1 PRODUCT AND COMPANY IDENTIFICATION
217-245-7810
CHEMTREC (800) 424-9300 Carolina Brands dba Rutland 7 Crabtree Road
Jacksonville, IL 62650 Product Identifier:
SDS Number:
Product Code:
Revision Date:
Version:
Product Description:
Product Use:
Concrete & Masonry Patch 43
89 10/6/2021 1
Weather resistant patching material for re-pointing and repairing exterior chimneys, brick and stone Masonry repair
Supplier Details:
www.rutland.com 217-245-1194
Faith Nergenah, Brian Miller
[email protected] [email protected] Phone:
Emergency:
Web:
Fax:
Contact:
Email:
2 HAZARDS IDENTIFICATION
Health, Skin corrosion/irritation, 3 Health, Acute toxicity, 4 Inhalation
Health, Specific target organ toxicity - Single exposure, 3 Health, Specific target organ toxicity - Repeated exposure, 2 GHS Classification in Accordance with 29 CFR 1910 (OSHA HCS):
GHS Signal Word: WARNING GHS Hazard Pictograms:
GHS Hazard Statements:
H316 - Causes mild skin irritation H332 - Harmful if inhaled
H336 - May cause drowsiness or dizziness
H373 - May cause damage to organs ( state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
GHS Precautionary Statements:
P261 - Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
Route of Entry:
Inhalation:
Skin Contact:
Eye Contact:
May be harmful if inhaled.
May cause irritation.
May cause irritation.
Ingestion: Ingestion is not an applicable route of entry for intended use. May be harmful if swallowed.
Eyes; Ingestion; Skin;
Classification of the Substance or Mixture
GHS Label Elements, Including Precautionary Statements
Hazards not Otherwise Classified (HNOC) or not Covered by GHS
3 COMPOSITION/INFORMATION OF INGREDIENTS
Percentages withheld, Trade Secret
Chemical Ingredients:
CAS# Chemical Name:
64742-95-6 65997-15-1 13983-17-0 14808-60-7 14807-96-6 471-34-1 112945-52-5
%
Solvent naphtha, petroleum, light arom.
Cement, portland, chemicals
Calcium Metasilicate (Wollastonite) Silica, crystalline
Talc (containing no asbestos fibers)
Carbonic acid calcium salt (1:1) Silica, Pyrogenic Synthetic Amorphous
4 FIRST AID MEASURES
Inhalation: Remove to fresh air. Seek medical attention if cough or other symptoms develop or persist.
Skin Contact: Wash with plenty of water. Get medical attention if irritation develops or persists.
Eye Contact: Immediately flush eyes with plenty of water. After initial flushing, remove contact lenses and continue flushing for at least 15 minutes. If effects occur, consult a physician, preferably an ophthalmologist. May cause injury due to mechanical action.
Ingestion: If Swallowed, DO NOT INDUCE VOMITING. Give one cup (8 ounces or 240 ml) of water or milk if available and transport to a medical facility. Never give anything by mouth to an unconscious or convulsive person.
5 FIRE FIGHTING MEASURES
Flammability: Flammable
Flash Point: Not Available
Autoignition Temp: Does Not Self-Ignite Dry powder, foam, carbon dioxide.
6 ACCIDENTAL RELEASE MEASURES
Absorb spilled material and place in appropriate container for disposal.
7 HANDLING AND STORAGE
Handling Precautions: Avoid contact with eyes, skin, or clothing. Use with adequate ventilation. Avoid prolonged and repeated contact with skin. Wash thoroughly after handling. Keep away from food and drinking water.
Storage Requirements: Store in a cool, well ventilated area. Keep container closed to prevent drying out.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Protective Equipment:
EYES AND FACE: Wear safety glasses with side shields. Chemical splash goggles and face shield (ANSI Z87.1 or approved equivalent) are recommended.
SKIN: Wear protective clothing, including long sleeves and gloves, to prevent skin contact. Thoroughly wash clothing before reuse. RESPIRATORY: In case of insufficient ventilation, wear suitable respiratory equipment.
