Detergent Raw Materials.pdf

(1)

Raw Materials

for the

(2)

Index

page

A Fabric wash

Powder detergents, regular A-1001 to A-1003 4 – 6 Powder detergents, compact A-1004 to A-1005 7 – 8 Powder detergents, ultra compact A-1006 to A-1009 9 – 12 Heavy duty detergent, tabs A-2001 to A-2003 13 - 15 Heavy duty liquid detergents A-3001 to A-3004 16 – 19 Powder detergents for fine fabrics A-4001 to A-4002 20 – 21 Colour detergent powder A-5001 to A-5003 22 - 24 Liquid detergents for fine fabrics A-6002 to A-6007 25 - 30

Detergent Paste A 7001 31

B Fabric care

Fabric softener B-1001 to B-1005 32 – 36

C Dishwashing detergents

Hand diswashing detergent liquids C-1001 to C-1018 37 – 54 Automatic dishwashing detergent powders C-2001 to C-2009 55 – 63 Automatic dishwashing rinses C-3001 to C-3002 64 – 65 D Household cleaners

All purpose cleaners, liquid D-1001 to D-1010 66 – 75 Toilet and hygienic cleaners D-2001 to D-2008 76 - 83 Abrasive cleaners D-3001 to D-3002 84 - 85

Special cleaners D-4001 to D-4005 86 - 90

(3)

E Hand cleaners

Liquid soap E-1001 92

Hand washing pastes E-2001 to E-2003 93 – 95 F Industrial cleaners

Hard surface cleaners F-1001 to F-1003 96 - 98 Special cleaners F-2001 to F-2011 99 - 109 Bottle cleaners F-3001 to F-3006 110 – 115 Conveyor belt lubricants F-4001 to F-4002 116 - 117 G Vehicle cleaning

Car cleaning agents G-1001 to G-1014 118 - 131 Car dry-shine polishing G-2001 to G-2006 132 – 137

(4)

POWDER DETERGENT, REGULAR

A-1001

with SKS-6 Composition



SKS-6 (powder or granular) (Clariant) 21.3 %

Sodium carbonate or bicarbonate 6.7 %

Perborate tetrahydrate 25.0 %

_Peractive _(Clariant) _{2.2 %}

(types AC blue, AC green, AC white, AN)

Phosphonate 0.2 % _{Genapol OA 3070} _(Clariant) _{4.4 %} Enzymes 1.1 % Optical brighteners 0.2 % Perfume 0.2 % Foam suppressants 0.4 % Sodium sulphate to 100 %

REMARKS

Dosage: 135 g / wash for normally soiled laundry

(5)

POWDER DETERGENT, REGULAR

A-1002

with SKS-6 and Zeolite Composition

_{SKS-6 (powder or granular)} _(Clariant) _{8.3 %}

Zeolite A 8.3 %

Perborate tetrahydrate 25.0 %



Peractive (Clariant) 2.5 %

(types AC blue, AC green, AC white, AN)

Phosphonate 0.3 % Anionic surfactant 4.4 % _{Genapol OA 3070} _(Clariant) _{5.0 %} Polycarboxylate 2.5 % Enzymes 1.4 % Optical brighteners 0.3 % Perfume 0.3 % Foam suppressants 0.6 % Sodium sulphate to 100 % Remarks

(6)

POWDER DETERGENT, REGULAR

A-1003

with SKS-6 and Phosphate Composition



Sodium tripolyphosphate 22.2 % Perborate tetrahydrate 25.0 % Phosphonate 0.2 % Anionic surfactant 6.7 % _{Genapol OA 3070} _(Clariant) _{2.2 %} Polycarboxylate 1.5 % Enzymes 1.4 % Optical brighteners 0.3 % Perfume 0.3 % Foam suppressants 0.8 % Sodium sulphate to 100 % Remarks

(7)

POWDER DETERGENT, COMPACT

A-1004

with SKS-6 Composition 

Percarbonate 9.0 %

(types AC blue, ACgreen, ACwhite, AN, CB and CBS)

Phosphonate 0.3 % _{Genapol OA 3070} _(Clariant) _{6.0 %} Enzymes 1.5 % Optical brighteners 0.3 % Perfume 0.3 % Foam suppressants 0.6 % Sodium sulphate to 100 % Remarks

(8)

POWDER DETERGENT, COMPACT

A-1005



Zeolite A 11.3 %

Citric acid 4.5 %

Perborate monohydrate 16.9 %

(Types AC blue, AC green, AC white, AN, CB and CBS)

Phosphonate 0.4 % Anionic surfactant 6.0 %  Genapol OA 3070 (Clariant) 6.8 % Polycarboxylate 3.4 % Enzymes 1.9 % Optical brighteners 0.4 % Perfume 0.4 % Foam suppressants 0.8 % Sodium sulphate to 100 % Remarks

(9)

POWDER DETERGENT, ULTRA COMPACT

A-1006

with SKS-6 Composition 

Sodium bicarbonate 15.0 %

Sodium percarbonate 15.0 %

_{Peractive (types CB and CBS)} _(Clariant) _{5.0 %}

Phosphonate 0.5 % _{Genapol OA 3070} _(Clariant) _{10.0 %} Enzymes 2.5 % Optical brighteners 0.5 % Perfume 0.5 % Foam suppressants 1.0 % Sodium sulphate to 100 % Remarks

Dosage: 60-75 g / wash for normally soiled laundry

(10)

POWDER DETERGENT, ULTRA COMPACT

A-1007

Zeolite A 15.0 %

Citric acid 6.0 %

_{Peractive (types CB and CBS)} _(Clariant) _{5.0 %}

Phosphonate 0.5 % Anionic surfactant 8.0 % _{Genapol OA 3070} _(Clariant) _{9.0 %} Polycarboxylate 4.5 % Enzymes 2.5 % Optical brighteners 0.5 % Perfume 0.5 % Foam suppressants 1.0 % Sodium sulphate to 100 % Remarks

Dosage: 60 -75 g / wash for normally soiled laundry

(11)

POWDER DETERGENT, ULTRA COMPACT

A-1008

Zeolite A 30.0 %



Peractive (types CB and CBS) (Clariant) 6.0 %

Phosphonate 0.5 % Anionic surfactant 6.0 %  Genapol OA 3070 (Clariant) 4.0 % Polycarboxylate 6.0 % Enzymes 2.5 % Optical brighteners 0.5 % Perfume 0.5 % Foam suppressants 1.0 % Sodium sulphate to 100 % Remarks

