creating tomorrow’s solutions
english
elastomers,
Elastomers, Plastics & Composites:
Many of the applications
we encounter daily are only possible thanks to the availability of
highly efficient elastomers, plastics and composites. And these
materials owe their quality, productivity and economy more than
ever to efficient additives and processing auxiliaries – which have
become essential to the commercial success of the end product.
see also: www.wacker.com Products & Markets Elastomers, Plastics & Composites
elastomers, Plastics & comPosites
Contents
CompositesRTV-2 Silicone Rubber for Pad Printing
LR Liquid Silicone Rubbers
Additives for Silicone Rubbers
18
10
4
applications4
8
Products12
14
health care14
15
17
automotive14
15
Food contact water contact technical molded Parts
Baby articles &
toys extruded articles
15
safety applications17
18
19
19
color masterbatches for lr color masterbatches for hcr stabilizersProcessing Auxiliaries & Polymer Modification
21
21
22
24
24
26
Primers & adhesives
WACKER at a Glance
Polymer
modification Fillers catalysis Plasticscrosslinking additives for
Plastics
RTV-2 Silicone Rubber for Moldmaking
6
6
6
7
For architectural Design and Decoration
concrete
castings moldmaking for Food contact industrial Production rapid Prototyping
7
Design
7
Diverse Applications for HCR and LR Silicone Rubbers
calendering
17
injection molding molding & extrusion Pad Printing4
Composite Applications
Complex requirements require integrated solutions. That is particularly true in growth markets such as the composites industry. You can benefit from the pooled expertise of our composite experts and from new technologies for challenging composites applications. Whatever your needs – be they immaculate surfaces combined with zero shrinkage and high mechanical strength; control of the flow behavior of laminating resins and gel coats; or you want scratchproof composite stone, or effective control over curing – the correct additives will ensure you achieve just what you want. WACKER offers you a high-performance portfolio for optimum combinations whatev-er the application – bulk molding com-pound, pultrusion, resin transfer molding, sheet molding compound and hand lay-up or spray-up.
Composite Products
WACKER acetylacetone is used as a copro-moter to maximize the quality and yield of complex curing processes. ELASTOSIL® C
permits innovative silicone system solutions – such as dimensionally accurate produc-tion of reusable vacuum bags. They can achieve huge savings compared to dispos-able vacuum film. In challenging materials such as composite stone, GENIOSIL®
si-lanes act as coupling agents, enabling the organic resin to chemically bond to the inor-ganic mineral. For hand lay-up of compo-sites, HDK® pyrogenic silica provides expert
control of flow behavior. VINNAPAS® solid
resins are low-profile additives for compo-site parts providing a constant high product quality with first-class smooth and glossy surfaces and no shrinkage.
Products
Acetylaceton, ELASTOSIL® C, GENIOSIL®,
HDK®, VINNAPAS®
5
see also: www.wacker.com Products & Markets Elastomers, Plastics & Composites Composites
6
Concrete Castings
Concrete castings that remain permanently elegant and robust must be cast using moldmaking materials that are alkali resistant with long-term stability, and can faithfully reproduce even and uneven surfaces and undercuts. Molds made with addition-curing ELASTOSIL® M silicones from
WACKER are ideal for a wide range of applications – figurines and statues as well as the indus-trial production of composite-stone facings.
Moldmaking for
Food Contact
The prime consideration regard-ing moldmakregard-ing materials for foodstuffs is that they comply with legal requirements. Other im-portant concerns are neutral taste, permanent stability and im-parting a faithfully reproducible shape to the most diverse of food products. These advantages are exhibited by special addition-cur-ing ELASTOSIL® M molding
com-pounds, which can be used for the lifelike replication of foods.
For Architectural Design
and Decoration
In architecture, a striking, integrat-ed idea is creatintegrat-ed through a skilful combination of structural design, materials and visual effects. This makes tough demands on the re-production technology. Success depends more than ever on faithful replication of the original model – not to mention molds with good long-term stability and resistance to different molding materials. ELASTOSIL® M moldmaking
com-pounds do all this, while also offer-ing architects many other product advantages for the customized reproduction of classical elements or special effects.
