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Trade name: ALM 2010

Peelable Soldermask

1.) IDENTIFICATION OF THE

SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1.) Product identifier

Product form : Trade name :

1.2.) Relevant identified uses of the substance or mixture and uses advised against

1.2.1.) Relevant identified uses

Main use category:

Use of the substance/mixture:

1.2.2.) Uses advised against

1.3.) Details of the supplier of the safety data sheet

Manufacturer Address:

1.4.) Emergency telephone number

Mixture ALM 2010

Reserved for industrial and professional use.

Peelable Soldermask

No additional information available.

EDSYN GMBH EUROPA

Finkenweg 2 Tel.: 09342 - 6413 D 97892 Kreuzwertheim Fax: 09342 - 6417 closest hospital Emergency number

2.) HAZARDS IDENTIFICATION 2.1.) Classification of the substance or

mixture

Classification according to Regulation (EC) no 1272/2008 (CLP):

Adverse physicochemical, human health and environmental effects: Other information

NFPA-Code:

2.2.) Label elements

Aquatic Chronic 3 H412

Full text of H statements: see section 16

According to EC directives or the corresponding national regulations there is no labelling obligation for this product.

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Labelling according to Regulation (EC) No. 1272/2008 [CLP]

Signal word (CLP): Hazard statements: CLP): Precautionary statements (CLP): 2.3.) Other hazards

Other hazards not contributing to the classification:

No labelling applicable.

-H412 – Harmful to apuatic life with long lasting effects. P273 – Avoid release to the environment.

This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII

This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

Contains no substance on the REACH candidate list.

3.) COMPOSITION/INFORMATION ON INGREDIENTS

3.1.) Substances Not applicable.

Mixtures

name Product identifier % Classification according to Regulation (EC) no 1272/2008 (CLP)

rubber, natural (CAS N°) 9006-04-6

(EC N°) 232-689-0 50 Not classified

ammonium hydroxide,aqueous solution,conc=25%

(CAS N°) 1336-21-6 (EC N°) 215-647-6 (EC index no) 007-001-01-2

< 0,7

Skin Corr. 1A, H314 Eye Dam. 1, H318 STOT SE 3, H335 Aquatic acute 1, H400 zinc oxide (CAS N°) 1314-13-2 (EC N°) 215-222-5 (EC index no) 030-013-00-7

< 0,3 Aquatic Chronic 1, H410 Aquatic Acute 1, H400

Specific concentration limits:

name Product identifier Specific concentration limits

ammonium hydroxide,aqueous solution,conc=25% (CAS N°) 1336-21-6 (EC N°) 215-647-6 (EC index no) 007-001-01-2

(C>= 5 STOT SE 3, H335

Full text of H-statements: see section 16

4.) FIRST AID MEASURES

4.1.) Description of first aid measures First aid measures after skin contact:

First aid measures after eye contact:

First aid measures after ingestion:

4.2.) Most important symptoms and effects, both acute and delayed

After contact with skin, wash immediately with plenty of warm water and soap.

Rinse immediately with plenty of water. Take victim to an ophthalmologist if irritation persists.

Rinse mouth with water. Consult a doctor/medical service if you feel unwell.

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Symptoms/effects:

Symptoms/injuries after inhalation:

Symptoms/injuries after skin contact: Symptoms/injuries after eye contact: Symptoms/injuries after ingestion:

4.3.) Indication of any immediate medical attention and special treatment needed

Handle in accordance with good industrial hygiene and safety practice. EXPOSURE TO HIGH CONCENTRATIONS. Irritation of the respiratory tract. Nausea.

Slight irritation.

Irritation of the eye tissue. Gastrointestinal complaints.

No additional information available.

5.) FIREFIGHTING MEASURES 5.1.) Extinguishing media

Suitable extinguishing media 5.2.) Special hazards arising from the

substance or mixture Fire hazard:

5.3.) Advice for firefighters

Dry chemical, CO2, dry sand, or alcohol-resistant foam.

None

No additional information available.

6.) ACCIDENTAL RELEASE MEASURES 6.1.) Personal precautions, protective

equipment and emergency procedures General measures:

6.1.1.) For non-emergency personnel 6.1.2.) For emergency responders 6.2.) Environmental precautions

6.3.) Methods and material for containment and cleaning up

Methods for cleaning up:

6.4.) Reference to other sections

Ensure adequate ventilation. No additional information available. No additional information available.

Avoid release to the environment. Do not discharge into drains or the environment.

Collect spillage. Take up liquid spill into absorbent material. No additional information available.

7.) HANDLING AND STORAGE 7.1.) Precautions for safe handling 7.2.) Conditions for safe storage, including

any incompatibilities Maximum storage period:

No additional information available.