Dosage: 60-75 g / wash for normally soiled laundry

(12)

Powder DETERGENT, Compact

A-1009

with SKS-6 Composition

Percarbonate 9.0 %



Peractive (Clariant) 3.0 %

(types AC blue, ACgreen, ACwhite, AN, CB and CBS)

Phosphonate 0.3 %

_{Genapol OA 050} _(Clariant) _{6.0 %}

_{TexCare SRA-100} _(Clariant) _{1.0 %}

Enzymes 1.5 % Optical brighteners 0.3 % Perfume 0.3 % Foam suppressants 0.6 % Sodium sulphate to 100 % Remarks

(13)

HEAVY DUTY DETERGENT, TABS

A-2001

_{Peractive (Types AN and CB)} _(Clariant) _{4.0 %}

_{SKS-6 DI} _(Clariant) _{25.0 %} _{Zeolite A} _{10.0 %} Anionics 14.0 % Nonionics 4.0 % Percarbonate 15.0 % Citric acid 5.0 % Polycarboxylate 4.0 % Sodium carbonate 13.0 %

(14)

HEAVY DUTY DETERGENT, TABS

A-2002

_{SKS-6 granular} _(Clariant) _{10.0 %} _{Zeolite A} _{15.0 %} Anionics 8.0 % Nonionics 7.0 % Percarbonate 15.0 % Citric acid 5.0 % Polycarboxylate 4.0 % Sodium carbonate 12.0 %

(15)

HEAVY DUTY DETERGENT, TABS

A-2003

_{TexCare SRA-100} _(Clariant) _{2.0 %}

_{SKS-6 DI} _(Clariant) _{25.0 %} _{Zeolite A} _{10.0 %} Anionics 14.0 % Nonionics 4.0 % Percarbonate 15.0 % Citric acid 5.0 % Polycarboxylate 4.0 % Sodium carbonate 13.0 %

(16)

HEAVY DUTY LIQUID DETERGENT

A-3001

36 % active Composition A Genapol OA 080 (Clariant) 12.0 % Fatty acid 14.0 % Potassium hydroxide (w=85 %) 2.6 % 1,2 Propanediol 2.0 % Optical brightener 0.2 % B Water (50°C) 39.6 %

C Trisodium citrate dihydrate 5.0 %

_{Hostapur SAS 60} _(Clariant) _{17.0 %}

_{Dequest 2066} _(Monsanto) _{4.0 %}

D Ethanol 3.0 %

Enzymes (amylase, protease) 0.6 %

Perfume, dye, preservative q.s.

Procedure

I Mix the components of A. II Add B and dissolve completely.

III Add the components of C one after another.

(17)

HEAVY DUTY LIQUID DETERGENT

A-3002

40 % active Composition

A Genapol OA 080 (Clariant) 12.0 %

B Optical brightener 0.2 %

C Coconut fatty acid 8.0 %

Potassium hydroxide (w = 85 %) 2.5 %

D Water (40 - 50°C) 34.2 %

E Hostapur SAS 60 (Clariant) 33.0 %

Sodium tetra borate hydrate 2.0 %

Sodium citrate dihydrate 2.0 %

F Dequest 2066 (Monsanto) 1.5 %

1,2-Propanediol 4.0 %

Procedure I Melt A.

II Add B and stir well. III Add the components of C.

IV Add D and dissolve completely by stirring thoroughly. V Add the components of E one after another.

(18)

HEAVY DUTY LIQUID DETERGENT

A-3003

D Water (40 - 50°C) 41.2 %

Sodium tetra borate hydrate 2.5 %

Sodium citrate dihydrate 5.0 %

F 1,2-Propanediol 5.0 %

Procedure I Melt A.

IV Add D and dissolve completely by stirring thoroughly. V Add the components of E one after another.

(19)

HEAVY DUTY LIQUID DETERGENT

A-3004

D Water (40 - 50°C) 76.8 %

F Perfume, dye, preservative q.s.

Procedure I Melt A.

IV Add D and dissolve completely by stirring thoroughly. V Add E.

(20)

POWDER DETERGENT FOR FINE FABRICS

A-4001

with phosphate Composition

_{Genapol OA 080} _(Clariant) _{3.0 %}

Sodium dodecyl benzene sulphonate 5.0 %

_{Thermphos NW} _(Thermphos) _{25.0 %}

Tallow soap, powder 1-3.0 %

Sodium disilicate 3.0 %

_{Sokalan CP 5} _(BASF) _{1.0 %}

Perfume q.s.

Sodium sulphate ad 100 %

Procedure

To be prepared by spray mix process. Therefore DDBS-Na must be employed in form of a spray dried powder. DDBS-Na paste is not suitable.

(21)

POWDER DETERGENT FOR FINE FABRICS

A-4002

without phosphate Composition

Sodium dodecyl benzene sulphonate 15.0 %

Zeolite A 20-25.0 %

Tallow soap, Powder 1-3.0 %

Sodium disilicate 3.0 %

_{Sokalan CP 5} _(BASF) _{2-3.0 %}

Perfume q.s.

Sodium sulphate ad 100 %

Procedure

To be prepared by spray mix process. Therefore DDBS-Na must be employed in form of a spray dried powder. DDBS-Na paste is not

(22)

COLOUR DETERGENT POWDER, CONCENTRATE

A-5001

Composition Anionic surfactant 7.0 % _{Genapol OA 080} ₍_Clariant) _{10.0 %} Soap 1.5 %  SKS-6 granular (Clariant) 35.0 % Sodium citrate 2.0 % Sodium bicarbonate 15.0 % Enzymes 2.0 % Polycarboxylate 5.0 % Polyvinyl pyrrolidone (PVP) 1.0 % _{TexCare SRC-1} _(Clariant) _{1.0 %} _{Tylose CR 1500 G2} _(Clariant) _{1.0 %} Silicone defoamer 0-0.5 % Sodium sulphate ad 100 %

REMARKS

Dosage 50 g for hardness range I + II Dosage 65 g for hardness range III Dosage 75 g for hardness range IV

(23)