Reproduction at its Best
Whether for individual works of craftsmanship, functional prototyping or industrial mass production – first-class results in modern moldmaking demand faithful reproduction, outstanding release properties and high resistance.
7
Design
While there are potentially infinite design possibilities, there are se-rious constraints on the repro-duction of design elements – un-less you use the right products, of course. With ELASTOSIL® M
condensation-curing RTV-2 sili-cone rubber grades, molds can be produced quickly and easily. Their functional properties allow the original to be replicated in faithful detail, and they offer the added benefit of excellent resis-tance to different reproduction materials.
Industrial Production
Industrial mass production re-quires materials with extremely high product reliability, perma-nent durability and efficient pro-cessability – all these require-ments are met by ELASTOSIL® M
moldmaking compounds. WACKER’s RTV-2 silicone rubber grades exhibit excellent mechani-cal properties such as tear resis-tance and tensile strength. They are also available in different hardnesses, ensuring that every mold has just the right flexibility.
Rapid Prototyping
When prototypes are needed, a mold must be produced quickly. This requires moldmaking materi-als with outstanding inherent release properties, excellent flow and good transparency. WACKER’s ELASTOSIL® M
addition-curing RTV-2 silicone rubber grades ensure success in these challenging applications, and permit functional as well as economic advantages in this application field.
see also: www.wacker.com Products & Markets Elastomers, Plastics & Composites RTV-2 Silicone Rubber Moldmaking Compounds elastomers, Plastics & comPosites rtV-2 silicone ruBBer For molDmaking
8
Pad Printing
Pad printing is currently the most important process for printing modern plastic articles. Efficient products of the ELASTOSIL® RT -
line, in some cases with antistatic proper-ties, offer outstanding flowability, good self-deaeration and high reactivity for rapid demolding in the manufacture of printing pads – even when the rubber contains large amounts of silicone fluid. Mechanical prop-erties that stay impressively constant in the long term and excellent tear resistance make our addition- and condensation-curing silicone rubber grades indispensable for the many and varied challenges of pad printing.
Striking Results
Products
ELASTOSIL® RT
For toys, CDs, model railroads or screw caps – the right additive helps with the optimum transfer of printing inks, yielding strikingly clear printed images.
9
see also: www.wacker.com Products & Markets Elastomers, Plastics & Composites RTV-2 Silicone Rubber for Pad Printing
10
Injection Molding
With ELASTOSIL® LR liquid silicone
rub-bers, you benefit from lower unit costs with-out compromising on excellent properties. These high temperature vulcanizing rubber grades have an especially low viscosity and can be processed fully automatically on state-of-the-art injection molding machines with no need for secondary processing. The outstanding physical and chemical proper-ties of ELASTOSIL® LR make it the ideal
choice for diverse applications – including those requiring special properties such as self-adhesion and oil bleeding.
Tailored Multifunctional Talent
Applications
Automotive
Baby articles & toys Health care
Food contact Safety applications Technical molded parts Water contact
Applications from A to Z:
For more details, see pages 14 – 17 and online at www.wacker.com/Products
Products
11
see also: www.wacker.com Products & Markets Elastomers, Plastics & Composites LR Liquid Silicone Rubber for Injection Molding elastomers, Plastics & comPosites lr liquiD silicone ruBBer
12
Versatile, Efficient and Economical
silmiX® - compounded excellence:SILMIX®-silicone rubber compounds are developed and produced to customers’ specifications, and supplied as ready-to-process compounds. SILMIX® products provide a direct and reliable way of manufacturing a wide range of silicone rubber articles by the common processes of compression, transfer and injection molding, and extrusion – while minimizing production outlay and the time involved.
13
see also: www.wacker.com Products & Markets Elastomers, Plastics & Composites HCR Solid Silicone Rubber for Molded Parts elastomers, Plastics & comPosites hcr soliD silicone ruBBer
Molding & Extrusion
Peroxide-induced crosslinking ELASTOSIL® R
and platinum-catalyzed addition-curing ELASTOSIL® Rplus products offer extreme
mechanical and chemical resistance for a wide range of extrusion and molding appli-cations. Rapid-curing HCR solid silicone rubber grades from WACKER are excellent for either efficient molding with very fast cycles or for economic extrusion of cables, wires, sheets and profiles.
