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Safety Data Sheet

Copyright,2015,3M Company.

All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 28-1029-9 Version Number: 2.01

Issue Date: 03/02/15 Supercedes Date: 02/21/14

Product identifier

3M™ EZ Sand Multi-Purpose Repair Material PNs 05887 35887, 55887 ID Number(s): LB-K100-0909-2, 41-0003-6760-1, 41-0003-7957-2, 41-0003-7997-8, 60-4550-5209-6, 60-4550-5482-9, 60-4550-7033-8, 60-9801-0922-1 Recommended use Automotive Supplier's details MANUFACTURER: 3M

DIVISION: Automotive Aftermarket

ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) Emergency telephone number

1-800-364-3577 or (651) 737-6501 (24 hours)

This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included. Please do not separate the component documents from this cover page. The document numbers for components of this product are:

28-6974-1, 28-6979-0

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M

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Safety Data Sheet

SECTION 1: Identification

1.1. Product identifier

3M™ EZ Sand Multi-Purpose Repair Material PNs 05887, 35887, 55887 - Part B (Base)

1.2. Recommended use and restrictions on use Recommended use

Automotive, Flexible Parts Repair 1.3. Supplier’s details

MANUFACTURER: 3M

ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number

1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification

The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies.

2.1. Hazard classification

Serious Eye Damage/Irritation: Category 2B. Skin Sensitizer: Category 1.

Carcinogenicity: Category 1A.

Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements

Signal word Danger Symbols

Exclamation mark | Health Hazard | Pictograms

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Hazard Statements Causes eye irritation.

May cause an allergic skin reaction. May cause cancer.

Causes damage to organs through prolonged or repeated exposure: respiratory system |

Precautionary Statements General:

Keep out of reach of children. Prevention:

Obtain special instructions before use.

Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray.

Wear protective gloves.

Do not eat, drink or smoke when using this product. Wash thoroughly after handling.

Contaminated work clothing must not be allowed out of the workplace. Response:

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water.

If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse.

Get medical advice/attention if you feel unwell. Storage:

Store locked up. Disposal:

Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified

None.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt

Bisphenol A-Epichlorohydrin Polymer 25068-38-6 20 - 50 Trade Secret *

Talc 14807-96-6 10 - 30 Trade Secret *

Limestone 1317-65-3 10 - 30 Trade Secret *

1,2,3-Propanetriyl Ester of 12-(Oxiranylmethoxy)-9-Octadecenoic Acid

74398-71-3 5 - 15 Trade Secret * Oxide Glass Chemicals 65997-17-3 1 - 10 Trade Secret *

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Stearic Acid 57-11-4 < 1.5 Trade Secret * Quartz Silica 14808-60-7 < 0.5 Trade Secret *

Carbon Black 1333-86-4 < 0.09 Trade Secret *

Epichlorohydrin 106-89-8 < 0.011 Trade Secret *

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:

Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact:

Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.

Eye Contact:

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.

If Swallowed:

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required Not applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media

In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

Aldehydes During Combustion

Carbon monoxide During Combustion

Carbon dioxide During Combustion

Hydrogen Chloride During Combustion

5.3. Special protective actions for fire-fighters

No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

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Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Use personal protective equipment (gloves,

respirators, etc.) as required.

7.2. Conditions for safe storage including any incompatibilities

Keep container tightly closed. Store away from heat. Store away from acids.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component.

Ingredient C.A.S. No. Agency Limit type Additional Comments

Epichlorohydrin 106-89-8 ACGIH TWA:0.5 ppm A3: Confirmed animal carcin., Skin Notation Epichlorohydrin 106-89-8 OSHA TWA:19 mg/m3(5 ppm) Skin Notation

Limestone 1317-65-3 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3

Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3

A3: Confirmed animal carcin.

Carbon Black 1333-86-4 CMRG TWA:0.5 mg/m3 Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3

Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3

A4: Not class. as human carcin

Talc 14807-96-6 CMRG TWA(as respirable dust):0.5 mg/m3

Talc 14807-96-6 OSHA TWA concentration(as total dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.);TWA:20 millions of particles/cu. ft. Quartz Silica 14808-60-7 ACGIH TWA(respirable

fraction):0.025 mg/m3

A2: Suspected human carcin.