9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Gray paste
Molecular Formula:
Not Available Not Available
Not Available 1.98
225,150 - 248,850 centipoise Not Available
Not Available Not Available Not Available Not Available Not Available Not Available Not Available Not Available
Solubility:
Softening Point:
Percent Volatile:
Heat Value:
Freezing/Melting Pt.:
Flash Point:
Octanol:
Vapor Density:
VOC:
Bulk Density:
Auto-Ignition Temp:
UFL/LFL:
Insoluble in water Not Available Not Available Not Available Not Available Not Available Not Available Not Available 2.33 lbs/gal Not Available Not Available Not Available Odor Threshold:
Particle Size:
Spec Grav./Density:
Viscosity:
Saturated Vapor Concentration:
Boiling Point:
Flammability:
Partition Coefficient:
Vapor Pressure:
pH:
Evap. Rate:
Molecular weight:
Decomp Temp:
Physical State: Paste Odor: Solvent
10 STABILITY AND REACTIVITY
Reactivity: This product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical Stability:
Conditions to Avoid:
Materials to Avoid:
Hazardous Decomposition:
Hazardous Polymerization:
Product is stable under normal conditions.
None Known
Strong Acids; Strong Oxidizing Agents;
May include, and are not limited to Oxides of Carbon Will not occur.
11 TOXICOLOGICAL INFORMATION
No data available.
Silica, crystalline cas#:(14808-60-7) []
Information on toxicological effects Acute toxicity:
Oral LD50 no data available Inhalation LC50
Dermal LD50
Other information on acute toxicity Skin corrosion/irritation: no data available
Serious eye damage/eye irritation: no data available Respiratory or skin sensitization: no data available Germ cell mutagenicity: no data available Carcinogenicity:
Limited evidence of carcinogenicity in human studies IARC: 1 - Group 1: Carcinogenic to humans (Quartz)
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
NTP: Known to be human carcinogen (Quartz)
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
Reproductive toxicity: no data available Teratogenicity: no data available
Specific target organ toxicity - single exposure (Globally Harmonized System):
no data available
Specific target organ toxicity - repeated exposure (Globally Harmonized System):
Inhalation - May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard: no data available
Potential health effects: Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Ingestion May be harmful if swallowed. Skin May be harmful if absorbed through skin. May cause skin irritation. Eyes May cause eye irritation.
Signs and Symptoms of Exposure: Prolonged inhalation of crystalline silica may result in silicosis, a disabling pulmonary fibrosis characterized by fibrotic changes and miliary nodules in the lungs, a dry cough, shortness of breath, emphysema, decreased chest expansion, and increased susceptibility to tuberculosis. In advanced stages, loss of appetite, pleuritic pain, and total incapacity to work. Advanced silicosis may result in death due to cardiac failure or destruction of lung tissue. Crystalline silica is classified as group 1 "known to be carcinogenic to humans" by IARC and
"sufficient evidence" of carcinogenicity by the NTP., The chronic health risks are associated with respirable particles of 3-4 um over protracted periods of time. Currently, there is a limited understanding of the mechanisms of quartz toxicity, including its mechanisms for lung carcinogenicity.
Additional studies are needed to determine whether the cell transforming activity of quartz is related to its carcinogenic potential.
Synergistic effects: no data available Additional Information:
RTECS: VV7330000
Talc (containing no asbestos fibers) cas#:(14807-96-6) []
Information on toxicological effects Acute toxicity:
Oral LD50 no data available
Inhalation LC50 Dermal LD50
Other information on acute toxicity
Skin corrosion/irritation: Skin - Human - Mild skin irritation - 3 h Serious eye damage/eye irritation: no data available
Respiratory or skin sensitization: no data available Germ cell mutagenicity: no data available Carcinogenicity:
Carcinogenicity - rat - Inhalation:
Tumorigenic:Carcinogenic by RTECS criteria. Lungs, Thorax, or Respiration:Bronchiogenic carcinoma. Endocrine:Tumors.
Carcinogenicity - rat - Inhalation:
Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Lungs, Thorax, or Respiration:Tumors.
This product is or contains a component that has been reported to be possibly carcinogenic based on its IARC, ACGIH, NTP, or EPA classification.
IARC: 1 - Group 1: Carcinogenic to humans (Quartz)
IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (Hydrous magnesium silicate) NTP: Known to be human carcinogen (Quartz)
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
Reproductive toxicity: no data available Teratogenicity: no data available
Specific target organ toxicity - single exposure (Globally Harmonized System):
Inhalation - May cause respiratory irritation. - Lungs
Specific target organ toxicity - repeated exposure (Globally Harmonized System):
no data available
Aspiration hazard: no data available
Potential health effects: Inhalation Toxic if inhaled. May cause respiratory tract irritation. Ingestion May be harmful if swallowed. Skin May be harmful if absorbed through skin. May cause skin irritation. Eyes May cause eye irritation.
