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Hydrogen bonds and π–π inter­actions in two new crystalline phases of methyl­ene blue

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Figure

Figure 1
Figure 4
Figure 6Views of the stacking geometry of MB+ in compound (II): (i) displayed orthogonally to the stacking pillar axis by showing a tetramer of stackedmolecules; (ii) the same group of MB+ cations is shown along the stacking direction; (iii) view along the MB+ longer dimension, highlighting the nearlycompletely eclipsed superposition of the cations in the antiparallel columns.
Figure 7Hirshfeld fingerprint plots of compounds (exhibited byI) and (II) (above) and some relevant components (I.a–d and II.a–d), highlighting the main interactions MB+ in the respective solid phases.
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