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dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.)

STEARATES 57-11-4 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin

Oxide Glass Chemicals 65997-17-3 Manufacturer determined

TWA(as dust):10 mg/m3

Filler Mixture CMRG CEIL:5 mg/m3

SILICA, AMORPHOUS Mixture OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft.

ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association

CMRG : Chemical Manufacturer's Recommended Guidelines

OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average

STEL: Short Term Exposure Limit CEIL: Ceiling

8.2. Exposure controls 8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Provide appropriate local exhaust ventilation for cutting, grinding, sanding or machining.

8.2.2. Personal protective equipment (PPE) Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended:

Indirect Vented Goggles Skin/hand protection

Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing.

Gloves made from the following material(s) are recommended: Polymer laminate

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:

Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer.

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9.1. Information on basic physical and chemical properties

General Physical Form: Solid

Specific Physical Form: Paste

Odor, Color, Grade: Black, with little odor

Odor threshold No Data Available

pH Not Applicable

Melting point No Data Available

Boiling Point Not Applicable

Evaporation rate No Data Available

Flammability (solid, gas) Not Classified

Flammable Limits(LEL) Not Applicable

Flammable Limits(UEL) Not Applicable

Vapor Pressure No Data Available

Vapor Density No Data Available

Density 1.0 - 1.5 g/ml

Specific Gravity 1.0 - 1.5 [Ref Std: WATER=1]

Solubility in Water Nil

Partition coefficient: n-octanol/ water No Data Available

Autoignition temperature No Data Available

Decomposition temperature No Data Available

Viscosity 40 - 110 sec [Details: Pressflow Viscosity]

Hazardous Air Pollutants 0.00024 lb HAPS/lb solids [Test Method: Calculated]

Molecular weight No Data Available

Volatile Organic Compounds 1 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 0.1 % weight [Test Method: calculated per CARB title 2]

Percent volatile 0.1 % weight

VOC Less H2O & Exempt Solvents 1 g/l [Test Method: calculated SCAQMD rule 443.1]

SECTION 10: Stability and reactivity

10.1. Reactivity

This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid

Heat

10.5. Incompatible materials Strong acids

10.6. Hazardous decomposition products

Phosgene Not Specified

Toxic Vapor, Gas, Particulate Not Specified Refer to section 5.2 for hazardous decomposition products during combustion.

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SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.

11.1. Information on Toxicological effects Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects: Inhalation:

Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

May cause additional health effects (see below). Skin Contact:

Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:

Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion:

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Additional Health Effects:

Prolonged or repeated exposure may cause target organ effects:

Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests.

Carcinogenicity:

Contains a chemical or chemicals which can cause cancer.

Ingredient CAS No. Class Description Regulation

Carbon Black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Epichlorohydrin 106-89-8 Grp. 2A: Probable human carc. International Agency for Research on Cancer Epichlorohydrin 106-89-8 Anticipated human carcinogen National Toxicology Program Carcinogens Quartz Silica 14808-60-7 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg

Bisphenol A-Epichlorohydrin Polymer Dermal Rat LD50 > 1,600 mg/kg Bisphenol A-Epichlorohydrin Polymer Ingestion Rat LD50 > 1,000 mg/kg

Talc Dermal LD50 estimated to be > 5,000 mg/kg

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Limestone Dermal Rat LD50 > 2,000 mg/kg

Limestone

Inhalation-Dust/Mist (4 hours)

