for point groups. 1hr Assignment 4^th week of April 2021

Sd/-

Total Teaching hours ^{16 hrs} Last week of Jan

2021

February 2021

Sd/-

10. Internal Assessment-02 (C2) ^1hr ^{IA tes} 17-02-2021 Sd/-

(13)

Government of Karnataka Department of Collegiate Education

Government Science College(Autonomous), Hassan

UNITWISE LESSON PLAN FOR THE ACADEMIC YEAR 2020-21

Course/Paper Name: Chemical spectroscopy-I – UNIT II Semester: First Sem MSc

Sl.

No.

Methodology/

pedagogy

1. Representation of groups: Reducible and irreducible representations. The Great Orthogonality theorem and its consequences.

2hrs Black board/

Lecture PPT

Sd/-

2. Labeling of irreducible representations.

Group theory and hybrid orbitals to form bonds

3 hrs Black board/

Lecture PPT

Sd/-

3. Applications of group theory: Applications of group theory to crystal field theory. Bonding in octahedral and tetrahedral complexes.

4 Hrs Black board/

Lecture PPT

17-02-2021 Sd/-

4. Symmetry and dipole moments, symmetry and optical activity.

Sd/-

5. Character tables (Cs, Ci, C2, 1hr Seminar By the end of April 2021

Sd/- 6. Character tables C2v, C2h and C3v). 1hr Seminar

7. Molecular vibrations: Introduction, symmetry of normal vibrations, determining the symmetry types of normal modes, selection rules for fundamental vibration transitions.

Representation of vibrational modes in non- linear molecules.

3 hrs Black board/

Lecture PPT

Sd/-

8. Group theory and linear molecules (Integration method).

Sd/-

9. Total Teaching hours ^{16 hrs} Last week of Jan

2021

February 2021

Sd/-

(14)

Government of Karnataka Department of Collegiate Education

Government Science College(Autonomous), Hassan

UNITWISE LESSON PLAN FOR THE ACADEMIC YEAR 2020-21

Course/Paper Name: Chemical spectroscopy -I – UNIT III Semester: First Sem MSc

Sl.

No.

Methodology/

pedagogy

1. Microwave spectroscopy: Rotation spectra of diatomic Molecules - rigid and non rigid rotator model. selection rule. isotopic substitution.

2hrs Black board/

Lecture PPT

Sd/-

2. Vibration spectroscopy: Vibration of diatomic molecules, vibrational energy.

Effects of anharmonic oscillation.

3 hrs Black board/

Lecture PPT

Sd/-

3. fundamental, overtone, combination and difference bands. Fermi resonance.

4 Hrs Black board/

Lecture PPT

17-02-2021 Sd/- 4. Factors affecting-hydrogen bonding, steric

effect and ring strain.

Sd/-

5. Applications: Structures of small molecules:

XY2 – linear or bent, XY3 – planar or pyramidal. Coordination compounds (N,N dimethyl acetamide, urea, DMSO and nitrite complexes).

April 2021

Sd/-

6. Factors affecting the group frequency – Physical state, vibrational coupling, electrical effect,

1hr Seminar 1^st march Sd/-

7. Raman spectroscopy: Introduction, Raman and Rayleigh scattering, Stokes and anti- Stokes lines, polarizability ellipsoid.

3 hrs Black board/

Lecture PPT

Sd/-

8. Experimental techniques - Principles of determination of Bond length and moment of inertia, dipole moments

Sd/-

9. Total Teaching hours 16 hrs Last week of Jan

2021

Sd/- 10. Internal Assessment Test-1 (C1) ^1hr ^{IA test} ¹^st^{, 2}^nd^{week of}

February 2021

Sd/-

11. Internal Assessment-02 (C2) ^1hr ^{IA test} 17-02-2021 Sd/-

(15)

Government of Karnataka Department of Collegiate Education

Government Science College, Hassan

LESSON PLAN FOR THE ACADEMIC YEAR 2020-21

Course/Paper Name: Analytical Chemistry - III UNIT 1 Semester: Third Sem MSc

No.

Methodology/

pedagogy

1. Classification of electrochemical methods: potentiometers, galvanostats and potentiostats.

Potentiometric methods of analysis.

