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(1)

Extrusion Blow

Extrusion Blow

-

-

Moulding:

Moulding:

The Process

(2)

Dept. Polymer Engineering

University of Minho

Applications

Applications

(3)

Extrusion based process

Extrusion based process

Hopper

Control

panel

Plasticising unit

Extrusion

die

Mould and

clamping unit

(4)

Dept. Polymer Engineering

University of Minho

Extrusion based process

Extrusion based process

(5)

Extrusion based process

Extrusion based process

(6)

Dept. Polymer Engineering

University of Minho

Extrusion based process

Extrusion based process

(7)

Extrusion based process

Extrusion based process

(8)

Dept. Polymer Engineering

University of Minho

Extrusion based process

Extrusion based process

(9)

Extrusion based process

Extrusion based process

(10)

Dept. Polymer Engineering

University of Minho

Extrusion based process:

(11)

Extrusion based process:

(12)

Dept. Polymer Engineering

University of Minho

Extrusion based process:

Extrusion based process: effect of sag and

effect of sag and

extrudate

extrudate

swell

swell

1 - swell and no sag

2 - sag and no swell

3 – sag plus swell

(13)

Extrusion based process:

(14)

Dept. Polymer Engineering

University of Minho

Extrusion based process:

(15)

Extrusion based process:

(16)

Dept. Polymer Engineering

University of Minho

Extrusion based process:

Extrusion based process:

transversal

transversal

pa

pa

rison

rison

thickness

thickness

programming

(17)

Extrusion based process:

Extrusion based process: extrusion with accumulator

extrusion with accumulator

(18)

Dept. Polymer Engineering

University of Minho

Extrusion based process:

(19)

Extrusion based process:

(20)

Dept. Polymer Engineering

University of Minho

Extrusion based process:

Extrusion based process: moulds

moulds

1

2

3

4

Types of ventilation systems

Capacity (l) Slit depth (mm)

>5 0.01-0.02

5-10 0.02-0.03

10-30 0.03-0.04

30-100 0.04-0.10

100-500 0.10-0.30

(21)

Extrusion based process:

Extrusion based process: moulds

moulds

(22)

Dept. Polymer Engineering

University of Minho

Extrusion based process:

Extrusion based process: moulds

moulds

Inflation

with needle

(23)

Extrusion based process:

Extrusion based process: moulds

moulds

Cooling system:

• Channels diameter (d):

6 ≤ d ≤ 20 mm

• Length: as short as possible (

T

exit

-T

entrance

≤5ºC

)

• Reduced number of curve zones

• Distance channel-cavity surface:

d

(24)

Dept. Polymer Engineering

University of Minho

Extrusion based process:

Extrusion based process: co

co-

-extrusion

extrusion

Permeability coefficients

Prices (relative to PVC)

HDPE

Adhesive

PA

Recycled HDPE

(25)

Extrusion based process:

(26)

Dept. Polymer Engineering

University of Minho

Injection moulding based process

Injection moulding based process

(27)

Injection moulding based process

Injection moulding based process

(28)

Dept. Polymer Engineering

University of Minho

Injection moulding based process

Injection moulding based process

Advantages

(29)

Injection moulding based process:

Injection moulding based process:

designing pre-

designing pre

-forms

forms

Espessuras tão pequenas

quanto possível

Razões de sopro elevadas

Machos cónicos (conicidade

mínima de 0.5º)

Variações de espessura por

maquinação da cavidade

Machos cilíndricos

Variações de espessura

por maquinação do macho

(30)

Dept. Polymer Engineering

University of Minho

Injection moulding based process:

Injection moulding based process:

sequence for designing

sequence for designing

pre

pre

-

-

forms

forms

1

– Desenho do contentor (conhecido) e do macho (diâmetro e

inclinação conhecidos)

2

– Selecção das secções transversais a dimensionar

3

– Determinação da espessura da pré-forma (balanço mássico)

nas secções seleccionadas no passo 2

4

– Representação das espessuras determinadas no passo 3 no

desenho

5

– Atenuação de transições bruscas de espessura

6

– Cálculo do volume da pré-forma

7

– Repetição dos passos 5 e 6 até se obter um volume de

pré-forma semelhante ao do contentor

(31)

Stretch blow moulding

Stretch blow moulding

Injection moulding

of the pre-form

Stretching

and blowing

Ejection of

the bottle

(32)

Dept. Polymer Engineering

University of Minho

Stretch blow moulding

Stretch blow moulding

(33)

Stretch blow moulding

Stretch blow moulding

(34)

Dept. Polymer Engineering

University of Minho

Stretch blow moulding

Stretch blow moulding

(35)

Stretch blow moulding:

Stretch blow moulding:

sequence of stretch and blowing

sequence of stretch and blowing

Wang et al., 1997

(36)

Dept. Polymer Engineering

University of Minho

Stretch blow moulding:

Stretch blow moulding:

sequence of stretch and blowing

sequence of stretch and blowing

Wang et al., 1997

(37)

Stretch blow moulding:

(38)

Dept. Polymer Engineering

University of Minho

Stretch blow moulding:

(39)

Carbonated drinks:

Carbonated drinks: permeability (CO

permeability (CO

2

2

)

)

Maximise ratio volume / surface area

Geometry

(40)

Dept. Polymer Engineering

University of Minho

Stretch blow moulding:

Stretch blow moulding:

typical processing parameters

typical processing parameters

(41)

Stretch blow moulding:

Stretch blow moulding:

crystallisation kinetics

crystallisation kinetics

Crystals cannot

form: molecules

are too sluggish

Crystals cannot

exist: molecules

are too energetic

Glassy

state

Rubbery

state

Melt

state

Temperature (ºC)

60

65

250

255

(42)

Dept. Polymer Engineering

University of Minho

Stretch blow moulding:

(43)

Stretch blow moulding:

(44)

Dept. Polymer Engineering

University of Minho

Stretch blow moulding:

Stretch blow moulding:

two stages versus one stage process

two stages versus one stage process

Advantages

Disadvantages

• Higher production rates

• Better pre-form temperature control

• Simpler bottle production (no need of

know-how on polymer processing )

• Higher global energy

consumption

(45)

Extrusion Blow

Extrusion Blow

-

-

Moulding:

Moulding:

Non

(46)

Dept. Polymer Engineering

University of Minho

Non

(47)

Non

Non

-

-

conventional techniques:

conventional techniques:

3D technique

3D technique

Battenfeld

Battenfeld

Fischer

Fischer

(48)

Dept. Polymer Engineering

University of Minho

3D Technique:

3D Technique: X

X-

-Y mould

Y mould

Placo

Placo

, Ltd

, Ltd

Parison

Cavity

(49)

Placo

Placo

, Ltd

, Ltd

3D Technique:

(50)

Dept. Polymer Engineering

University of Minho

3D Technique:

3D Technique: mould with vacuum

mould with vacuum

Battenfeld

(51)

Pre

Pre

-

-

blowing and moulds with moveable parts

blowing and moulds with moveable parts

Double

walled

container

(52)

Dept. Polymer Engineering University of Minho

Hollow

container with

re-entrant zone

Pre

(53)

Cycle time

Sequential co

Sequential co

-

-

extrusion

extrusion

Rigid

Rigid

Flexible

(54)

Dept. Polymer Engineering

University of Minho

Sequential co

Sequential co

-

-

extrusion

extrusion

Battenfeld

Battenfeld

Fischer

Fischer

Extruder 1

Extruder 2

Accumulator 1

Accumulator 2

Die flow channel 2

Die flow channel 1

(55)

Pressblower

References

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