Rat LC50 3 mg/l

Limestone Ingestion Rat LD50 6,450 mg/kg

1,2,3-Propanetriyl Ester of 12-(Oxiranylmethoxy)-9-Octadecenoic Acid

Dermal Rabbit LD50 > 2,000 mg/kg 1,2,3-Propanetriyl Ester of

12-(Oxiranylmethoxy)-9-Octadecenoic Acid

Ingestion Rat LD50 > 5,000 mg/kg

Oxide Glass Chemicals Dermal LD50 estimated to be > 5,000 mg/kg

Oxide Glass Chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg

Filler Dermal Rabbit LD50 > 5,000 mg/kg

Filler

Rat LC50 > 0.691 mg/l

Filler Ingestion Rat LD50 > 5,110 mg/kg

Stearic Acid Dermal Rabbit LD50 > 2,000 mg/kg

Stearic Acid Ingestion Rat LD50 > 5,000 mg/kg

Quartz Silica Dermal LD50 estimated to be > 5,000 mg/kg

Quartz Silica Ingestion LD50 estimated to be > 5,000 mg/kg

Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg

Carbon Black Ingestion Rat LD50 > 8,000 mg/kg

Epichlorohydrin Dermal Rabbit LD50 755 mg/kg

Epichlorohydrin

Inhalation-Vapor (4 hours)

Rat LC50 1.7 mg/l

Epichlorohydrin Ingestion Rat LD50 260 mg/kg

ATE = acute toxicity estimate Skin Corrosion/Irritation

Name Species Value

Bisphenol A-Epichlorohydrin Polymer Rabbit Mild irritant

Talc Rabbit No significant irritation

Limestone Rabbit No significant irritation

Oxide Glass Chemicals Professio

nal judgeme nt

No significant irritation

Filler Rabbit No significant irritation

Stearic Acid Rabbit Mild irritant

Quartz Silica Professio

nal judgeme nt

Carbon Black Rabbit No significant irritation

Epichlorohydrin Human

and animal

Corrosive

Serious Eye Damage/Irritation

Bisphenol A-Epichlorohydrin Polymer Rabbit Moderate irritant

nal judgeme nt

Filler Rabbit No significant irritation

Stearic Acid Professio

nal judgeme

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nt

Carbon Black Rabbit No significant irritation

Epichlorohydrin Rabbit Corrosive

Skin Sensitization

Bisphenol A-Epichlorohydrin Polymer Human

and animal Sensitizing Filler Human and animal Not sensitizing Epichlorohydrin Human and animal Sensitizing Respiratory Sensitization

Bisphenol A-Epichlorohydrin Polymer Human Some positive data exist, but the data are not sufficient for classification

Talc Human Not sensitizing

Germ Cell Mutagenicity

Name Route Value

Bisphenol A-Epichlorohydrin Polymer In vivo Not mutagenic

Bisphenol A-Epichlorohydrin Polymer In Vitro Some positive data exist, but the data are not sufficient for classification

Talc In Vitro Not mutagenic

Talc In vivo Not mutagenic

Oxide Glass Chemicals In Vitro Some positive data exist, but the data are not sufficient for classification

Filler In Vitro Not mutagenic

Stearic Acid In Vitro Not mutagenic

Quartz Silica In Vitro Some positive data exist, but the data are not

sufficient for classification

Quartz Silica In vivo Some positive data exist, but the data are not

Carbon Black In Vitro Not mutagenic

Carbon Black In vivo Some positive data exist, but the data are not

Epichlorohydrin In Vitro Some positive data exist, but the data are not

Epichlorohydrin In vivo Mutagenic

Carcinogenicity

Bisphenol A-Epichlorohydrin Polymer Dermal Mouse Some positive data exist, but the data are not sufficient for classification

Talc Inhalation Rat Some positive data exist, but the data are not

Oxide Glass Chemicals Inhalation Multiple

animal species

Some positive data exist, but the data are not sufficient for classification

Filler Not

Specified

Mouse Some positive data exist, but the data are not sufficient for classification

Stearic Acid Ingestion Rat Not carcinogenic

Quartz Silica Inhalation Human

and animal

Carcinogenic

Carbon Black Dermal Mouse Not carcinogenic

Carbon Black Ingestion Mouse Not carcinogenic

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Epichlorohydrin Dermal Mouse Not carcinogenic

Epichlorohydrin Ingestion Rat Carcinogenic

Epichlorohydrin Inhalation Rat Carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test Result Exposure