COLOUR DETERGENT POWDER, CONCENTRATE

A-5002

Composition Zeolite A 33.0 % Anionic surfactant 8.0 % _{Genapol OA 080} _(Clariant) _{10.0 %} Soap 2.0 %  SKS-6 granular (Clariant) 10.0 % Sodium citrate 9.0 % Sodium carbonate 12.0 % Enzymes 2.0 % Polycarboxylate 7.0 % Polyvinyl pyrrolidone (PVP) 1.0 % _{TexCare SRC-1} _(Clariant) _{1.0 %} _{TyloseCR 1500 G2} _(Clariant) _{1.0 %} Silicone defoamer 0-0.5 % Sodium sulphate ad 100 %

REMARKS

(24)

COLOUR DETERGENT POWDER, CONCENTRATE

A-5003

Composition Anionic surfactant 7.0 % _{Genapol OA 080} _(Clariant) _{10.0 %} Soap 1.5 %  SKS-6 granular (Clariant) 17.0 %  SKS-6 HD (Clariant) 25.0 % Sodium citrate 2.0 % Sodium bicarbonate 8.0 % Enzymes 2.0 % Polyvinyl pyrrolidone (PVP) 1.0 % _{TexCare SRC-1} _(Clariant) _{1.0 %} _Tylose_{CR 1500 G2} _(Clariant) _{1.0 %} Silicone defoamer 0-0.5 % Sodium sulphate ad 100 %

REMARKS

(25)

LIGHT DETERGENT LIQUID

A-6002

10.8 % active Composition

A Hostapur SAS 60 (Clariant) 10.0 %

B Water (40°C) 76.0 %

C Genapol ZRO liquid (Clariant) 10.0 %

_{Genapol UD 080} _(Clariant) _{2.0 %}

D Sodium chloride 2.0 %

E Perfume, dye, preservative q.s.

Procedure

I Dissolve A in B.

II Add the components of C and stir thoroughly. III Adjust to the desired viscosity with D.

(26)

LIGHT DETERGENT LIQUID

A-6003

44 % active Composition A Genapol OA 080 (Clariant) 18.0 % Fatty acid 10.0 % Triethanolamine 10.6 % 1,2-Propanediol 5.0 % B Water (50-60°C) 17.4 %

C Trisodium citrate dihydrate 3.0 %

_{Hostapur SAS 60} _(Clariant) _{20.0 %}



Genapol LRO paste (Clariant) 6.0 %



Dequest 2066 (Monsanto) 4.0 %

D Ethanol 5.0 %

Procedure

I Blend A thoroughly.

II Add B and dissolve completely by stirring well.

III One after another, add the components of C and mix thoroughly. IV Finally, add D in the order given and homogenize.

(27)

LIGHT DETERGENT LIQUID

A-6004

30 % active Composition A Fatty acid 3.0 % Potassium hydroxide (w=85 %) 0.6 % B Water (40-50°C) 41.9 %

C Hostapur SAS 60 (Clariant) 23.3 %

_{Genapol ZRO liquid} _(Clariant) _{25.0 %}

D Citric acid monohydrate 0.2 %

Procedure

I Blend A.

II Add B and dissolve completely.

III One after another the components of C are added by stirring thoroughly. IV Finally D is added.

(28)

LIGHT DETERGENT LIQUID

A-6005

_{Genapol UD 080} _(Clariant) _{24.0 %}

D Citric acid monohydrate 0.2 %

Procedure

I Blend A.

III One after another the components of C are added by stirring thoroughly. IV Finally D is added.

(29)

LIGHT DETERGENT LIQUID

A-6006

D TexCare SRC-1 Dispersion (Clariant) 4.0 %

Citric acid monohydrate 0.2 %

Procedure

I Blend A.

III One afer another the components of C are added by stirring thoroughly. IV Fianlly add D in the order given.

(30)

LIGHT DETERGENT LIQUID

A-6007

7 % active, for wool Composition

A Hostapur SAS 60 (Clariant) 4.2 %

B Water 77.7 %

C Genapol LRO liquid (Clariant) 8.9 %

_{Genagen CAB 818} _(Clariant) _{6.7 %}

Procedure

I A is dissolved in B.

II One after another the components of C are added by stirring well. III Finally add D to regulate the viscosity.

Remarks

pH (t.q.) 5.2

(31)

DETERGENT PASTE

A-7001

Composition

A Tylose CBR 10000 G1 (Clariant) 3.0 %

B Water (20-25°C) 50.0 %

Sodium chloride 8.0 %

D TexCare SRC-1 Dispersion (Clariant) 4.0 %

Procedure

I Add A to B with continuous stirring. Let it swell over night if possible, to obtain a gel free of lumps.

II Then add C one after another and homogenize well. III Finally add D.

(32)

FABRIC SOFTENER

B-1001

A Praepagen WK (Clariant) 6.7 %

B Water (50-60°C) 93.2 %

C Magnesium chloride (w=10 % in deionized. water) 0.1 %

D Perfume, dye q.s.

Procedure

I Disolve A in B.

II Cooling down to 40°C, adjust the viscosity with C. III At 30°C add D.

Remarks

(33)

FABRIC SOFTENER

B-1002

5 % active Composition A Triethanolamine diesterquat (85 %) 5.88 % B Water 89.55 % C Genapol UD 088 (Clariant) 0.57 % D Perfume, dye q.s.

_{TexCare SRC-1 Dispersion} _(Clariant) _{4.00 %}

Procedure

I Melt A at 50°C. II Heat B to 50°C.

III Stir I into II, then add C.

IV Cool mixture down to 30°C, then add D one after another.

Remarks

Viscosity (Brookfield, spindle 1, 20 rpm) approx. 40 –65* mPas * Depending on procedure and MgCl2 dosage

(34)

FABRIC SOFTENER

B-1003

11.5 % active Composition A Genamin S 250 (Clariant) 0.90 % Phosphoric acid (w= 9.5 %) 0.45 % Water (50-60°C) 80,15 % B Praepagen WK (Clariant) 13.80 % Polyglycol 400 (Clariant) 3.70 %

C Magnesium chloride (w=10 % in deionized water) 1.00 %

D Perfume, dye q.s.

Procedure

I Mix the components of A.

II One after another, the components of B are added to A II After cooling to 40°C, adjust the viscosity with C III At 30°C the components of D are added.

(35)

FABRIC SOFTENER

B-1004

15 % active Composition A Genamin S-250 (Clariant) 2.0 % Phosphoric acid (1 M; w=9,5 %) 1.0 % B Water (50-60°C) 76.7 % C Praepagen WK (Clariant) 17.3 %

D Magnesium chloride (w=10 % in deionized water) 3.0 %

E Perfume, dye q.s.

