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25 5 AApprriil l 22000011 EEsstteerra a TToommuulleett 11

 Ethanol 

 Ethanol 

(2)

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25 5 AApprriil l 22000011 EEsstteerra a TToommuulleett 22

 Pro

 Pro

perties

perties

 

 

 Also re

 Also referre

ferre

d to as ethyl alcohol 

d to as ethyl alcohol 

 

 

 It’

 It’

s

s

chemical formul

chemical formula: CH 

a: CH 

33

CH 

CH 

22

OH 

OH 

 

 

 Molecular W

 Molecular W

e

e

iht: !"#$%rams

iht: !"#$%rams

 

 

 Ethanol is an alcohol

 Ethanol is an alcohol

& has a & has a hydro'yl rohydro'yl roup( an up( an )OH)OH

*onded to a car*on atom+#

*onded to a car*on atom+#

 

 

 Is a clear

 Is a clear

(

(

colorless li,uid -ith sliht od

colorless li,uid -ith sliht odor 

or 

 

 

 In dilute a,ueous solution( has r

 In dilute a,ueous solution( has relati.e

elati.e

ly s-eet

ly s-eet

 fla.or

 fla.or(

(

*ut -hen concentrated

*ut -hen concentrated

( it has a *urnin

( it has a *urnin

taste#

(3)

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25 5 AApprriil l 22000011 EEsstteerra a TToommuulleett 33

 Pro

 Pro

perties

perties

&continued+

&continued+

 

 

 Meltin point of 

 Meltin point of 

)//!#/ derees Celsius

)//!#/ derees Celsius

 

 

 0oilin point of %1# derees Celsius

 0oilin point of %1# derees Celsius

 

 

 3ensity of $#%415m6 at 2$ derees Celsius

 3ensity of $#%415m6 at 2$ derees Celsius

 

 

 7ta*le *ut hihly flamma*le

 7ta*le *ut hihly flamma*le

 

 

 Incompati*le -ith acids( al8ali metals(

 Incompati*le -ith acids( al8ali metals(

moisture

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25 5 AApprriil l 22000011 EEsstteerra a TToommuulleett 44

9ses of Ethanol

9ses of Ethanol

 

 

9sed as thermometer

9sed as thermometer

 for temp#’

 for temp#’

s

s

*elo- H’

*elo- H’

s

s

 fre

 fre

ein point

ein point

&)!$ derees&)!$ derees Celsius+

Celsius+

 

 

9sed as antifreee in

9sed as antifreee in

automo*ile radiators

automo*ile radiators

 

 

9sed to ma8e se.eral

9sed to ma8e se.eral

types of alcohol

types of alcohol

&such as&such as -his8y and *randy+

-his8y and *randy+

 

 

9sed to *urn in

9sed to *urn in

automo*ile enines li8e

automo*ile enines li8e

 asoline

 asoline

 Ethanol can *e mi'ed  Ethanol can *e mi'ed -ith asoline &/:4+ to -ith asoline &/:4+ to help reduce air

help reduce air  pollution) CO is  pollution) CO is

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25 5 AApprriil l 22000011 EEsstteerra a TToommuulleett 55

;he Alcohol Part

;he Alcohol Part

 

 

 Made since ancient

 Made since ancient times *y fermentat

times *y fermentation of

ion of

 suars &*e.erae ethanol is sti

 suars &*e.erae ethanol is still made *y this

ll made *y this

 pro

 pro

cess:

cess:

 simple suars ar simple suars are the ra- e the ra- material( and <ymase material( and <ymase anan enyme from yeast( chanes the simple suars into

enyme from yeast( chanes the simple suars into ethanol and car*onethanol and car*on dio'ide *y this r'n:

dio'ide *y this r'n:

 +

 +

 

 

 H 

 H 

/2/2

O

O

""

)))=

)))=

2 CH 

2 CH 

33

CH 

CH 

22

OH > 2 CO

OH > 2 CO

22

 

 

 ?eaction is comple'

 ?eaction is comple' *ecause impur

*ecause impure cu

e cu

lture

lture

s of

s of

 yeast pro

 yeast pro

duce other su*stances and .a

duce other su*stances and .arious

rious

other

other

oranic

oranic acids

acids

&in the production of *e.eraes( such&in the production of *e.eraes( such as -his8y and *randy( the impurities *rin a*out fla.or+

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25 5 AApprriil l 22000011 EEsstteerra a TToommuulleett 66

;he Alcohol Part

;he Alcohol Part

&continued+

&continued+

 

 

7ince ethanol is to'ic(

7ince ethanol is to'ic(

the *ody

the *ody

disposes of it immediately

disposes of it immediately

 

 

 Ethanol acts as a depre

 Ethanol acts as a depressant that

ssant that

affects the central ner.ous

affects the central ner.ous

 system and suppre

 system and suppre

sses certain

sses certain

*rain functions

*rain functions

Classic symptoms of into'ication include: slurredClassic symptoms of into'ication include: slurred

 speech( unsteady -al8( ina*ility to re

 speech( unsteady -al8( ina*ility to react ,uic8lyact ,uic8ly( etc#( etc#

• Ho-e.er Ho-e.er( ( moderate amounts of alcoholmoderate amounts of alcohol

 stimulate the mind and re

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25 5 AApprriil l 22000011 EEsstteerra a TToommuulleett 77

 Ethanol in the 0rain

 Ethanol in the 0rain

 

 

 Ethanol affects neur

 Ethanol affects neur

otransmitte

otransmitters in the *rain#

rs in the *rain#

 

 

One neurotransmit

One neurotransmit

ter is

ter is

amma)amino*utyric acid

amma)amino*utyric acid

&@A0A+

&@A0A+

(8)

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25 5 AApprriil l 22000011 EEsstteerra a TToommuulleett 88

 Pro

 Pro

duction

duction

 

 

;hree main processes for the manufacture of

;hree main processes for the manufacture of

ethanol:

ethanol:

  fermentation of car*ohydrates &transformation of fermentation of car*ohydrates &transformation of

car*ohydrates s to ethanol *y ro-in yeast cells+

car*ohydrates s to ethanol *y ro-in yeast cells+

 hydration of ethylene &achie.ed *y passin a mi'ture ofhydration of ethylene &achie.ed *y passin a mi'ture of

ethylene and a lare e'cess of steam+) most

ethylene and a lare e'cess of steam+) most commoncommon

 process used in 97A

 process used in 97A today &%$ to 4$ perctoday &%$ to 4$ percent+ent+

 reduction of acetylene &achie.ed *y hydration ofreduction of acetylene &achie.ed *y hydration of

acetylene+

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25 5 AApprriil l 22000011 EEsstteerra a TToommuulleett 99

 Pro

 Pro

duction

duction

&continued+

&continued+

 

 

 0ecause ther

 0ecause there is a

e is a ta' in all countries on t

ta' in all countries on the

he

 pro

 pro

duction of ethyl al

duction of ethyl alcohol for *e.erae purposes(

cohol for *e.erae purposes(

the ethyl alcohol that is used for

the ethyl alcohol that is used for industrial purposes

industrial purposes

must *e rendered unfit to drin8 &denatured+ to

must *e rendered unfit to drin8 &denatured+ to

escape ta'ation#

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25 5 AApprriil l 22000011 EEsstteerra a TToommuulleett 1100

 ANY QUESTIONS?  ANY QUESTIONS?

References

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