Membrane electodes –

4 hrs Black board/

Lecture PPT

1^st week of December 2020

2. Quantitative applications. 4 hrs Black board/

Lecture PPT

2nd week of December 2020

3. Coulometric methods of analysis:

General discussion, coulometry at controlled potential, apparatus and

general technique, applications

4 hr 3^rd week of December

2020

4. Voltammetry:

Fundamentals of voltammetry.

Cyclic voltammetry: Principles and applications.

Stripping analysis: Stripping voltammetry

3 hrs Black board/

Lecture PPT

4^th week of December 2020

5. Gas sensing electrodes. Potentiometric biosensors.

Electrogravimetric analysis:

1 hrs Seminar 3^rd week of December

2^nd Week of January 2021

Internal Assessment Test/Quiz/Assignment – 02

3^rd week of Febrary 2021

(16)

Government of Karnataka Department of Collegiate Education

Government Science College, Hassan

LESSON PLAN FOR THE ACADEMIC YEAR 2020-21

No.

Methodology/

pedagogy

1. Flame photometry and Atomic absorption spectrometry:

4 hrs Black board/

Lecture PPT

1^st week of January 2021

2. Typical commercial instruments for FP and AAS, applications.

4 hrs Black board/

Lecture PPT

2nd week of January 2021

3. Molecular luminescence spectrometry:

Theoretical basis for fluorescence and phosphorescence. Singlet and triplet excited states. Variables affecting luminescence -

4hr 3^rd week of January

2021

4. Fluorescence instrumentation - fluorometers and spectrofluorometers.

Sensitivity and selectivity.

Modification necessary to measure phosphorescence. General scope of applications of luminescence.

3hrs Black board/

Lecture PPT

4^th week of January 2021

5. Nephelometry and turbidometry:

Principles, instrumentation and applications.

1 hrs Seminar

6. 1 hr

3^rd week of February 2021

(17)

Government of Karnataka Department of Collegiate Education

Government Science College, Hassan

LESSON PLAN FOR THE ACADEMIC YEAR 2020-21

No.

Methodology/

pedagogy

1. Thermal method of analysis:

Introduction,

Thermogravimetric analysis (TGA):

types of thermogravimetric analysis, principles. Applications

5 hrs Black board/

Lecture PPT

1^st week of February 2021

2. Differential thermal analysis (DTA):

Theory - variables affecting the DTA curves. Differences between TGA and

DTA. General principles.

Instrumentation. Applications -

5 hrs Black board/

Lecture PPT

2nd week of February 2021

3. Differential scanning calorimetry (DSC): Basic principle. Differences between DTA and DSC Applications he samples

5hr Black board/

Lecture PPT

4. . Instrumentation - power compensated DSC, Heat flux DSC.

Enthalpimetric analysis: Thermometric titrimetry and.

1 hrs Seminar

5. direct injection enthalpimetry - principle, instrumentation, applications

1hrs Assignment . Total

hours:16 Internal Assessment

(18)

Course/Paper Name: Organic Chemistry-III – UNIT I Semester: Third Sem MSc

Sl.

No.

Methodology/

pedagogy

1. Reductions: Catalytic hydrogenations (homogeneous and heterogeneous) - catalysts, solvent,equipment and reduction of functional groups,

2hrs Black board/

Lecture PPT First week of December 2020

Sd/-

2. diborance, Meerwein-Ponndorf-Verley reduction, Wolf-Kishner reduction, Clemensen reduction.

2hrs Black board/

Lecture PPT

2^nd Week of December 2020

Sd/

3. Oxidations: Oxidation with chromium and manganese compounds (CrO3, K2Cr2O7, PCC, PDC, Sarret reagent,

3hrs Black board/

Lecture PPT

3^rd, 4^th week of December 2020

Sd/

4. Jones reagent, MnO2, KMnO4), ozone, peroxides and peracids, lead tetra acetate, periodic acid, OsO4, SeO2, NBS,

3hrs Black board/

Lecture PPT

Ist, 2^nd week of Jan 2021

Sd/

5. chloramine-T, Sommelet oxidation, Oppenauer oxidation.

