Poly[[tri­aqua­(μ3 4 oxido­pyridine 2,6 di­carboxyl­ato)terbium(III)] monohydrate]

The Co II atom is coordinated by two TMB anions and two water molecules in the basal plane while another water mol- ecule bridges the Co II atoms in the axial directions, resulting in

Oxygen atoms of the water solvent molecules O8, O9, O10 were refined isotropically- O8 is statistically disordered with occupancy 1/2 and it position depends on the disorder of

In the crystal structure the manganese(III) cations are coordinated by four oxygen atoms of two symmetry related acetylacetone anions and two nitrogen atoms of an

One Cd II atom is six-coordinated by two O atoms from two ligand molecules and by four 3-OH groups in a distorted trigonal–prismatic geometry.. The other is five-coordinated by one

The coordinated water molecules and hydrogen phthalate anions are located between the repeated rhomboidal chains, and form hydrogen bonds with the coordinated water molecules..

In the title compound, the cadmium atom is six coordinated by two azide anions and three pyrazine-2-carboxylate (Fig. Each pyrazine-2-carboxylate bridges three cadmium atoms whereas

The Nd atom is coordinated by four O atoms from four 1,4-benzenedicarboxylate ligands and four O atoms from three succinate anions, in a distorted square-antiprismatic

The high coordination number arises from the bridging nature of the two water molecules, and also from bridging by carboxyl O atoms, which are themselves already bonded to a