Revision 6
SAFETY DATA SHEET
PAJ CONFORMAL COATING
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier
Product name PAJ CONFORMAL COATING
Product No. PAJ, EPAJ05L, ZE
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Conformal coating for appliance protection
Uses advised against At this moment in time we do not have information on use restrictions. They will be included in this safety data sheet when available
1.3. Details of the supplier of the safety data sheet
ELECTROLUBE. A division of HK WENTWORTH LTD
Supplier
ASHBY PARK, COALFIELD WAY,
ASHBY DE LA ZOUCH, LEICESTERSHIRE LE65 1JR
UNITED KINGDOM +44 (0)1530 419600 +44 (0)1530 416640 [email protected] 1.4. Emergency telephone number
+44 (0)1530 419600 between 8.30am - 5.00pm GMT Mon – Fri SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical
Hazards Flam. Liq. 3 - H226
Human health Acute Tox. 4 - H312;Acute Tox. 4 - H332;Skin Irrit. 2 - H315;Eye Irrit. 2 - H319
Environment Not classified.
Classification (1999/45/EEC) Xn;R20/21. Xi;R36/38. R10.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. 2.2. Label elements
Contains XYLENE
Label In Accordance With (EC) No. 1272/2008
Signal Word Warning
Hazard Statements
H319 Causes serious eye irritation. H332 Harmful if inhaled.
Precautionary Statements
P280 Wear protective gloves, eye and face protection.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P313 Get medical advice/attention.
Supplementary Precautionary Statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P261 Avoid breathing vapour/spray.
P332+313 If skin irritation occurs: Get medical advice/attention. 2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures XYLENE 30-60% CAS-No.: 1330-20-7 EC No.: 215-535-7 Classification (67/548/EEC) R10 Xn;R20/21 Xi;R38 Classification (EC 1272/2008) Flam. Liq. 3 - H226 Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Irrit. 2 - H315 BUTANOL-norm 5-10% CAS-No.: 71-36-3 EC No.: 200-751-6 Classification (67/548/EEC) R10 Xn;R22 Xi;R37/38,R41 R67 Classification (EC 1272/2008) Flam. Liq. 3 - H226 Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Eye Dam. 1 - H318 STOT SE 3 - H335 STOT SE 3 - H336
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
Ingredients not listed are classified as non-hazardous or at a concentration below reportable levels. SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical attention.
Ingestion
DO NOT INDUCE VOMITING! Rinse mouth thoroughly. Get medical attention immediately!
Skin contact
Wash the skin immediately with soap and water. Get medical attention if irritation persists after washing.
Eye contact
4.3. Indication of any immediate medical attention and special treatment needed Treat Symptomatically.
SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media
Extinguishing media
Fire can be extinguished using: Foam. Dry chemicals, sand, dolomite etc. 5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
Unusual Fire & Explosion Hazards
Aerosol cans may explode in a fire. May explode when heated or when exposed to flames or sparks. Vapours are heavier than air and may spread near ground to sources of ignition.
Specific hazards
Aerosol containers can explode when heated, due to excessive pressure build-up. 5.3. Advice for firefighters
Special Fire Fighting Procedures
Avoid breathing fire vapours. Cool containers exposed to flames with water until well after the fire is out.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet. 6.2. Environmental precautions
Do not discharge into drains, water courses or onto the ground. 6.3. Methods and material for containment and cleaning up
Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Clean-up personnel should use respiratory and/or liquid contact protection. Absorb in vermiculite, dry sand or earth and place into containers. 6.4. Reference to other sections
Wear protective clothing as described in Section 8 of this safety data sheet. See section 11 for additional information on health hazards. For waste disposal, see section 13.
SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling
Avoid spilling, skin and eye contact. Keep away from heat, sparks and open flame. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level.
7.2. Conditions for safe storage, including any incompatibilities
Flammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container.
Storage Class
Flammable compressed gas storage. 7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
STD TWA - 8 Hrs STEL - 15 Min Name Notes WEL 50 ppm(Sk) 154 mg/m3(Sk) BUTANOL-norm 50 ppm 220 mg/m3 WEL 100 ppm 441 mg/m3 XYLENE Sk
WEL = Workplace Exposure Limit. Sk = Can be absorbed through skin.
Ingredient Comments
WEL = Workplace Exposure Limits 8.2. Exposure controls
Protective equipment
Process conditions
Use engineering controls to reduce air contamination to permissible exposure level.
Engineering measures
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded.
Respiratory equipment
Respiratory protection must be used if air contamination exceeds acceptable level. In case of inadequate ventilation and work of brief duration, use suitable respiratory equipment. Use respiratory equipment with combination filter, type A2/P3. EN14387
Hand protection
Use suitable protective gloves if risk of skin contact. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material.
Eye protection
Wear approved, tight fitting safety glasses where splashing is probable.
Other Protection
Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly with soap & water if skin becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties
Appearance Liquid
Colour Colourless to pale yellow.
Odour Aromatic.
Solubility Immiscible with water
Initial boiling point and boiling range
(°C) 120 - 140 (248 - 284 F) Relative density 1.022 @ 20 °C (68 F)
Flash point (°C) 22 (71.6 F) Not noted.
