: Anisic Aldehyde. SECTION 1: Identification of the substance/mixture and of the company/undertaking. SECTION 2: Hazards identification

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Date of issue: 10/09/2013 Version: 1.0

06/03/2015 EN (English US) Page 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Substance

Trade name : Anisic Aldehyde

CAS No : 123-11-5

Product code : A5010

Formula : C8H8O2

Synonyms : 4-anisaldehyde / anisaldehyde / anisic aldehyde / aubepine / benzaldehyde, 4-methoxy- / crategine / FEMA no 2670 / obepin / p-anisaldehyde / p-anisic aldehyde / para-anisaldehyde / para-anisic aldehyde / para-formylanisole / para-methoxybenzaldehyde / formylanisole / p-methoxybenzaldehyde

BIG no : 21159

1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet

CHEMTEX USA 27-29 Dwight Place Fairfield, 07004 - USA

T 862-702-8900 - F 862-702-8180

[email protected] - www.chemtexusa.com

1.4. Emergency telephone number

Emergency number : CHEMTEL:(800)255-3924

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture Classification (GHS-US)

Skin Irrit. 2 H315 Eye Irrit. 2A H319 Aquatic Acute 3 H402

Full text of H-phrases: see section 16

2.2. Label elements GHS-US labeling

Hazard pictograms (GHS-US) :

GHS07 Signal word (GHS-US) : Warning

Hazard statements (GHS-US) : H315 - Causes skin irritation H319 - Causes serious eye irritation H402 - Harmful to aquatic life

Precautionary statements (GHS-US) : P264 - Wash skin thoroughly after handling P273 - Avoid release to the environment

P280 - Wear eye protection, face protection, protective clothing, protective gloves P302+P352 - If on skin: Wash with plenty of water

P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P321 - supplemental first aid Specific treatment (see supplemental first aid on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention

P337+P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing and wash it before reuse

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according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

2.3. Other hazards

No additional information available

2.4. Unknown acute toxicity (GHS-US)

Not applicable

SECTION 3: Composition/information on ingredients

3.1. Substance

Name Product identifier % Classification (GHS-US)

p-Methoxybenzaldehyde (Main constituent)

(CAS No)123-11-5 100 Skin Irrit. 2, H315

Eye Irrit. 2A, H319 Aquatic Acute 3, H402 Full text of H-phrases: see section 16

3.2. Mixture

Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

First-aid measures after inhalation : Remove the victim into fresh air. Assure fresh air breathing. Allow the victim to rest. First-aid measures after skin contact : Wash immediately with lots of water (15 minutes)/shower. Soap may be used. Do not apply

(chemical) neutralizing agents. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see ... on this label).

First-aid measures after eye contact : Rinse cautiously with water for several minutes. Rinse immediately with plenty of water for 15 minutes. Take victim to an ophthalmologist. Do not apply neutralizing agents. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

First-aid measures after ingestion : Rinse mouth with water. Ingestion of large quantities: immediately to hospital. Call Poison Information Centre (www.big.be/antigif.htm). Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Feeling of weakness. Dizziness. Nausea. Symptoms/injuries after skin contact : Tingling/irritation of the skin. Causes skin irritation.

Symptoms/injuries after eye contact : Irritation of the eye tissue. Causes serious eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Water spray. Alcohol-resistant foam. Polymer foam. BC powder. Carbon dioxide. Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Unsuitable extinguishing media : Solid water jet ineffective as extinguishing medium. Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

Fire hazard : DIRECT FIRE HAZARD. Combustible. INDIRECT FIRE HAZARD. Temperature above flashpoint: higher fire/explosion hazard.

Explosion hazard : DIRECT EXPLOSION HAZARD. No data available on direct explosion hazard. INDIRECT EXPLOSION HAZARD. No data available on indirect explosion hazard.

Reactivity : Upon combustion: CO and CO2 are formed.

5.3. Advice for firefighters

Precautionary measures fire : Exposure to fire/heat: keep upwind. Exposure to fire/heat: seal off low-lying areas. Exposure to fire/heat: have neighbourhood close doors and windows.

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06/03/2015 EN (English US) 3/7 Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus. Do not enter fire area without proper

protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel

Protective equipment : Gloves. Face-shield. Protective clothing. See "Material-Handling" to select protective clothing. Emergency procedures : Mark the danger area. No naked flames. Wash contaminated clothes. Evacuate unnecessary

personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area.

6.2. Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

For containment : Contain released substance, pump into suitable containers. Consult "Material-handling" to select material of containers. Plug the leak, cut off the supply.

Methods for cleaning up : Take up liquid spill into inert absorbent material, e.g.: sand, earth, vermiculite. Scoop absorbed substance into closing containers. See "Material-handling" for suitable container materials. Clean contaminated surfaces with an excess of water. Wash clothing and equipment after handling. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.

6.4. Reference to other sections

See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Comply with the legal requirements. Remove contaminated clothing immediately. Clean contaminated clothing. Keep away from naked flames/heat. Finely divided: spark- and explosionproof appliances. Finely divided: keep away from ignition sources/sparks. Observe normal hygiene standards. Keep container tightly closed. Carry operations in the open/under local exhaust/ventilation or with respiratory protection. Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Provide good ventilation in process area to prevent formation of vapor.

Hygiene measures : Wash ... thoroughly after handling.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.

Incompatible products : Strong bases. strong acids. Incompatible materials : Sources of ignition. Direct sunlight.

Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources.

Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: oxidizing agents. reducing agents. (strong) bases. Storage area : Store in a dry area. Store in a dark area. Ventilation at floor level. May be stored under

nitrogen. Meet the legal requirements.