Procedure

I Mix the components of A in 50-60°C in B. II Add C and dissolve well.

III After cooling down to 40°C, adjust the viscosity with D (ca. 100-150 mPas). IV At 30°C, the components of E are added.

(36)

FABRIC SOFTENER

B-1005

15 % active Composition A Triethanolamine diesterquat (85 %) 17.65 % B Water 76.14 % C Genapol UD 088 (Clariant) 1.11 %

D Magnesium chloride hexahydrate (w=20 %) 0.50 %

E Perfume, dye q.s.

_{TexCare SRC-1 Dispersion} _(Clariant) _{4.00 %}

F Magnesium chloride hexahydrate (w=20 %) 0.15 %

Procedure

I Melt A at 50°C. II Heat B to 50°C.

III Stir I into II, then add C. IV Add D to reduce viscosity.

V Cool mixture down to 30°C, then add E one after another. VI If necessary, the viscosity can be adjusted with F at the end.

Remarks

Viscosity (Brookfield, spindle 1, 20 rpm) approx. 60 - 100* mPas * Depending on procedure and MgCl2 dosage

(37)

DISHWASHING LIQUID

C-1001

clear, 9 % active Composition

B Water 64.0 %

_{Genagen CAB 818} _(Clariant) _{3.3 %}

Procedure

I Dissolve A in B

II Add the components of C one after another and stir thoroughly. III Finally add the components of D and homogenize well.

Remarks

Ratio: alkane sulphonate : alkyl ether sulphate = 1 : 1

Viscosity: Brookfield RVT, spindle 2, 20 rpm: 530 mPas

(38)

DISHWASHING LIQUID

C-1002

Water 65.5 %

_{Genapol ZRO liquid} _(Clariant) _{17.8 %}

Procedure

One after another the components are mixed thoroughly.

Remarks

(39)

DISHWASHING LIQUID

C-1003

B Water 56.2 %

_{Genagen CAB 818} _(Clariant) _{6.7 %}

Procedure

I Dissolve A in B.

Remarks

(40)

DISHWASHING LIQUID

C-1004



Genapol LRO liquid (Clariant) 29.6 %

B Water 48.7 %

C Urea 1.0 %

D Perfume, dye, preservative q.s.

Procedure

I Dissolve the components of A in B. II Add the components of C.

III Finally add D and homogenize.

Remarks

pH value (t.q. at rt) 5.9

Viscosity (Brookfield RVT, 20°C, spindle 2, 20 rpm) 165 mPas

Cold cloud point -10 up to -3°C

(turbid sample becomes solid, subsequent temperature increase)

(41)

DISHWASHING LIQUID

C-1005

clear, 25 % active (contains sweet powdered whey) Composition

B Water 43.7 %

C Genapol LRO liquid (Clariant) 14.3 %



Genagen LAB (Clariant) 1.6 %

D Serusweet 83 (F.H. Diedrichs) 6.0 %

E Acticide SPX-(L) (Thor-Chemie) 0.2 %

Procedure

I Dissolve A in B.

II Add the components of C by mixing thoroughly. III Then add D.

IV Finally the components of E are stirred in.

(42)

DISHWASHING LIQUID

C-1006



Genagen CAB (Clariant) 8.0 %



Genagen 24 MEE 080 (Clariant) 6.0 %

B Water 44.0 %

C Perfume, dye, preservative q.s.

Procedure

I Dissolve the components of A in B with stirring thoroughly but slowly. II Finally add C.

Remarks

pH value (t.q. at rt) 5.5

Viscosity (Brookfield RVT, 20°C, spindle 2, 20 rpm) 300 mPas

Cold cloud point -11°C

(43)

DISHWASHING LIQUID

C-1007

B Water 31.4 %

_{Genagen 81 MEE 100} _(Clariant) _{4.0 %}

_{Genaminox LA} _(Clariant) _{4.3 %}

D Citric acid solution q.s.

Procedure

I Dissolve A in B.

II Add the components of C in the order given and mix thoroughly. III Adjust the pH with D.

IV Finally add the components of E.

(44)

DISHWASHING LIQUID

C-1008

B Water 28.3 %

C Perfume, dye, preservative q.s.

Procedure

I Dissolve the components of A in B with slow but thorough stirring, then add C.

Remarks

(45)

DISHWASHING LIQUID

C-1009

B Water 24.4 %



Genagen CAB (Clariant) 10.0 %

Procedure

I Dissolve A in B.

II Add the components of C one after another with slow but thorough stirring. III Add D.

Remarks

(46)

DISHWASHING LIQUID

C-1010

B Water 33.6 %

Procedure

I Dissolve A in B.

Remarks

(47)

DISHWASHING LIQUID

C-1011

clear, 36 % active, with terpene Composition

B Water 14.8 %

D Limonene 4.0 %

PEG 400 (Clariant) 4.0 %

Procedure

I Dissolve A in B.

II Add the components of C one after another with stirring thoroughly but slowly. III Add the components of D, finally add E.

Remarks

pH value (t.q., 25°C) 6.15

Viscosity (Brookfield RVT, 20°C, spindle 2, 20 rpm 2) 400 mPas

Cold cloud point +14°C

(48)

DISHWASHING LIQUID

C-1012

clear, 36 % active, with terpene and sodium hydrogen carbonate Composition

A Sodium hydrogen carbonate 2.0 %

B Water 34.7 %

C Hostapur SAS 60 (Clariant) 43.8 %

_{Genapol LRO paste} _(Clariant) _{12.5 %}

Limonene 1.0 %

D PEG 400 (Clariant) 5.0 %

Procedure

I Dissolve A in B.

II Mix C by stirring thoroughly. III Stir I into II and dissolve well. IV Add finally D and homogenize.

Remarks

pH value (t.q. at 25°C) 8.4

Viscosity at 20°C, Brookfield RVT, spindle 2, 20 rpm) 350 mPas

Cold cloud point +13°C

(49)

DISHWASHING LIQUID

C-1013

B Water 21.4 %

_{Genagen CAB} _(Clariant) _{10.0 %}

_{Genagen UD 080} _(Clariant) _{3.0 %}

Procedure

I Dissolve A in B.

