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Comparison of Structural Relaxation Behavior in As Cast and Pre Annealed Zr Based Bulk Metallic Glasses Just below Glass Transition

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Figure

Table 1The diameter dc, Tg and Tx of rod-shaped BMGs. The BMGs witha diameter of 3 mm or 8 mm were prepared by suction cupper-moldcasting or tilted cupper-mold casting, respectively.
Fig. 1Volume changes, ¦V/Vas and ¦V/Vp, of (a) as-cast, (b) pre-annealed (715 K) Zr55Cu30Ni5Al10 BMGs during isothermal structuralrelaxation at various temperatures below Tg.
Fig. 4Saturation values of volumes, (¦V/Vas)eq, obtained from fittingvolume relaxation data in Fig
Fig. 6Relaxation times, ¸M and ¸NTM, modified by Moynihan andNarayanaswamy-Tool-Moynihanmethodsareshowntogetherwithisothermal relaxation time, ¸¡ (open symbols)

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