Applications
Automotive
Baby articles & toys Health care
Cable extrusion Calendering Food contact Safety applications Technical molded parts Water contact
Applications from A to Z:
For more details, see pages 14 – 17 and online at www.wacker.com/Products
Products
ELASTOSIL® R, ELASTOSIL® Rplus,
14
Healthcare
With their excellent biocompati-bility, silicones are playing ever more important roles in health care. The sensitive and optimized formulations based on silicones are tailored completely to the needs of the health care industry – while also meeting the market’s requirements for the manufacture of the end product. WACKER SILPURAN® silicone elastomers
offer a comprehensive breadth of performance for the most varied of demands: from very soft gels for external mammary prostheses or wound dressings, through soft rubber for catheters or masks, to hard elastomers for sturdy tubing.
ELASTOSIL
®– Variety for Injection Molding,
Molded Parts & Extrusion
Food Contact
ELASTOSIL® silicone grades are
ideal for direct and indirect food contact because they have inor-ganic characteristics. They are heat resistant, easy to clean and meet all current food regulations. Since our silicones consist of just a few defined ingredients, they are clean, plasticizer-free, flexible plastics for any application where reliability and convenience are demanded.
Automotive
HCR solid silicone rubber and LR liquid silicone rubber grades are ideal for producing moldings for the automotive sector, where they ensure stable production proces-ses and perfectly functioning end products. Preferred applications include membranes, weather-resistant and contamination-resistant parts, spark-plug boots, molded seals, vibration dampers, exhaust pipe mounts and turbo-charger and radiator hoses. Self-adhesive and oil-bleeding grades are only two examples of how WACKER is meeting the special demands of this industry.
15 elastomers, Plastics & comPosites DiVerse aPPlications For hcr anD lr silicone ruBBer
Water Contact
ELASTOSIL® silicone grades are
water repellent and have an inor-ganic backbone. They therefore offer little opportunity for algal and bacterial growth, and are ex-tremely resistant to hot water and fatigue. The weathering resis-tance of ELASTOSIL® silicones is
so good that they can be used in the open air with no loss of effec-tiveness. Their high resistance to detergents and cleaning agents also makes them outstanding processing auxiliaries in all drinking-water and sanitary applications.
Technical Molded Parts
ELASTOSIL® silicone elastomers
are high-performance materials with outstanding chemical and thermal resistance, very good general mechanical properties and excellent compression set. With their superb low-tempera-ture flexibility, they retain their properties unchanged, even under extreme conditions – unlike other flexible plastics. They are also easy to process and cure rapidly.
Safety Applications
Silicone elastomers from WACKER are extremely reliable and safe to use. Emitting no toxic fumes or halogens in a fire, they are the perfect materials for safety- critical applications – e.g. in air-planes, rail cars or shipbuilding. Some ELASTOSIL® grades also
contain flame retardants to make them fire resistant.
16
Bonding without pressure or priming: An innovative technology allows excellent bonding to many different materials, including thermoplastics, steel and aluminum, during injection molding.
17 elastomers, Plastics & comPosites DiVerse aPPlications For hcr anD lr silicone ruBBer
see also: www.wacker.com Products & Markets Elastomers, Plastics & Composites
Baby Articles & Toys
Plasticizer-free, hypoallergenic, flexible and tough: ELASTOSIL®
silicone elastomers offer the best conditions for safe toys, as well as baby bottles, teats, teething rings, pacifiers and the like. Our silicones are made of a few defined ingredients, meet all the relevant standards, such as EN 71 and EN 1400, and are therefore ideal for all applications where the comfort and safety of infants is concerned.
Extruded Cable Articles
WACKER silicone rubber materi-als are excellent insulators for cables and wires. Where high re-quirements are set for electrical, mechanical and chemical proper-ties, ELASTOSIL® is a guarantee
of perfect functionality: for exam-ple, in automotive applications, household appliances, medical products, ships, aircraft, instru-mentation and control, and gen-eral electrical installations.