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Storage temperature: 7.3.) Specific end use(s)

REACH Disclaimer:

15-20 °C Avoid: T° < 7 °C

This information is based on current knowledge. Consistency of data in the SDS with CSR is considered, as far as the information is available at the time of compilation (cfr Revision date and Version number).

8.) EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1.) Control parameters rubber, natural (9006-04-6)

Belgium Limit value (mg/m³) 0,001 mg/m³

Italy-Portugal-USA ACGIH ACGIH TWA (mg/m³) 0,0001 mg/m³ (Inhalable fraction) United Kingdom WEL TWA (mg/m³) 0,6 mg/m³ (limit relates to

cyclohexane soluble material) 6 mg/m³

Zinc oxide (1314-13-2)

Belgium Limit value (mg/m³) 2 mg/m³ Belgium Short time value ((mg/m³) 10 mg/m³ France VME (mg/m³) 5 mg/m³

10 mg/m³

Italy – Portugal – USA ACGIH ACGIH TWA (mg/m³) 2 mg/m³ (Respirable fraction) Italy – Portugal – USA ACGIH ACGIH STEL (mg/m³) 10 mg/m³ (Respirable fraction)

8.2.) Exposure controls

Personal protective equipment:

Eye protection:

Skin and body protection: Respiratory protection:

Gloves.

Eye protection designed to protect against liquid splashes should be worn. Wear suitable protective clothing.

Local exhaust is needed at source of vapours.

9.) PHYSICAL AND CHEMICAL PROPERTIES

9.1.) Information on basic physical and chemical properties Physical state: Appearance: Colour: Odour: Odour threshold: pH: Melting point: Liquid Viscous. Paste. White.

Characteristic odour. Faint odour of ammonia. No data available.

8,4 – 9,4

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Boiling point: Flash point:

Relative evaporation rate (butylacetate=1):

Flammability (solid, gas); Explosive limits:

Vapour pressure:

Relative vapour density at 20 °C: Relative density: Solubility: Log Pow: Log Kow: Auto-ignition temperature: Decomposition temperature: Viscosity, kinematic: Viscosity, dynamic: Explosive properties: Oxidising properties: 9.2.) Other information Other properties: No data available. No data available. No data available. No data available. No data available. No data available. No data available. 1,091

Water: Liquid: dilutable / Dry film: insoluble No data available. No data available. No data available. > 200°C No data available. 25.000 – 35.000cP No data available. No data available.

Polymerisation of product/curing: 1hr at room temperature.

10.) STABILITY AND REACTIVITY 10.1.) Reactivity

10.2.) Chemical Stability

10.3.) Possibility of hazardous reactions 10.4.) Conditions to avoid

10.5.) Incompatible materials

10.6.) Hazardous decomposition products

No additional information available. Stable under normal conditions. None under normal use.

When storage conditions are not respected, polymerisation can occur. Keep away from acids, salts, alcohol as they coagulate the masking products. Avoid contact with: copper.

No additional information available.

11.) TOXICOLOGICAL INFORMATION 11.1.) Information on toxicological effects

Acute toxicity: zinc oxide (1314-13-2) LD50 oral rat LD50 dermal rat LC50 inhalation rat (mg/l) Skin corrosion/irritation:

Serious eye damage/irritation:

Not classified.

> 5000 mg/kg (Equivalent or similar to OECD 401, Rat, Male/female, Experimental value)

> 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat. Male/female, Experimental value)

> 5.7 mg/l (Equivalent or similar to OECD 403, 4 h, Rat. Male/female, Experimental value)

Not classified. pH: 8,4 – 9,4 Not classified.

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Respiratory or skin sensitisation: Germ cell mutagenicity:

Carcinogenicity: Reproductive toxicity: STOT-single exposure: STOT-repeated exposure: Aspiration hazard: pH. 8,4 – 9,4 Not classified. Not classified. Not classified. Not classified. Not classified. Not classified. Not classified. 12.) ECOLOGICAL INFORMATION 12.1.) Toxicity Ecology - general: zinc oxide (1314-13-2) LC50 fish 1 EC50 Daphnia 1

12.2.) Persistence and degradability zinc oxide (1314-13-2) Persistence and degradability

Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD

Not available.

0.169 mg/l (ASTM E729-88, 96 h, Oncorhynchus mykiss, Static system, Fresh water, Read-across)

1 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Rest, 48 h, Daphnia magna, Static system, Fresh water, Experimental value)

Biodegradability in soil: not applicable. Biodegradability: not applicable

Not applicable(inorganic) Not applicable(inorganic) Not applicable(inorganic)

12.3.) Bioaccumulative potential

ammonium hydroxide, aqueous solution, conc=25% (1336-21-6)

Bioaccumulative potential Not bioaccumulative.