Remarks

(50)

DISHWASHING LIQUID

C-1014

B Water 22.3 %

Procedure

I Dissolve A in B completely.

II One after another the components of C are added by stirring thoroughly. III Finally the components of D are added.

Remarks

(51)

DISHWASHING LIQUID WITH ANTIBACTERIAL

MATTER

C-1015

B Water 14.2 %

_{Sandoteric ABD} _(Clariant) _{8.0 %}

D Ethanol 2.0 %

Urea 2.0 %

Procedure

I Dissolve A in B.

Remarks

(52)

DISHWASHING LIQUID

C-1016

B Water 2.9 %

D Ethanol 3.0 %

Urea 2.0 %

Procedure

I A is dissolved in B. II C is added.

III The components of D are added one after another by mixing thoroughly.

Remarks

(53)

DISHWASHING LIQUID

C-1017

_{Genapol LRO paste} _(Clariant) _{14.3 %}

B Water 30.4 %

C Genagen CAB (Clariant) 10.0 %

Procedure

I Blend the components of A. II Add B by stirring thoroughly.

III Add C and mix well, afterwards add the components of D.

Remarks

(54)

DISHWASHING LIQUID, CONCENTRATE

C-1018

B Water 14.0 %

Procedure

I Dissolve A in B.

II Then add the components of C and homogenize well.

Remarks

(55)

AUTOMATIC DISHWASHING DETERGENT, POWDER

C-2001

Phosphate-free, with SKS-6 Composition

_{SKS-6 HD} _(Clariant) _{31.0 %}

Sodium carbonate (Solvay Interox) 19.2 %

Sodium citrate 30.0 %

Percarbonate 10.0 %



Peractive (types AC blue, ACgreen, ACwhite) (Clariant) 5.0 %

Enzymes 3.0 %

_{Genapol 2909} _(Clariant) _{1.5 %}

Perfume 0.3 %

Remarks

Soilings: light medium heavy

(56)

AUTOMATIC DISWASHING DETERGENT, POWDER

C-2002

reduced phosphate-content, with SKS-6 Composition



Makrophos 1018 (BK-Giulini) 25.0 %

_{SKS-6, granular} _(Clariant) _{15.0 %}

Sodium carbonate (Solvay Interox) 30.0 %

Sodium sulphate (Solvay Interox) 7.2 %

Perborate monohydrate (Degussa) 10.0 %

_{Sokalan CP 45} _(BASF) _{5.0 %}

_{Peractive CB} _(Clariant) _{2.0 %}



Genapol 2822 (Clariant) 1.5 %

Perfume 0.3 %

Remarks

Soiling: light medium heavy

(57)

AUTOMATIC DISHWASHING DETERGENT, POWDER

C-2003

phosphate containing, with SKS-6 Composition



Makrophos 1018 (BK-Giulini) 40.0 %

_{SKS-6 powder} _(Clariant) _{15.0 %}

Sodium carbonate (Solvay Interox) 20,7 %

Perborate monohydrate (Degussa) 10.0 %



Sokalan CP 45 (BASF) 3.5 %

_{Peractive CB} _(Clariant) _{2.0 %}

Enzymes (Amylase, Protease) 3.0 %



Perfume 0.3 %

Remarks

Soiling: light medium heavy Dosage: 20 mL 25 mL 30 mL

(58)

AUTOMATIC DISHWASHING DETERGENT

C-2004

with SKS-6 granular Composition



SKS-6 granular (Clariant) 10.0 %

3 NaG (disilicate) (Clariant) 12.0 %

Sodium carbonate 22.2 %

_{Sokolan CP 5} _(BASF) _{7.5 %}

Trisodium citrate dihydrate 30.0 %

Percarbonate 10.0 %

_{Peractive AC blue, ACgreen, ACwhite} _(Clariant) _{5.0 %}

Enzymes (protease, amylase) 1.5 %

Perfume 0.3 %

Remarks

(59)

AUTOMATIC DISHWASHING DETERGENT

C-2005

with SKS-6 granular Composition _{SKS-6 granular} _(Clariant) _{20.0 %} Sodium carbonate 24.2 % _{Sokolan CP 5} _(BASF) _{7.5 %}

Trisodium citrate dihydrate 30.0 %

Percarbonate 10.0 %

_{Peractive AC blue, ACgreen, ACwhite} _(Clariant) _{5.0 %}



Perfume 0.3 %

Remarks

(60)

AUTOMATIC DISHWASHING DETERGENT

C-2006

with SKS-6 granular, phosphat containing Composition _{SKS-6 granular} _(Clariant) _{10.0 %} Sodium tripolyphosphate 45.0 % Sodium carbonate 27.4 % _{Sokalan CP 5} _(BASF) _{2.3 %} Perborate tetrahydrate 10.0 % _{Peractive CB} _(Clariant) _{2.0 %}

Perfume 0.3 %

Remarks

(61)

AUTOMATIC DISHWASHING DETERGENT

C-2007

with SKS-6 granular reduced phosphate content Composition _{SKS-6 granular} _(Clariant) _{15.0 %} Sodium tripolyphosphate 25.0 % Sodium carbonate 30.0 % Sodium sulphate 9.2 % _{Sokalan CP 5} _(BASF) _{5.0 %} Perborate tetrahydrate 10.0 % _{Peractive CB} _(Clariant) _{2.0 %}

Perfume 0.3 %

Remarks

(62)

AUTOMATIC DISHWASHING DETERGENT

C-2008

with SKS-6 HD, with phosphate Composition _{SKS-6 HD} _(Clariant) _{7.1 %} Sodium tripolyphosphate 48.0 % Sodium carbonate 29.6 % Perborate tetrahydrate 10.0 %  Peractive CB (Clariant) 2.0 %

Perfume 0.3 %

Remarks

(63)

AUTOMATIC DISHWASHING DETERGENT, GEL

C-2009

with SKS-6 fine powder Composition

Water 17.5 %

Sodium hydroxide 1.0 %

Sodium carbonate 4.0 %



SKS-6 fine powder (Clariant) 5.5 %



Dequest 2000 (Monsanto) 0.5 %

_{Sokalan CP 5} _(BASF) _{1.5 %}

Sodium silicate (w=45.5 %) 37.0 %

_{Hordaphos 158} _(Clariant) _{0.5 %}

Sodium hypochlorite (15.0 g/l activechlorine) 8.0 %

_{Makrophos 1018} _(BK-Giulini) _{23.0 %}

Remarks

(64)

AUTOMATIC DISHWASHING RINSE

C-3001

Ingredients

A Genapol 2908 (Clariant) 14.0 %

Citric acid 3.0 %

Sodium cumene sulphonate, 40 % 8.0 %

B Water 75.0 %

Procedure

I The components of A are dissolved one after another in B.

