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Spectral Evidence for the One Step Three Electron Oxidation of Phenylsufinylacetic Acid and Oxalic Acid by Cr(VI)

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Figure

Figure 2. GC-MS spectrogram of the product.
Figure 3. UV-vis spectra of the product mixture.
Table 2. Second-order rate constants, enthalpy and entropy of activations for the co-oxidation of X-C6H4SOCH2COOH and OxH2 by Cr(VI)
Figure 4. UV-vis spectra of (a) Cr(VI) alone (b) Cr(VI) and OxH= 7.5 × 10PSAA and Al2; (c) Cr(VI), OxH2 and PSAA and (d) Cr(VI), OxH2, 3+ [Cr(VI)] = 3.0 × 10−4 mol·dm−3; [PSAA] = 3.0 × 10 −2 mol·dm−3; [OxH2] =1.0 × 10−2 mol·dm−3; [HClO4] −1 mol·dm−3; solve
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