Auto Ignition Temperature (°C) 500 9.2. Other information
SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity
There are no known reactivity hazards associated with this product. 10.2. Chemical stability
10.3. Possibility of hazardous reactions Not available.
Hazardous Polymerisation
Will not polymerise. 10.4. Conditions to avoid
Avoid heat. Avoid contact with oxidisers or reducing agents. 10.5. Incompatible materials
Materials To Avoid
Strong oxidising substances.
10.6. Hazardous decomposition products
Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
General information
Prolonged and repeated contact with solvents over a long period may lead to permanent health problems.
Inhalation
Vapours may cause headache, fatigue, dizziness and nausea. Vapour may irritate respiratory system or lungs.
Ingestion
Harmful if swallowed. Swallowing concentrated chemical may cause severe internal injury. May cause liver and/or renal damage.
Skin contact
Acts as a defatting agent on skin. May cause cracking of skin, and eczema. Prolonged or repeated exposure may cause severe irritation.
Eye contact
Irritating to eyes. Vapour or spray may cause temporary (reversible) eye damage.
Toxicological information on ingredients.
XYLENE (CAS: 1330-20-7)
Acute toxicity:
Acute Toxicity (Oral LD50)
3523 mg/kg Rat
Acute Toxicity (Dermal LD50)
12126 mg/kg Rabbit
Acute Toxicity (Inhalation LC50)
2700 mg/l (vapours) Rabbit 4 hours
Aspiration hazard: Inhalation
Harmful by inhalation. Upper respiratory irritation. Central nervous system depression. Vapours may cause drowsiness and dizziness.
Ingestion
Swallowing concentrated chemical may cause severe internal injury. May cause nausea, headache, dizziness and intoxication. Diarrhoea.
Skin contact
Harmful in contact with skin. Irritating to skin.
Eye contact
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Not regarded as dangerous for the environment.
Ecological information on ingredients.
XYLENE (CAS: 1330-20-7)
Ecotoxicity
The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
12.1. Toxicity
Ecological information on ingredients.
XYLENE (CAS: 1330-20-7)
Acute Toxicity - Aquatic Invertebrates
EC50 48 hours 1.0 mg/l Daphnia magna
Acute Toxicity - Aquatic Plants
IC50 72 hours 2.2 mg/l 12.2. Persistence and degradability
Degradability
There are no data on the degradability of this product.
Ecological information on ingredients.
XYLENE (CAS: 1330-20-7)
Degradability
The product is biodegradable. 12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.
Ecological information on ingredients.
XYLENE (CAS: 1330-20-7) Bioaccumulation factor BCF 25.9 Partition coefficient 3.2 12.4. Mobility in soil
Ecological information on ingredients.
XYLENE (CAS: 1330-20-7)
Mobility:
The product is insoluble in water. 12.5. Results of PBT and vPvB assessment
This product does not contain any PBT or vPvB substances.
Ecological information on ingredients.
XYLENE (CAS: 1330-20-7) Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
Ecological information on ingredients.
SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods
Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION
14.1. UN number
UN No. (ADR/RID/ADN) 1263
UN No. (IMDG) 1263
UN No. (ICAO) 1263
14.2. UN proper shipping name
Proper Shipping Name PAINT 14.3. Transport hazard class(es)
ADR/RID/ADN Class 3
ADR/RID/ADN Class Class 3: Flammable liquids.
ADR Label No. 3
IMDG Class 3 ICAO Class/Division 3 Transport Labels FLAMMABLE LIQUID
3
14.4. Packing groupADR/RID/ADN Packing group III
IMDG Packing group III
ICAO Packing group III
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
EMS F-E, S-E
Emergency Action Code •3Y
Hazard No. (ADR) 30
Tunnel Restriction Code (D/E)
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code No information required.
SECTION 15: REGULATORY INFORMATION
Statutory Instruments
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health.
Guidance Notes
Workplace Exposure Limits EH40.
EU Legislation
Commission Directive 2000/39/EC of 8 June 2000 establishing a first list of indicative occupational exposure limit values in implementation of Council Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work.
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC,
93/105/EC and 2000/21/EC, including amendments.
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.
Authorisations (Title VII Regulation 1907/2006)
No specific authorisations are noted for this product.
Restrictions (Title VIII Regulation 1907/2006)
No specific restrictions of use are noted for this product. 15.2. Chemical Safety Assessment
No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION
Issued By Helen O'Reilly
Revision Date APRIL 2013
Revision 6
SDS No. 10536
Risk Phrases In Full
Flammable. R10
Harmful by inhalation and in contact with skin. R20/21
Harmful if swallowed. R22
Irritating to eyes and skin. R36/38
Irritating to respiratory system and skin. R37/38
Irritating to skin. R38
Risk of serious damage to eyes. R41
Vapours may cause drowsiness and dizziness. R67
Hazard Statements In Full
Flammable liquid and vapour. H226
Harmful if swallowed. H302
Harmful in contact with skin. H312
Causes skin irritation. H315
Causes serious eye damage. H318
Causes serious eye irritation. H319
Harmful if inhaled. H332
May cause respiratory irritation. H335
May cause drowsiness or dizziness. H336
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