Remarks

(65)

AUTOMATIC DISHWASHING RINSE

C-3002

Ingredients

A Genapol 2909 (Clariant) 14.0 %

Citric acid 3.0 %

Sodium cumene sulphonate, 40 % 5.0 %

B Water 78.0 %

Procedure

I The components of A are dissolved one after another in B.

Remarks

(66)

ALL PURPOSE CLEANER

D-1001

A Sandosan LNBA (Clariant) 2.3 %

Propylene glycol n-butyl ether 2.0 %

B Water 93.2 %

Sodium hydroxide solution to regulate the pH value

Procedure

I Dissolve the components of A in B.

II If necessary regulate the pH value to 3 – 3.5.

Remarks

(67)

ALL PURPOSE CLEANER

D-1002

acidic, 5 % active Composition

Polycarboxylate 2.0 %

Propylene glycol n-butyl ether 0.5 %

Lactic acid 0.3 %

B Water 91.5 %

Procedure

I Dissolve the components of A in B.

Remarks

pH-value about 3.3

(68)

ALL PURPOSE CLEANER

D-1003

contains hydrogen peroxide, low foaming, 5 % active Composition

B Water 80.0 %

C Ethanol 2.5 %

Hydrogen peroxide (35% by weight) 4.3 %

D Sodium hydroxide solution q.s.

Procedure

I Dissolve the components of A with about 80 % of B. II Add C with stirring.

III Regulate the pH value with D and fill up with water to 100 %

Remarks

(69)

ALL PURPOSE CLEANER

D-1004

liquid, with orange terpene and with pearl lustre effect, 6.8 % active Composition

B Water 75.3 %

_{Genapol LA 040} _(Clariant) _{0.5 %}

_{Genagen CAB} _(Clariant) _{5.0 %}

D Genapol TSM (Clariant) 1.7 %

Orange terpene 0.2 %

Preservative, dye, perfume q.s.

Procedure

I Dissolve A in B.

II Add one after another the components of C.

(70)

ALL PURPOSE CLEANER

D-1005

8 % active Composition A Sandosan LNBS (Clariant) 10.0 % _{Genapol UD 080} _(Clariant) _{3.0 %} B Water 84.0 %

C Tri-sodium citrate dihydrate 3.0 %

Procedure

I Dissolve the components of A in B. II Add C to I.

III If necessary regulate the pH value.

Remarks

pH value about 8.5

(71)

ALL PURPOSE CLEANER

D-1006

B Lactic acid 0.5 %

Propylene glycol-n-butylether 0.5 %

C Water 84.0 %

D Preservative, dye, perfume q.s.

Procedure

II Dissolve the components of B in C. III Add II to I.

(72)

ALL PURPOSE CLEANER WITH ANTIBACTERIAL

MATTER

D-1007

liquid, 10 % active Composition

_{Sandoteric ABD liquid} _(Clariant) _{4.0 %}

B Water 80.0 %

C Ethanol 3.0 %

Preservative, dye, perfume q.s.

Procedure

I Dissolve one after another the components of A in B. II Finally add C.

Remarks

(73)

ALL PURPOSE CLEANER

D-1008

contains hydrogen peroxide, strong degreasing, 10 % active Composition

B Water 66.0 %

C Genapol UD 080 (Clariant) 2.5 %

_{Genaminox CST} _(Clariant) _{5.0 %}

D Ethanol 2.2 %

Hydrogen peroxide (35% by weight) 4.3 %

E Sodium hydroxide solution q.s.

Procedure

I Dissolve the components of A with about 80 % of B. II Add C and D with stirring.

(74)

ALL PURPOSE CLEANER

D-1009

B Tri-sodium citrate dihydrate 2.0 %

C Water 81.3 %

Procedure

I Mix the components of A. II Dissolve B in C.

III Add II to I. IV Finally add D.

(75)

ALL PURPOSE CLEANER

D-1010

clear, liquid, 14 % active Composition

B Water 77.7 %

C Propylene glycol n-butylether 3.0 %

Cumene sulphonate 2.0 %

Procedure

I Mix the components of A. II Add B and dissolve well. III Add the components of C. IV Finally add D.

(76)

BATHROOM CLEANER

D-2001

Composition

A Isopropanol 3.0 %

Water 89.5 %

B Hostapur SAS 60 (Clariant) 3.0 %

C Lactic acid 3.0 %

_{Hordaphos CC MS} _(Clariant) _{1.0 %}

Dye, perfume q.s.

Procedure

I Mix the ingredients of A.

II Add the components of B with stirring well. III Finally add the components of C one after another.

(77)

TOILET BOWL AND HYGIENIC CLEANER

D-2002

Composition

 Genapol UD 050 (Clariant) 3.0 % _{Genaminox CSL} _(Clariant) _{5.0 %} Citric acid* 10.0 % B Water 74.5 % C Dye, perfume q.s. Procedure

I Dissolve the components of A in B one after another. II Add C.

(78)

TOILET BOWL AND HYGIENIC CLEANER

D-2003

high concentrate Composition

A Citric acid 15.0 %

B Water 34.0 %

_{Genamin O 080} _(Clariant) _{9.0 %} Phosphoric acid 15.0 %  Hordaphos CC MS (Clariant) 15.0 % Procedure I Dissolve A in B.

(79)

ACIDIC HOUSEHOLD CLEANER

D-2004

Composition A Lactic acid 5.0 % Water 75.0 % B Genamin O 080 (Clariant) 3.0 % _{Genapol UD 080} _(Clariant) _{3.0 %}

_{Hordaphos CC MIN} _(Clariant) _{10.0 %}

C Potassium hydroxide (w=85 %) 4.0 %

Procedure

II Add the components of B with stirring well. III Adjust the pH value with C to pH 2.

(80)

ACIDIC CLEANER

D-2005

clear, liquid Composition

B Water (about 40°C) 71.3 %

C Genapol LA 070 (Clariant) 1.8 %

D Citric acid 18.0 %

Perfume, preservative, dye q.s.