Calendering
ELASTOSIL® R solid silicone
rubber can be calendered into sheet or used to coat fabrics or other materials. WACKER offers a comprehensive range especially for these applications, including specialty grades char-acterized by excellent green strength.
18
Color Masterbatches
for LR
ELASTOSIL® Pigment Pastes FL
for liquid silicone are based on ELASTOSIL® LR polymers. As a
result they offer extremely high yield and are opaque even in very low doses of 1% with low wall thicknesses. For perfect compati-bility and breathtakingly brilliant colors, the concentrated pigments have been extensively tested for use in silicone.
Primers and Adhesives
High-performance ELASTOSIL®
products and silicone-rubber additives ensure that the various silicones bond reliably to different substrates, such as metals, plas-tic or glass. WACKER offers you a comprehensive range of addi-tives and develops efficient pro-duct solutions tailored to your specific processes, for various application processes, such as spraying, dipping, brushing or bead application.
Premium Quality Additives
whether you're in pigmenting or bonding – a top-quality result is always based on perfectly matched ingredients. WACKER supplies you with an extensively tested product portfolio for this.
19
see also: www.wacker.com Products & Markets Elastomers, Plastics & Composites Additives for Silicone Rubber
elastomers, Plastics & comPosites aDDitiVes For silicone ruBBer
Color Masterbatches for
HCR
PT Color Masterbatches excel with ELASTOSIL® polymers. That
ensures high yield and excellent opacity even at very low doses of 1% and low wall thicknesses. The concentrated pigments are precisely matched to the particu-lar requirement, thus ensuring impressive color results.
Stabilizers
Optimally matched and tested, high-performance ELASTOSIL®
stabilizers and stabilizing pigment pastes improve solid and liquid silicones’ heat, oil and reversion resistance, as well as their com-pression set. The stabilizers are used in a dose between 1 and 3% and are extremely efficient: for example, their remarkable performance profile allow hot-air resistance to be increased by up to 50°C.
20
see also: www.wacker.com Products & Markets Elastomers, Plastics & Composites Processing Auxiliaries & Polymer Modification
Plastics Modified to Measure
21 elastomers, Plastics & comPosites Process auXiliaries & Polymer moDiFication
Additives for Plastics
Thermoplastics manufacturers now face tougher demands than ever on productivity, quality, and efficiency. They require novel additives for modifying desirable properties, such as flowability and scratch resistance, or improving the mechanical properties of plastic compounds. GENIOPLAST®
pro-ducts are excellent processing aids and modifiers for silicone-based thermoplastics, and have a proven track record as additives and processing aids for both standard ther-moplastics and engineering plastics.
Applications
Plastics modification
Products
GENIOPLAST®
Polymer Modification
Conventional compounding or modern ex-trusion and coexex-trusion processes allow the properties of polymer surfaces to be selec-tively modified by means of silicone-based thermoplastics. A valuable help here is provided by WACKER’s line of GENIOMER®
products. In the extrudate or coextrudate, they impart tailored silicone characteristics to the plastic surface, providing it with desirable properties such as release, hydro-phobicity or tactile effects.
Applications
Polymer Modification
Products
22
Fillers
For perfect results, silicone elastomers and natural and synthetic rubber grades require suitable fillers. They are essential to obtain specific mechanical characteristics in various application fields. HDK® pyrogenic
silica functions as an active filler here, pro-viding the material with the required system properties. Hydrophobic HDK® grades
pro-vide the high filler contents combined with outstanding processability. The outstanding reinforcing effect of HDK® increases sag
resistance, elongation at break and loading capacity of elastomers. In non-polar silicone rubber, HDK® can act as a reinforcing filler
while at the same time being used as a rheol-ogical additive, ensuring that low-viscosity systems do not run off vertical construction elements. In silicone elastomers, hydrophilic HDK® is an effective reinforcing agent –
together with low-molecular plasticizers, the system benefits from optimum processing.
hDk® pyrogenic silica from wacker is extremely versatile as an active filler, providing outstanding properties: High load-bearing strength, flexibility and reinforcement – together with efficient processability.