Rubber, natural (9006-04-6)

Bioaccumulative potential No bioaccumulation data available.

zinc oxide (1314-13-2)

Log Pow 1.53 (Estimated value) Bioaccumulative potential Not bioaccumulative.

12.4.) Mobility in soil

ammonium hydroxide, aqueous solution, conc=25% (1336-21-6)

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Ecology - soil zinc oxide (1314-13-2) surface tension Log Koc Ecology - soil

12.5.) Results of PBT and vPvB assessment ALM 2010 Peelable Soldermask

ammonium hydroxide, aqueous solution, conc=25% (1336-21-6)

zinc oxide (1314-13-2)

12.6.) Other adverse effects

No (test) data on mobility of the components available.

Not applicable (solid) 2.2 (log Koc, Literature study) Low potential for adsorption in soil.

This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII

This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII

This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII

This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

No additional information available.

13.) DISPOSAL CONSIDERATIONS 13.1.) Waste treatment methods

Ecology - waste materials: Do not discharge into surface water. Do not discharge into the sewer.

14.) TRANSPORT INFORMATION 14.1.) UN-No. (ADR): UN-No. (IMDG): UN-No. (IATA): UN-No. (ADN): UN-No. (RID):

14.2.) UN proper shipping name Proper Shipping Name (ADR): Proper Shipping Name (IMDG): Proper Shipping Name (IATA): Proper Shipping Name (ADN): Proper Shipping Name (RID): 14.3.) Transport hazard (class(es)

ADR

Transport hazard class(es) (ADR): IMDG

Transport hazard class(es) (IMDG):

In accordance with ADR / RID / IMDG / IATA / ADN Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable

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IATA

Transport hazard class(es) (IATA): ADN

Transport hazard class(es) (ADN): RID

Transport hazard class(es) (RID): 14.4.) Packing group

Packing group (ADR): Packing group (IMDG): Packing group (IATA): Packing group (ADN): Packing group (RID): 14.5.) Environmental hazards

Dangerous for the environment Marine pollutant

Other information:

14.6.) Special precautions for user Overland transport

No data available Transport by sea

Transport regulations (IMDG): Air transport

Transport regulations (IATA): Inland waterway transport No data available

Rail transport No data available

14.7.) Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable No. No.

No supplementary information available

Not subject

Not subject

Additional rules to be obtained at EDSYN GMBH EUROPA

Remark:

Above mentioned regulations are in force at the moment of publication of this (SDS) safety data sheet. With reference to possible modifications in transport regulations of dangerous goods, we advise you to verify its validity at EDSYN GMBH EUROPA.

15.) REGULATORY INFORMATION 15.1.) Safety, health and environmental

regulations/legislation specific for the substance or mixture

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15.1.1.) EU Regulations

15.1.2.) National regulations Germany

Reference to AwSV

WGK remark:

12th Ordinance Implementing the Federal Immission Control Act – 12 BlmSCHV

15.2.) Chemical safety assessment

Contains no REACH substances with Annex XVII restricions. Contains no substance on the REACH candidate list. Contains no REACH Annex XIV substances

Water hazard class (WGK) 1, low hazard to waters (Classification according to AwSV, Annex 1)

Not available.

Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Chemical safety assessments for substances in this mixture were not carried out.

16.) OTHER INFORMATION Other information:

Full text of R-, H- and EUH-phrases:

PC32 SU0

Intrastat code 4001 29 00

Aquatic Acute 1 Hazardous to the aquatic environment – Acute Hazard,

Category 1

Aquatic Chronic 1 Hazardous to the aquatic environment – Chronic

Hazard, Category 1

Aquatic Chronic 3 Hazardous to the aquatic environment – Chronic

Hazard, Category 3

Eye Dam. 1 Serious eye damage/eye irritation, Category 1

Skin Corr. 1A Skin corrosion/irritation, Category 1A

STOT SE 3 Specific target organ toxicity – Single exposure, Category 3, Respiratory tract irritation

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

H335 May cause respiratory irritation

H400 Very toxic to aquatic life

H410 Very toxic to aquatic life with long lasting effects

H412 Harmful to aquatic life with lasting effects Full text of use descriptions

Polymer preparations and compounds Other

SDS EU (REACH Annex II)

This information is based on our current knowledge and is intended to describe the product for the

purposes of health, safety and environmental requirements only. It should not therefore be construed

as guaranteeing any specific property of the product.

DISCLAIMER

The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.

Because we cannot anticipate or control the many different conditions under which this information

and our products may be used, we do not guarantee the applicability or the accuracy of this

information or the suitability of our products in any given situation. Users of our products should make

their own tests to determine the suitability of each such product for their particular purposes. The

products discussed are sold without such warranty, either expressed or implied.

References

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