2hrs Black board/

Lecture PPT

3^rd and fourthWeek of Jan 2021

Sd/

6. Wilkinson catalyst. Bakers yeast 1hrs Black board/

Lecture PPT

First week of Feb 2021

Sd/- 7. Oxidation with peroxides 1 Hrs Seminar Last week of

December 2020

Sd/- 8. metal dissolving re actions (Birch

reduction)

1hr Seminar First week of Jan 2021

Sd/- 9. Oxidation with oxygen (singlet and triplet) 1hr Seminar Last week of

December 2020

Sd/- 10. Catalytic hydrogen transfer reactions.,.

Leukart reaction

1hr Assignment second week of February 2021

Sd/-

11. Internal Assessment Test-1 (C1) 1hr IA test Last week of Jan 2021

Sd/- 12. Internal Assessment -02 (C2) 1hr IA test First week of

March

Sd/- 13. Date of submission of IA Marks to the department: Second week of March 2021

(19)

Course/Paper Name: Organic Chemistry-III – UNIT II Semester: Third Sem MSc

Sl.

No.

Methodology/

pedagogy

1. Lithium disopropylamide (LDA),

Gilmann reagent,

dicyclohexylcarbodimide (DCC),

2hrs Black board/

Sd/-

2. dichloro dicyano quinone (DDQ), , 2hrs Black board/

Lecture PPT

Sd/

3. trialkyl silyl halides, trimethyl silylcyanide, cyclodextrins

3hrs Black board/

Lecture PPT

Sd/

4. Fenton’s reagent, Ziegler-Natta catalyst, diazomethane, tributyl tinhydride, stannous chloride, Sharpless epoxidation,

3hrs Black board/

Lecture PPT

Sd/

5. Phosphorus ylides – Wittig and related reactions, sulphur ylides – reactions with aldehydes and ketones,1,3-dithiane anions - Umpolung reaction

2hrs Black board/

Lecture PPT

Sd/

6. Peterson reactions - synthesis of alkenes. 1hrs Black board/

Lecture PPT

Sd/- 7. Woodwardand Prevost hydroxylation 1 Hrs Seminar Last week of

December 2020

Sd/- 8. Stark enamine reaction 1hr Seminar First week of Jan

2021

Sd/- 9. phase transfer catalyst, crown ethers 1hr Seminar Last week of

December 2020

Sd/- 10. Microwave induced organic synthesis, 1hr Assignment second week of

February 2021

Sd/-

March

(20)

Course/Paper Name: Organic Chemistry-III – UNIT III Semester: Third Sem MSc

Sl.

No.

Methodology/

pedagogy

1. Organic Name reactions: Reactions, Mechanisms and synthetic uses of the following: Stolbe condensation, Darzen condensation, Cannizzaro reaction, , Benzoin condensation,

3hrs Black board/

Sd/-

2. Claisen-Schmidt condensation, Claisen reaction, Simon-Smith reaction,

2hrs Black board/

Lecture PPT

Sd/

3. . Michael addition, Robinson’s annulation reaction

2hrs Black board/

Lecture PPT

Sd/

4. Protecting groups: Protection of hydroxyl, carboxyl, carbonyl, thiol and amino groups.

Illustration of protection and deprotection in synthesis

2hrs Black board/

Lecture PPT

Sd/

5. Retrosynthesis: Introduction to disconnection approach: Basic principles and terminologies used in disconnection approach. One group C-X and two group C- X disconnections. Synthons and synthetic equivalents

2hrs Black board/

Lecture PPT

Sd/

6. Retrosynthesis and synthesis of benzofurans, p-methoxy acetophenone, saccharine, α- bisabolene,nuciferine, penicillin-V.

2hrs Black board/

Lecture PPT

Sd/-

7. Gattermann-Koch reaction 1 Hrs Seminar Last week of

December 2020

Sd/- 8. Suzuki coupling, Ullmann reaction. 1hr Seminar First week of

Jan 2021

Sd/- 9. Chichibabin reaction, Hofmann-Loffler-

Freytag reaction,

1hr Seminar Last week of December 2020

Sd/- 10. Wittig reaction-Mitsunobu reaction.

Tischenko reaction

1hr Assignment 2nd week of February 2021

Sd/-

March