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Constraining the sensitivity of iodide adduct chemical ionization mass spectrometry to multifunctional organic molecules using the collision limit and thermodynamic stability of iodide ion adducts

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Figure

Figure 1. An example of collision-limited sensitivity determinationof the ToF-CIMS. Top: the reagent ions and sum of total ions dur-ing the addition of high concentrations of 15N2O5 to the inlet of theToF-CIMS
Figure 2. A schematic of the voltages in the APi region of the Tofw-erk ToF-MS. The region of the mass spectrometer that we conductdeclustering scanning is between the skimmer (orange) and the en-trance to the second quadrupole (red)
Table 1. Compounds used to determine the relationship betweendV50% and binding enthalpy derived from quantum calculations(Iyer et al., 2016) at the DLPNO-CCSD(T)//PBE-aug-cc-pVTZ-PPlevel
Figure 4. The relationship between calculated binding enthalpy andcalculations have been performed (see Table 1)

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