Signs and Symptoms of Exposure: Prolonged inhalation of crystalline silica may result in silicosis, a disabling pulmonary fibrosis characterized by fibrotic changes and miliary nodules in the lungs, a dry cough, shortness of breath, emphysema, decreased chest expansion, and increased susceptibility to tuberculosis. In advanced stages, loss of appetite, pleuritic pain, and total incapacity to work. Advanced silicosis may result in death due to cardiac failure or destruction of lung tissue. Crystalline silica is classified as group 1 "known to be carcinogenic to humans" by IARC and
"sufficient evidence" of carcinogenicity by the NTP.
Synergistic effects: no data available Additional Information:
RTECS: WW2710000
Carbonic acid calcium salt (1:1) cas#:(471-34-1) []
Information on toxicological effects Acute toxicity:
LD50 Oral - rat - 6,450 mg/kg Inhalation: no data available Dermal: no data available
Skin corrosion/irritation: Skin - rabbit Result: No skin irritation (OECD Test Guideline 404)
Serious eye damage/eye irritation: Eyes - rabbit Result: Mild eye irritation (OECD Test Guideline 405)
Respiratory or skin sensitisation: no data available Germ cell mutagenicity: no data available Carcinogenicity:
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
Reproductive toxicity: no data available
Specific target organ toxicity - single exposure: no data available Specific target organ toxicity - repeated exposure: no data available Aspiration hazard: no data available
Additional Information:
RTECS: FF9335000
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
12 ECOLOGICAL INFORMATION
No information available
Silica, crystalline cas#:(14808-60-7) []
Information on ecological effects Toxicity: no data available
Persistence and degradability: no data available Bioaccumulative potential: no data available Mobility in soil: no data available
PBT and vPvB assessment: no data available Other adverse effects: no data available
Talc (containing no asbestos fibers) cas#:(14807-96-6) []
Information on ecological effects Toxicity: no data available
Persistence and degradability: no data available Bioaccumulative potential: no data available Mobility in soil: no data available
PBT and vPvB assessment: no data available Other adverse effects: no data available
Carbonic acid calcium salt (1:1) cas#:(471-34-1) []
Information on ecological effects Toxicity: no data available
Persistence and degradability: no data available Bioaccumulative potential: no data available Mobility in soil: no data available
Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted Other adverse effects: no data available
13 DISPOSAL CONSIDERATIONS
Dispose of this product in accordance with all applicable local, state and federal regulations.
Silica, crystalline cas#:(14808-60-7) []
Waste treatment methods
Product: Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging: Dispose of as unused product.
Talc (containing no asbestos fibers) cas#:(14807-96-6) []
Waste treatment methods
Product: Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging: Dispose of as unused product.
Carbonic acid calcium salt (1:1) cas#:(471-34-1) []
Waste treatment methods
Product: Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging: Dispose of as unused product.
14 TRANSPORT INFORMATION
Not Regulated
15 REGULATORY INFORMATION
[%] RQ (CAS#) Substance - Reg Codes ---
[--%] Solvent naphtha, petroleum, light arom. (64742-95-6) TSCA
[--%] Cement, portland, chemicals (65997-15-1) MASS, OSHAWAC, PA, TSCA, TXAIR [--%] Calcium Metasilicate (Wollastonite) (13983-17-0)
[--%] Silica, crystalline (14808-60-7) GADSL, MASS, NRC, OSHAWAC, PA, PROP65, TSCA, TXAIR [--%] Talc (containing no asbestos fibers) (14807-96-6) MASS, OSHAWAC, PA, TSCA, TXAIR [--%] Carbonic acid calcium salt (1:1) (471-34-1) TSCA
[--%] Silica, Pyrogenic Synthetic Amorphous (112945-52-5)
Regulatory Code Legend
--- TSCA = Toxic Substances Control Act
MASS = MA Massachusetts Hazardous Substances List OSHAWAC = OSHA Workplace Air Contaminants PA = PA Right-To-Know List of Hazardous Substances
TXAIR = TX Air Contaminants with Health Effects Screening Level GADSL = Global Automotive Declarable Substance List (GADSL) NRC = Nationally Recognized Carcinogens
PROP65 = CA Prop 65
This product can expose you to chemicals including Silica, Crystalline, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov.
WARNING
16 OTHER INFORMATION
PREPARED BY: Brian Miller
MANUFACTURER DISCLAIMER: The information presented herein is believed to be accurate but is not warranted. Recipients are advised to confirm in advance that the information is current, applicable and suitable to their circumstances.
Revision Date: 10/6/2021