Duration Bisphenol A-Epichlorohydrin Polymer Ingestion Not toxic to female reproduction Rat NOAEL 750

mg/kg/day

2 generation Bisphenol A-Epichlorohydrin Polymer Ingestion Not toxic to male reproduction Rat NOAEL 750

mg/kg/day

2 generation Bisphenol A-Epichlorohydrin Polymer Dermal Not toxic to development Rabbit NOAEL 300

mg/kg/day

during organogenesi s

Bisphenol A-Epichlorohydrin Polymer Ingestion Not toxic to development Rat NOAEL 750 mg/kg/day

2 generation

Talc Ingestion Not toxic to development Rat NOAEL 1,600

mg/kg

Limestone Ingestion Not toxic to development Rat NOAEL 625

mg/kg/day

premating & during gestation

Filler Ingestion Not toxic to female reproduction Rat NOAEL 509

mg/kg/day

1 generation

Filler Ingestion Not toxic to male reproduction Rat NOAEL 497

mg/kg/day

1 generation

Filler Ingestion Not toxic to development Rat NOAEL 1,350

mg/kg/day

Epichlorohydrin Inhalation Not toxic to female reproduction Rat NOAEL 0.2 mg/l

10 weeks

Epichlorohydrin Inhalation Not toxic to development Multiple

animal species NOAEL 0.09 mg/l during organogenesi s

Epichlorohydrin Ingestion Some positive developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL 160 mg/kg/day during gestation

Epichlorohydrin Ingestion Toxic to male reproduction Rat LOAEL 6.25

mg/kg/day

23 days

Epichlorohydrin Inhalation Toxic to male reproduction Rat NOAEL 0.02

mg/l

10 weeks

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test Result Exposure

Duration Limestone Inhalation respiratory system All data are negative Rat NOAEL

0.812 mg/l

90 minutes Stearic Acid Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for classification

NOAEL Not available Epichlorohydrin Inhalation respiratory irritation May cause respiratory irritation Human NOAEL not

available

occupational exposure Epichlorohydrin Inhalation liver Some positive data exist, but the

Human NOAEL not available

occupational exposure

Specific Target Organ Toxicity - repeated exposure

Duration Bisphenol

A-Epichlorohydrin Polymer

Dermal liver Some positive data exist, but the data are not sufficient for

Rat NOAEL

1,000

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classification mg/kg/day Bisphenol

Dermal nervous system All data are negative Rat NOAEL 1,000 mg/kg/day

13 weeks

Bisphenol

All data are negative Rat NOAEL 1,000 mg/kg/day

28 days

Talc Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure

Human NOAEL Not available

occupational exposure Talc Inhalation pulmonary fibrosis |

respiratory system

Rat NOAEL 18

mg/m3

113 weeks

Limestone Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification

occupational exposure Oxide Glass Chemicals Inhalation respiratory system Some positive data exist, but the

Human NOAEL not available

occupational exposure Filler Inhalation respiratory system |

silicosis

All data are negative Human NOAEL Not available

occupational exposure Stearic Acid Ingestion blood Some positive data exist, but the

Rat NOAEL Not

available

6 weeks

Quartz Silica Inhalation silicosis Causes damage to organs through prolonged or repeated exposure

occupational exposure Carbon Black Inhalation pneumoconiosis Some positive data exist, but the

occupational exposure Epichlorohydrin Inhalation liver Causes damage to organs through

prolonged or repeated exposure

Rat NOAEL 0.21 mg/l

19 days Epichlorohydrin Inhalation kidney and/or

bladder

May cause damage to organs though prolonged or repeated exposure

Rat NOAEL 0.04 mg/l

136 weeks

Epichlorohydrin Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification

Rat NOAEL

0.377 mg/l

4 weeks

Epichlorohydrin Inhalation immune system Some positive data exist, but the data are not sufficient for classification

Rat LOAEL

0.211 mg/l

4 weeks

Epichlorohydrin Inhalation heart Some positive data exist, but the data are not sufficient for classification

Rat NOAEL 0.02 mg/l

98 days

Epichlorohydrin Inhalation nervous system Some positive data exist, but the data are not sufficient for classification

Rat NOAEL

0.002 mg/l

98 days

Epichlorohydrin Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.02 mg/l 13 weeks

Epichlorohydrin Inhalation blood All data are negative Rat NOAEL

0.189 mg/l

90 days Epichlorohydrin Ingestion heart | blood Some positive data exist, but the

Rat NOAEL 80

mg/kg/day

12 weeks

Epichlorohydrin Ingestion liver Some positive data exist, but the data are not sufficient for classification

Rat NOAEL 25

mg/kg/day

90 days

Aspiration Hazard

For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.