Procedure

I Dissolve A in B completely. II Add C and stir well.

(81)

ACIDIC CLEANER

D-2006

Composition

A p-Toluene sulfonic acid monohydrate 0.6 %

Phosphoric acid 18.0 %

Water 77.1 %

B Genamin CTAC (Clariant) 4.3 %

Procedure

I Mix the ingredients of A. II Then add B with stirring well.

Remarks

(82)

HARD SURFACE CLEANER WITH SODIUM

HYPOCHLORITE

D-2007

Composition

A Genaminox LA (Clariant) 3.0 %

B Water 68.5 %

C Sodium hydroxide (w=100 %) 1.0 %

Sodium hypochlorite solution (150 g/L active chlorine) 25.0 %

D Perfume, dye q.s.

Procedure

I Mix the components of A with B.

II Add the components of C with stirring thoroughly. III Finally add D.

(83)

THICKENED CLEANER WITH SODIUM

HYPOCHLORITE

D-2008

Composition A Genaminox MY (Clariant) 12.0 % _{Medialan LD} _(Clariant) _{2.5 %} Sodium hydroxide (w=100 %) 1.0 % B Water 34.5 %

C Sodium hypochlorite solution (150 g/l active chlorine) 50.0 %

D Perfume q.s.

Procedure

I Mix the ingredients of A with B. II Add C with stirring well.

(84)

ABRASIVE CLEANER

D-3001

Composition

B Water (40-50°C) 50.1 %

C Calibrite SL (Calcium carbonate) (Omya GmbH) 40.0 %

Procedure

I One after another, the components of A are added to B and dissolved. II At about 30°C add C.

(85)

ACIDIC ABRASIVE CLEANER

D-3002

Composition

Acetic acid* (w=99,8 %) 3.3 %

Water 66.2 %

B Alsigran 25 (Quartz powder) (Alpha Calcit Füllstoff GmbH, KG) 18.8 %

Procedure

I Mix the components of A with a good fitting blade stirrer at 100 to 110 rpm for about 30 min.

II Allow mixture to stand undisturbed for 3 hours

III With a stirring rate of 100-110 rpm, disperse B in the formulation within 15 min. IV Stir for further 30 minutes.

(86)

GLASS CLEANER

D-4001

Composition

A Genapol LRO liquid (Clariant) 0.5 %

B Water 70.0 % C Isopropanol 29.0 % Ammonia (w= 25 %) 0.5 % Dye, preservative q.s. Procedure: I Mix A with B.

(87)

FLAGSTONE CLEANER

D-4002

Composition A Citric acid 5.0 % Water 79.0 % B Genamin O 080 (Clariant) 3.0 % _{Genapol OX 080} _(Clariant) _{3.0 %} C Hordaphos CC MS (Clariant) 5.0 % Phosphoric acid 5.0 % Procedure

II Add the componetns of B and dissolve. III Add the coponents of C.

(88)

GRILL AND OVEN CLEANER

D-4003

Composition

A Water 66.9 %

Potassium hydroxide(w= 85%) 2.1 %

2-Aminoethanol 18.0 %

C Isopropanol 5.0 %

Diethyleneglycol-monobutylether 5.0 %

_{Hordaphos MDGB} _(Clariant) _{2.0 %}

Procedure

I Mix the components of A. II Add B with stirring well.

(89)

HIGH PRESSURE CLEANER

D-4004

Composition

A Genapol UD 050 (Clariant) 2.5 %

_{Genopur ASA} _(Clariant) _{3.0 %}

Potassium hydroxide (w= 85 %) 5.0 %

B Water (50°C) 67.0 %

C Sodium metasilicate penta-hydrate 10.0 %

NTA-solution (40 %) (e.g. Trilon A) 10.0 %

Procedure

I Mix the components of A thoroughly. II Add B and dissolve well.

(90)

CARPET SHAMPOO

D-4005

Composition

A Hostapur OS liquid (Clariant) 25.0 %

_{Medialan LD} _(Clariant) _{3.0 %}

B Water 72.0 %

C Preservative, dye q.s.

Procedure

I One after another, add the components of A to B. II Add C.

(91)

UNIVERSAL SCOURING PASTE

D-5001

Composition

A Tylose CBR 10000 G1 (Clariant) 5.0 %

B Water (50°C) 51.8 %

Cocos fatty acid diethanolamid 0.7 %

Preservative, perfume q.s.

Procedure

I Add A to B with continuous stirring, allowing A to swell, to obtain a homogeneous gel free of lumps.

II One after another, add the components of C. III Add D and homogenize well.

(92)

LIQUID SOAP, WITH PEARL LUSTRE EFFECT

E-1001

Composition

B Water 43.9 %

_{Genapol PGM} _(Clariant) _{4.0 %}

_{Genapol LA 030} _(Clariant) _{3.0 %}

E Sodium chloride 1.1 %

Procedure

I Dissolve A in B.

II One after another add the components of C with stirring thoroughly. III Add the components of D.

IV If necessary adjust the pH. V Adjust the viscosity with E.

(93)

HANDCLEANER GEL

E-2001

Composition A Genapol UD 030 (Clariant) 5.0 % Oleic acid 4.0 % Triethanolamine 2.0 % Preservative q.s.

B Genapol ZRO liquid (Clariant) 15.0 %

Water 29.0 %

C Shellsol D 70 (Shell AG) 25.0 %

Procedure

II One after another add the components of B. III Heat to 80°C, then add C with stirring very fast. IV Fill in PE-bottles immediately.

(94)

HANDCLEANER PASTE

E-2002

Composition

A Genapol UD 030 (Clariant) 5.0 %

Oleic acid 4.0 %

Triethanolamine 2.0 %

_{Genapol LRO liquid} _(Clariant) _{15.0 %}

Plastic abrasives (powder or fine granules) 5.0 %

Water (45°C) 42.0 %

Preservative q.s.

C Citrus terpene (Eramex) 5.0 %



Genapol LA 030 (Clariant) 2.0 %

Procedure

II One after another add the components of B. III Add the components of C and homogenize well.

(95)

HANDCLEANER PASTE

E-2003

Composition A Genapol UD 050 (Clariant) 4.0 % Oleic acid 3.0 % Triethanolamine 1.5 % Paraffin oil 5.0 % _{Tylose CR 1500 W} _(Clariant) _{2.0 %} B Water (50°C) 50.0 % Preservative q.s.