Special rules on packaging : SPECIAL REQUIREMENTS: hermetical. correctly labelled. meet the legal requirements. Secure fragile packagings in solid containers.

Packaging materials : SUITABLE MATERIAL: glass. aluminium.

7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Anisic Aldehyde (123-11-5)

ACGIH Not applicable

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8.2. Exposure controls

Personal protective equipment : Avoid all unnecessary exposure. Materials for protective clothing : GIVE GOOD RESISTANCE: rubber. Hand protection : Gloves. Wear protective gloves.

Eye protection : Face shield. Chemical goggles or safety glasses. Skin and body protection : Protective clothing. Wear suitable protective clothing.

Respiratory protection : High gas/vapour concentration: gas mask. Wear approved mask. Other information : When using, do not eat, drink or smoke.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Appearance : Liquid.

Color : Colourless Turns yellow

Odor : Floral odour

Odor threshold : No data available

pH : 7 (0.2 %) pH solution : 0.2 % Melting point : -1 °C

Freezing point : No data available

Boiling point : 248 °C

Flash point : 124 °C

Relative evaporation rate (butyl acetate=1) : No data available

Flammability (solid, gas) : No data available

Explosion limits : 1.4 - 5.3 vol %

Explosive properties : No data available

Oxidizing properties : No data available

Vapor pressure : < 1 hPa

Relative density : 1.1

Relative vapor density at 20 °C : 4.7

Specific gravity / density : 1120 kg/m³ Molecular mass : 136.15 g/mol

Solubility : Poorly soluble in water. Soluble in ethanol. Soluble in ether. Soluble in acetone. Soluble in oils/fats. Soluble in propyleneglycol. Soluble in chloroform. Soluble in sodiumhydrogensulfite. Water: 0.33 g/100ml Ethanol: Complete Ether: Complete Log Pow : 1.5

Log Kow : No data available

Auto-ignition temperature : 220 °C

Decomposition temperature : No data available

Viscosity : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

9.2. Other information

Other properties : Gas/vapour heavier than air at 20°C. Clear. Slightly volatile.

SECTION 10: Stability and reactivity

10.1. Reactivity

Upon combustion: CO and CO2 are formed.

10.2. Chemical stability

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10.3. Possibility of hazardous reactions

Not established.

10.4. Conditions to avoid

Direct sunlight. Extremely high or low temperatures.

10.5. Incompatible materials

strong acids. Strong bases.

10.6. Hazardous decomposition products

fume. Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

LD50 oral rat 3210 mg/kg (Rat) LD50 dermal rabbit > 5000 mg/kg (Rabbit) ATE US (oral) 3210.000 mg/kg body weight Skin corrosion/irritation : Causes skin irritation.

pH: 7 (0.2 %)

Serious eye damage/irritation : Causes serious eye irritation. pH: 7 (0.2 %)

Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated

exposure)

: Not classified

Aspiration hazard : Not classified Potential Adverse human health effects and

symptoms

: Based on available data, the classification criteria are not met.

Symptoms/injuries after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Feeling of weakness. Dizziness. Nausea. Symptoms/injuries after skin contact : Tingling/irritation of the skin. Causes skin irritation.

Symptoms/injuries after eye contact : Irritation of the eye tissue. Causes serious eye irritation.

SECTION 12: Ecological information

12.1. Toxicity

Ecology - water : Mild water pollutant (surface water). Slightly harmful to fishes (LC50 100-1000 mg/l). Toxic to algae. Toxic to aquatic organisms. Harmful to aquatic life.

LC50 fish 1 220 mg/l (96 h; Leuciscus idus) EC50 Daphnia 1 83 mg/l (48 h; Daphnia magna) Threshold limit algae 1 43 mg/l (72 h; Algae)

12.2. Persistence and degradability

Persistence and degradability Readily biodegradable in water. Not established.

12.3. Bioaccumulative potential

Log Pow 1.5

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12.4. Mobility in soil

12.5. Other adverse effects

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Remove to an authorized incinerator equipped with an afterburner and a flue gas scrubber with energy recovery. Do not discharge into drains or the environment. Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for empty clean containers which can be disposed of as non-hazardous waste. Additional information : Hazardous waste according to Directive 2008/98/EC.

Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

Department of Transportation (DOT)

In accordance with DOT Not regulated for transport

Additional information

Other information : No supplementary information available.

ADR

Transport by sea

Air transport

SECTION 15: Regulatory information

15.1. US Federal regulations

Listed on the United States TSCA (Toxic Substances Control Act) inventory

15.2. International regulations CANADA

EU-Regulations

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Acute Tox. 4 (Oral) H302

Full text of H-phrases: see section 16

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

Xn; R22 Xi; R36/38

Full text of R-phrases: see section 16

National regulations

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15.3. US State regulations

SECTION 16: Other information

Other information : None. Full text of H-phrases:

--- Aquatic Acute 3 Hazardous to the aquatic environment - Acute Hazard Category 3

--- Eye Irrit. 2A Serious eye damage/eye irritation Category 2A

--- Skin Irrit. 2 Skin corrosion/irritation Category 2

--- H315 Causes skin irritation

--- H319 Causes serious eye irritation

--- H402 Harmful to aquatic life

NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given.

NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,

and are not reactive with water.

SDS US (GHS HazCom 2012) Disclaimer:

______________________________________________________________________________________ 150 River Road, Suite G3B, Montville, NJ 07045. Ph. # (973) 335-2500; Fax # (973) 335-2552.