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SECTION 12: Ecological information

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components.

Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methods

Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the

respective regulating authorities to determine the available treatment and disposal facilities.

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations

Contact 3M for more information. 311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed Hazard - Yes

15.2. State Regulations

Contact 3M for more information. California Proposition 65

Ingredient C.A.S. No. Classification

SILICA, CRYSTALLINE (AIRBORNE PARTICLES OF RESPIRABLE SIZE)

None Carcinogen

Epichlorohydrin 106-89-8 Male reproductive toxin

Epichlorohydrin 106-89-8 Carcinogen

WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm.

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15.3. Chemical Inventories

The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information.

15.4. International Regulations

Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard Classification

Health: 2 Flammability: 1 Instability: 1 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar

emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

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Safety Data Sheet

SECTION 1: Identification

1.1. Product identifier

3M™ EZ Sand Multi-Purpose Repair Material PNs 05887, 35887, 55887 - Accelerator (Part A)

1.2. Recommended use and restrictions on use Recommended use

Automotive, Part A side of 2-Part Epoxy Adhesive for Flexible Parts Repair 1.3. Supplier’s details

MANUFACTURER: 3M

ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number

1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification

The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies.

2.1. Hazard classification

Serious Eye Damage/Irritation: Category 1. Skin Corrosion/Irritation: Category 2. Carcinogenicity: Category 1A.

Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements

Signal word Danger Symbols

Corrosion | Health Hazard | Pictograms

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Hazard Statements Causes serious eye damage. Causes skin irritation. May cause cancer.

Causes damage to organs through prolonged or repeated exposure: respiratory system |

Precautionary Statements General:

Keep out of reach of children. Prevention:

Obtain special instructions before use.

Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray.

Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.

Response:

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Get medical advice/attention if you feel unwell.

Storage: Store locked up. Disposal:

Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified

None.

65% of the mixture consists of ingredients of unknown acute oral toxicity. 65% of the mixture consists of ingredients of unknown acute dermal toxicity.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt

Mercaptan-Terminated Epoxy Curing Agent Trade Secret* 40 - 70 Trade Secret *

Talc 14807-96-6 10 - 30 Trade Secret *

Limestone 1317-65-3 10 - 30 Trade Secret *

Oxide Glass Chemicals 65997-17-3 1 - 10 Trade Secret * Tris(2,4,6-Dimethylaminomonomethyl)Phenol 90-72-2 1 - 5 Trade Secret *

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Titanium Dioxide 13463-67-7 < 1.0 Trade Secret * Quartz Silica 14808-60-7 < 0.5 Trade Secret *

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:

Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact:

Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.

Eye Contact:

Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention.

If Swallowed:

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required Not applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media

In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Carbon monoxide During Combustion

Carbon dioxide During Combustion

Oxides of Nitrogen During Combustion

Oxides of Sulfur During Combustion

Toxic Vapor, Gas, Particulate During Combustion

5.3. Special protective actions for fire-fighters

No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

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to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Clean up residue. Seal the container. Dispose of collected material as soon as possible.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities

Keep container tightly closed. Store away from heat. Store away from acids. Store away from oxidizing agents.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component.

Ingredient C.A.S. No. Agency Limit type Additional Comments

Limestone 1317-65-3 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3

Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin

Titanium Dioxide 13463-67-7 CMRG TWA(as respirable dust):5 mg/m3

Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3 Talc 14807-96-6 ACGIH TWA(respirable fraction):2

mg/m3

A4: Not class. as human carcin

Talc 14807-96-6 CMRG TWA(as respirable dust):0.5 mg/m3

Talc 14807-96-6 OSHA TWA concentration(as total dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.);TWA:20 millions of particles/cu. ft. Quartz Silica 14808-60-7 ACGIH TWA(respirable

fraction):0.025 mg/m3

A2: Suspected human carcin.

