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The Phonon Thermodynamics of Iron and Cementite

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Figure

Figure 1.1: The Fe-C phase diagram, maps all stable phases with blue regions. This figure wasconstructed using the 1992 phase diagram developed by Okamoto, et
Figure 1.2: The free energy of bcc (α-Fe) and fcc (γ-Fe) extracted from calorimetry measurements[7].
Figure 2.1: Phonon dispersions from triple-axis inelastic neutron scatter (points), overlaid withBorn-von K´arm´an model fits and the resulting phonon density of states shown on the right [12].
Figure 3.4: The temperature-dependent Gr¨uneisen parameter γTture values. BlackRed γT(T) from K γTT [28, 29],(T) from α K [25],TD CV from 14K NRIXS measurements, andV from a Debye model (Θ �� [28, 30], α [22], C(T) assembled from various litera-=420K), and
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