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Chiral wide bite angle diphosphine ligands : synthesis, coordination chemistry and application in Pd catalyzed allylic alkylation

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Figure

Fig. 2 Chiral DPEPhos ligand 7, hybrid analogues 8 and 9 and P-stereogenic derivative 10
Fig. 3 (top) Schematic representation of the potentially modular approach with modified
Fig. 4 ORTEP representation of compound 13. Displacement ellipsoids are drawn at the 50%
Table 2 IR and 31P{1H} NMR data of [Ni(L)(CO)2] of selected modified DPEPhos ligands
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