Citrus terpene (Eramex) 5.0 %

D Plastic abrasives 17.0 %

Procedure

I Mix and dissolve the components of A in B. It is necessary to allow the Tylose to swell, over approx. 30 min. with stirring accasionally.

(96)

ALL PURPOSE CLEANER

F-1001

liquid

Composition

A Tetra potassium pyrophosphate solution (60 %) 10.0 %

B Water 62.0 %

C NTA-solution (e.g. Trilon A) (40%) (e.g. BASF) 2.0 % Sodium cumolsulphonate (40%) (Condea) 5.0 %

_{Genaminox LA} _(Clariant) _{6.0 %}

D Citrusterpene 5.0 %

Procedure

I Dissolve A in B.

II Stir in the components of C one after another and stir until mixture has cooled. III Dissolve D in II.

Remarks

(97)

ALL PURPOSE CLEANER

F-1002

liquid, strongly degreasing Composition

A Genopur ASA (Clariant) 3.5 %

Potassium hydroxide solution (45%) 4.7 %

B Water 73.5 %

C Tetra potassium pyrophosphate solution (60%) 8.3 %

D Hostapur SAS 60 (Clariant) 5.0 %

_{Genamin O 080} _(Clariant) _{5.0 %}

Procedure

I Add the components of A to B. II Dissolve C in I.

III Finally add the components of D.

Remarks

(98)

ALL PURPOSE CLEANER

F-1003

A Hostapur SAS 60 (Clariant) 10 - 15 %



Genapol LRO liquid (Clariant) 0 - 4 %

_{Genapol UD 080} _(Clariant) _{1 - 3 %} B Water ad 100 % Perfume q.s. Preservative q.s. Dye q.s. Procedure

I Add one after another the components of B to A.

Remarks

(99)

CLEANER FOR MEAT PLANTS

F-2001

liquid

Composition

Potassium hydroxyde solution (45%) 6.7 %

B Water 64.5 %

C Tetra potassium pyrophosphate solution (60%) 8.3 % Potassium waterglass (approx. 30°Be) 10.0 %

D Hostapur SAS 60 (Clariant) 5 %

_{Genapol UD 080} _(Clariant) _{2 %}

Procedure

I Stir the components of A into B II Add C to I

III Stir the omponents of D into II

Remarks

(100)

SANITIZER

F-2002

liquid, cloudy Composition

A Hostapur SAS 30 (Clariant) 15 %

 Genapol UD 050 (Clariant) 3 % B Water 67 % C Hordaphos CCMS (Clariant) 10 % _{Genaminox CSL} _(Clariant) _{5 %} Procedure:

I Dissolve the components of A one after another in B. II Finally stir in the components of C one after another.

Remarks

(101)

SANITIZER

F-2003

Composition

A Fatty acid 1.5 %

B Water 70.4 %

D Trisodium citrate 5.0 %

Procedure

I Mix the components of A and dissolve in B of about 40°C. II Then stir in the components of C.

III Finally add D and stir homogeneous.

(102)

TILE CLEANER

F-2004

liquid, acidic Coamposition

A Citric acid monohydrate 5 %

B Water 79 %

C Genamin O 080 (Clariant) 3 %

_{Genapol OX 050} _(Clariant) _{3 %}

_{Hordaphos CC MIN} _(Clariant) _{10 %}

Procedure

I Dissolve A in B.

II Stir the components of C one after another into I.

Remarks

Using 10 % aqueous solution. The ceramic surfaces must be wetted before application of the cleaner and rinse with water afterwards.

(103)

TANK CLEANER

F-2005

special high pressure cleaner, liquid, clear, alkaline Composition

B Water 62.6 %

C Genapol UD 050 (Clariant) 2.5 %

D Sodium tripolyphosphate (Thermphos) 10.0 %

E Sodium metasilicate x 5 H2O 10.0 %

Procedure

I Dissolve the components of A in B at 60°C.

II Dissolve the components of C one after another in I. III Add D to II and stir clear

IV Finally dissolve E in III.

Remarks

(104)

CARPET EXTRACTION CLEANER

F-2006

A Potassium tripolyphosphate solution (50%) 15.0 %

Sodium cumolsulphonate (40%) (Condea) 1.5 %

Butyl diglycol 2.0 %

B Water 79.5 %

Procedure

Dissolve the components of A one after another in B.

Remarks Use undiluted

(105)

CARPET EXTRACTION CLEANER

F-2007

A Medialan LD (Clariant) 3 %



Hostapur OS liquid (Clariant) 25 %

Preservative q.s. %

B Water 72 %

Procedure

Dissolve the components of A one after another in B of about 40°C.

Remarks Dosage: 1:8

(106)

CLEANER FOR INDUSTRIAL AUTOMATIC

DISHWASHING MACHINES

F-2008

Composition

A Liquid Potassium Silicate KA/1 (Clariant) 22.7 %

Potassium hydroxide solution (50%) 15.6 % Potassium tripolyphosphate solution (50%) 18.0 % Sodium hypochlorite solution (150 g/l active chlorine) 30.0 %

B Water 13.7 %

Procedure

Remarks:

H2O2 solution alternatively to sodium hypochlorite solution in separate dosage:

(107)

CLEANER FOR INDUSTRIAL DISHWASHING

MACHINES

F-2009

Composition

A Liquid Potassium Silicate KA/1 (Clariant) 10 %

Potassium hydroxide solution (45%) 20 %

Potassium tripolyphosphate solution (50%) 15 % Sodium hypochlorite solution (150 g/l active chlorine) 20 %

B Water 35 %

Procedure

Remarks

(108)

INDUSTRIAL HAND CLEANER

F-2010

Composition

A Genapol UD 030 (Clariant) 4 %

Oleic acid 4 %

Triethanol amine 2 %

B Hostapur SAS 60 (Clariant) 8 %



Genapol LRO liquid (Clariant) 10 %

Citrusterpene 3 %

Glycerin 2 %

Preservative q.s.

C Kelzan S (Kelco) 1 %

D Water 51 %

E Walnut shell granule (e.g. Rehofix UNG 300) (e.g. Rettenmeyer) 15 %

Procedure

I Mix the components of A at 60°C. II Add the components of B.

III Dissolve C in D (perhaps with Ultra Turrax) while stirring and add to II. IV Finally add E.

Remarks Use undiluted