Applications
Reinforcement of mechanical properties
Products
23
see also: www.wacker.com Products & Markets Elastomers, Plastics & Composites Processing Auxiliaries & Polymer Modification elastomers, Plastics & comPosites Process auXiliaries & Polymer moDiFication
24
Catalysis
Automotive and mechanical engineering, packaging technology, building construc-tion, the textiles, toy and cosmetics industries – hardly any modern industrial application would be conceivable without the use of polypropylene (PP). There are good reasons why, since PP provides plas-tics manufacturers with a wide range of properties. Important ingredients in the chemical conception of this polymer are donor silanes from WACKER. The produc-tion of PP by olefin polymerizaproduc-tion is of enormous technical and economic impor-tance. Donor silanes are used as cocata-lysts in this case, ensuring a high content of isotactic polymer, controlling the mole-cular weight and determining the quality of the end polymer.
Applications
Polypropylene manufacture
Products
WACKER® Silane
Plastics Crosslinking
The innovative technology of silane cross-linking converts inexpensive thermoplastic polymers into cured polymers, and is there-fore ideal for producing cables and pipes from curable polyethylene. The necessary precursors for this are provided by GENIOSIL® vinyl silanes from WACKER.
GENIOSIL® is preferably used for silane
crosslinking and the production of curable polyolefin compounds. Here, formulating silanes together with processing auxiliaries creates a synergetic combination of the advantages of silane curing with those of silicones as polymer additives.
Applications
Cable and pipe manufacture
Products
25
see also: www.wacker.com Products & Markets Elastomers, Plastics & Composites Processing Auxiliaries & Polymer Modification elastomers, Plastics & comPosites Process auXiliaries & Polymer moDiFication
26
Expertise and Service Network
on Five Continents
All figures are for 2008.
WACKER is one of the world’s leading and most research-intensive chemical
companies. In 2008, its sales totaled € 4.3 billion. Products range from silicones,
binders and polymer additives for diverse industrial sectors to bio-engineered
pharmaceutical actives and hyperpure silicon for semiconductor and solar
ap-plications. As a technology leader focusing on sustainability, WACKER promotes
products and ideas that offer a high value-added potential to ensure that current
and future generations enjoy a better quality of life based on energy efficiency
and protection of the climate and environment.
Spanning the globe via five business divisions, 27 production sites and over 100
subsidiaries and sales offices, we have established a presence in all key economic
regions and growth markets. With a 15,900-strong workforce, WACKER sees itself
as a reliable innovation partner that develops trailblazing solutions for, and in
col-laboration with, its customers. WACKER also helps them boost their own success.
Our technical centers employ local specialists, who assist customers worldwide in
the development of products tailored to regional demands, supporting them during
every stage of their complex production processes, if required.
WACKER e-solutions are online services provided via our customer portal and as
integrated process solutions. Our customers and business partners thus benefit from
comprehensive information and reliable service to enable projects and orders to be
handled fast, reliably and highly efficiently. Visit us anywhere, anytime around the
world at:
www.wacker.com
27
•Sales offices and production sites •Technical centers
wacker at a glance
WACKER Technical Centers: our worldwide state-of-the-art competence centers focus on finding the best possible solution for your needs. WACKER has 17 technical centers – in Adrian, Akeno, Allentown, Beijing, Burghausen, Dubai, Hikari, Hsinchu, Jandira, Kolkata, Melbourne, Moscow, Nünchritz, Portland, Shanghai, Singapore and Suwon.
65 54 e/ 11 .0 9
Wacker Chemie AG Hanns-Seidel-Platz 4, 81737 Munich, Germany Tel. +49 89 62 79-0, Fax +49 89 62 79-1770, www.wacker.com
The data presented in this brochure are in accordance with the present state of our knowledge, but do not absolve the user from carefully checking all supplies immediately upon receipt. We reserve the right to alter product constants within the scope of technical progress or new developments. The information given in this brochure should be checked by preliminary trials because of conditions during processing over which we have no control, especially where other companies’ raw materials are also being used. The information provided by us does not absolve the user from the obligation of investigating the possibility of infringement of third parties’ rights and, if necessary, clarifying the position. Recommendations for use do not constitute a warranty, either express or implied, of the fitness or suitable of the product for a particular purpose.