Quartz Silica 14808-60-7 OSHA TWA concentration(as total dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of

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particles/cu. ft.) Oxide Glass Chemicals 65997-17-3 Manufacturer

determined TWA(as dust):10 mg/m3 Tris(2,4,6-Dimethylaminomonomethyl)Phen ol 90-72-2 CMRG TWA:5 ppm

ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association

CMRG : Chemical Manufacturer's Recommended Guidelines

OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average

STEL: Short Term Exposure Limit CEIL: Ceiling

8.2. Exposure controls 8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Provide appropriate local exhaust ventilation for cutting, grinding, sanding or machining.

8.2.2. Personal protective equipment (PPE) Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended:

Full Face Shield Indirect Vented Goggles Skin/hand protection

Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing.

Gloves made from the following material(s) are recommended: Butyl Rubber Nitrile Rubber

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:

Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

General Physical Form: Solid

Specific Physical Form: Paste

Odor, Color, Grade: Off-white, strong mercaptan odor

Odor threshold No Data Available

pH Not Applicable

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Boiling Point Not Applicable

Flash Point 474 ºF

Flammability (solid, gas) Not Classified

Flammable Limits(LEL) Not Applicable

Flammable Limits(UEL) Not Applicable

Vapor Pressure No Data Available

Vapor Density No Data Available

Density 8.8 - 9.4 lb/gal

Specific Gravity 1.078 - 1.09 [Ref Std: WATER=1]

Solubility In Water No Data Available

Solubility- non-water No Data Available

Partition coefficient: n-octanol/ water No Data Available

Autoignition temperature No Data Available

Decomposition temperature No Data Available

Viscosity 100 - 150 sec [Details: Pressflow Viscosity]

Hazardous Air Pollutants 0.00024 lb HAPS/lb solids [Test Method: Calculated]

Molecular weight No Data Available

Volatile Organic Compounds 1 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 0.1 % weight [Test Method: calculated per CARB title 2]

Percent volatile 0.1 % weight

VOC Less H2O & Exempt Solvents 1 g/l [Test Method: calculated SCAQMD rule 443.1]

SECTION 10: Stability and reactivity

10.1. Reactivity

This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid

None known.

10.5. Incompatible materials None known.

10.6. Hazardous decomposition products

None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.

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11.1. Information on Toxicological effects Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects: Inhalation:

Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

May cause additional health effects (see below). Skin Contact:

Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Eye Contact:

Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision.

Ingestion:

May be harmful if swallowed.

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Additional Health Effects:

Prolonged or repeated exposure may cause target organ effects:

Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests.

Carcinogenicity:

Contains a chemical or chemicals which can cause cancer.

Ingredient CAS No. Class Description Regulation

Quartz Silica 14808-60-7 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.

Acute Toxicity

Overall product Dermal No data available; calculated ATE > 5,000 mg/kg

Overall product Ingestion No data available; calculated ATE 2,000 - 5,000

mg/kg

Talc Dermal LD50 estimated to be > 5,000 mg/kg

Talc Ingestion LD50 estimated to be > 5,000 mg/kg

Limestone Dermal Rat LD50 > 2,000 mg/kg

Limestone

Rat LC50 3 mg/l

Limestone Ingestion Rat LD50 6,450 mg/kg

Oxide Glass Chemicals Dermal LD50 estimated to be > 5,000 mg/kg

Oxide Glass Chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg

Tris(2,4,6-Dimethylaminomonomethyl)Phenol Dermal Rat LD50 1,280 mg/kg Tris(2,4,6-Dimethylaminomonomethyl)Phenol Ingestion Rat LD50 1,000 mg/kg

Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg

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Dust/Mist (4 hours)

Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg

Quartz Silica Dermal LD50 estimated to be > 5,000 mg/kg

Quartz Silica Ingestion LD50 estimated to be > 5,000 mg/kg

ATE = acute toxicity estimate Skin Corrosion/Irritation

nal judgeme nt

Tris(2,4,6-Dimethylaminomonomethyl)Phenol Rabbit Corrosive

Titanium Dioxide Rabbit No significant irritation

Quartz Silica Professio

nal judgeme nt

Serious Eye Damage/Irritation

nal judgeme nt

Tris(2,4,6-Dimethylaminomonomethyl)Phenol Rabbit Corrosive

Titanium Dioxide Rabbit No significant irritation

Skin Sensitization

Tris(2,4,6-Dimethylaminomonomethyl)Phenol Guinea

pig

Titanium Dioxide Human

and animal

Not sensitizing

Respiratory Sensitization

Talc Human Not sensitizing

Germ Cell Mutagenicity

Name Route Value

Talc In Vitro Not mutagenic

Talc In vivo Not mutagenic

Oxide Glass Chemicals In Vitro Some positive data exist, but the data are not sufficient for classification

Tris(2,4,6-Dimethylaminomonomethyl)Phenol In Vitro Not mutagenic

Titanium Dioxide In Vitro Not mutagenic

Titanium Dioxide In vivo Not mutagenic

Quartz Silica In Vitro Some positive data exist, but the data are not

Quartz Silica In vivo Some positive data exist, but the data are not

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Carcinogenicity

Talc Inhalation Rat Some positive data exist, but the data are not

Oxide Glass Chemicals Inhalation Multiple

animal species

Titanium Dioxide Ingestion Multiple

animal species

Not carcinogenic

Titanium Dioxide Inhalation Rat Carcinogenic

Quartz Silica Inhalation Human

and animal

Carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test Result Exposure

Duration

Talc Ingestion Not toxic to development Rat NOAEL 1,600

mg/kg

Limestone Ingestion Not toxic to development Rat NOAEL 625

mg/kg/day

premating & during gestation Target Organ(s)

Specific Target Organ Toxicity - single exposure

Duration Limestone Inhalation respiratory system All data are negative Rat NOAEL

0.812 mg/l

90 minutes

Tris(2,4,6-Dimethylaminomonomethy l)Phenol

Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification

NOAEL Not available

Specific Target Organ Toxicity - repeated exposure

Duration Talc Inhalation pneumoconiosis Causes damage to organs through

prolonged or repeated exposure

occupational exposure Talc Inhalation pulmonary fibrosis |

respiratory system

Rat NOAEL 18

mg/m3

113 weeks

Limestone Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification

occupational exposure Oxide Glass Chemicals Inhalation respiratory system Some positive data exist, but the

Human NOAEL not available occupational exposure Tris(2,4,6-Dimethylaminomonomethy l)Phenol

Dermal skin | liver | nervous system

Some positive data exist, but the data are not sufficient for classification Rat NOAEL 125 mg/kg/day 28 days Tris(2,4,6-Dimethylaminomonomethy l)Phenol

Dermal auditory system | hematopoietic system | eyes

All data are negative Rat NOAEL 125 mg/kg/day

28 days

Titanium Dioxide Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification

Rat LOAEL 0.01 mg/l

2 years

Titanium Dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not available

occupational exposure Quartz Silica Inhalation silicosis Causes damage to organs through Human NOAEL Not occupational

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prolonged or repeated exposure available exposure Aspiration Hazard

For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components.

Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methods

Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of waste product in a permitted industrial waste facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations

Contact 3M for more information. 311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed Hazard - Yes

15.2. State Regulations

Contact 3M for more information. California Proposition 65

Ingredient C.A.S. No. Classification

SILICA, CRYSTALLINE (AIRBORNE PARTICLES OF RESPIRABLE SIZE)

None Carcinogen

Lead 7439-92-1 Female reproductive toxin

Lead 7439-92-1 Male reproductive toxin

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Lead 7439-92-1 Developmental Toxin

Titanium Dioxide 13463-67-7 Carcinogen

WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm.

WARNING: This product contains a chemical known to the State of California to cause cancer.

15.3. Chemical Inventories

The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information.

15.4. International Regulations

Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard Classification

Health: 3 Flammability: 1 Instability: 1 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar

emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.