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Chapter 5

(2)
(3)

Stowe Periodic Table

(4)

A Spiral Periodic Table

(5)

“Mayan” Mayan”

Periodic

Periodic

Table

(6)

John Newlands

In 1865 English chemist John Newlands arranged

the known elements according to their

(7)

Patterns in Newland’s table

Newland noticed that the

properties of the elements

repeated themselves every 8

elements.

(8)

Mendeleev’s Periodic Table

Mendeleev’s Periodic Table

(9)

Dimitri Mendeleev

In 1869 the Russian

chemist Mendeleev took

Newland’s ideas a step

further

Mendeleev is known as

the father of the modern

(10)

How Mendeleev arranged his table

:

He began to arrange the elements by increasing atomic mass. He noticed that as he did this

that there was a repeating pattern of properties of the elements. So he put elements with the

(11)

Mendeleev’s Predictions

When Mendeleev was arranging his table, many elements had not been discovered yet. So he left spaces blank on the table and predicted the

properties of elements when they were

(12)

Henry

Moseley

Henry Moseley took Mendeleev’s table and changed it by arranging the elements by increasing atomic number. See table for exceptions!!!

Periodic Law – the physical and chemical properties of the elements are periodic functions of their atomic number, that when elements are arranged by

(13)

Modern Periodic table

The modern

table is

arranged by

increasing

(14)

The Periodic Table

The Periodic Table

Period

Group or

family

Period

(15)

Elements in groups 1,2 and 13-18

are called the main group

(16)

The Properties of a Group:

The Properties of a Group:

the Alkali Metals

the Alkali Metals

Extremely reactive elements – never

found in nature as a pure element,

always as part of a compound. Elements in this group will form salts with

non-metals – Properties:

ShinySoft

(17)

Why do alkali metals behave in the same way and have the same physical and chemical properties?

Because their electron

configurations are similar. All alkali metals end is an s1

configuration.

Na: 1s22s22p63s1

(18)

Reason for alkali metals

reactivity

Alkali metals want to lose the s1 electron in

the outermost energy level - this way they have an electron configuration like a noble gas!

Example: Na: 1s22s22p63s1

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Videos of Alkali metals

Brainiac

https://www.youtube.com/watch?v=m55kg yApYrY

Disposal of Sodium after WW II

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Hydrogen is a special element!

Hydrogen is unique – it is in group 1 because its electron configuration is

similar to the alkali metals but it is not

considered to be an alkali metal!

Hydrogen is the most common element in the

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Stars are composed of hydrogen

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Like the alkali metals below it on

the table hydrogen is a very

reactive element!

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Group 2 – Alkaline Earth Metals

These elements are:

harder than alkali metalsgood conductors

shiny

reactive metals

very light but strong!Not found in nature as

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s block elements

Elements in groups 1 & 2 are

also called s block elements

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d-block elements – Transition metals

Elements in the d-block are also called

transition metals. Groups 3-12

They tend to have the following properties:

Excellent conductors

Shiny

Not very reactive

Do not easily form compounds compared to alkali or alkaline earth metals

(29)

Special transition metals

Gold, silver, nickel,

(30)

Titanium:

Used to make

replacement

(31)

Tungsten

This element has the highest melting point (6192 F) and is

used in incandescent light bulbs

Also because of its high strength its used as in the

(32)

Mercury

The only metal that is a liquid at room temperature

Used in thermometers, barometers, some electrical

(33)

The p – block elements

The p-block elements contains:

Metals like aluminum and tin

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Properties

Properties

of Nonmetals

of Nonmetals

Carbon, the graphite in “pencil lead” is a great example of a nonmetallic element.

Nonmetals poor conductors of

heat and electricity (insulators)

Nonmetals tend to be brittle When solid are usually dull

Many nonmetals are gases at

(35)

Examples of Nonmetals

Examples of Nonmetals

Sulfur, S, was once known as “brimstone”

Microspheres of phosphorus, P, a reactive nonmetal

(36)

Most of the non-metals are

gases

(37)

Group 17 - Halogens

These elements have the following properties:

Extremely reactive, like to react with alkali

and alkali earth metals to form salts

All have an electron configuration of s2p5

Fluorine and Chlorine are gases at room

(38)

Uses of halogens

Chlorine, bromine

and iodine are used as disinfectants

Fluorine is used to

strengthen teeth

Halogens are also

(39)

Gallium

A p-block metal that is

not a great conductor, it is often used as a

semiconductor in electronics.

An interesting property

of gallium is that it melts just above room

(40)

Aluminum

Another p-block metal –

known as a lightweight

metal that is very strong and

resists corrosion.

It is used in automobiles,

trucks, aircraft, trains, cans,

foil and construction

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Lead

A p-block metal that is dull, very soft and malleable and very heavy – has been used for thousands of years by man in plumbing (the symbol Pb comes from the Latin word

plumbum), in bullets, it makes

excellent pigments in paint, its high density makes it ideal for shielding of different forms of radiation. Lead is also used for electrolysis in car

(42)

Negatives of lead

While lead has many applications, it is a

dangerous metal for human beings!

Lead can cause damage to nervous system, blood and

(43)

Noble Gases These elements are special in that they do not react with anything. This is because they have

(44)

Uses of Noble Gases

• Helium is used for balloons and

blimps

(45)

Properties of Metalloids

Properties of Metalloids

Metalloids straddle the border between metals and nonmetals on the periodic table. Also

known as semiconductors

They have properties of both metals and

(46)
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Silicon, Si – A Metalloid

Silicon, Si – A Metalloid

Silicon has metallic luster

Silicon is brittle like a nonmetal Silicon is a semiconductor of

(48)

Arsenic

(49)

The f-block elements:

Lanthanides and Actinides

Elements 58-71 are known as the lanthanides – they are shiny, reactive metals, found in the Earth’s crust. These elements are also known as the rare earth

metals because they are so scarce! Not many common uses for these metals.

Elements 90-103 are known as the actinides – all

(50)

Periodic Trends

The word

trend

means a change in a

general direction.

The periodic table has many trends

that can be explained how the

(51)

Trend: Atomic Size

The size of an atom is dependant on the

electron clouds around the nucleus. The nucleus of an atom is extremely small and the closest electron is very far away. If the nucleus of the a

hydrogen atom was the size of a basketball its electron would be thousands of miles away. All

(52)

Trend within a group

Going down a group the size of the atom increases dramatically.

This is because there are layers of orbitals (like an onion) and the outermost electrons do not

(53)

Trend within a period

Within a period the size of the elements

generally tend to decrease but there are some exceptions.

The reason for the decrease is due to the greater pull from the nucleus and the desire for the

(54)
(55)

Electronegativity

Electronegativity is defined as an element’s ability to gain electrons for chemical

bonding.

(56)

Trends for electronegativity

Going down a group electronegativity of those elements decreases. There is less of a pull from

the nucleus and the element is less likely to want to gain electrons

Going across a period from left to right there is more pull from the nucleus and the outer most

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Trend for valence electrons in

the main group elements

Valence electrons are electrons in the outer most energy levels – for the main group

elements these are the electrons in the

outermost s & p orbitals!

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https://www.youtube.com/watch?v=m55kgyApYrY https://www.youtube.com/watch?v=HY7mTCMvpEM https://www.youtube.com/watch?v=zWKyYRJEcRo

References

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