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Reactivity and Mechanism in Oxidative Addition to Palladium(II) and Reductive Ellmlnation from Palladium(IV) and an Estimate of the Palladium Methyl Bond Energy

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Academic year: 2020

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Figure

Table I. Second-Order Rate Constants for Oxidative Addition of Me1 to [MMe2(bpy)] in Acetone
Figure 2. value at high constant A graph of ( 1 0 % ~  - 1.45)-' vs concentration of iodide for the reductive elimination of ethane from [PdIMeJbpy)] in acetone at 20 "C, where kobsd/s-l is the observed first-order rate for the reaction
Figure 4, though decomposition of the palladium complex is more exothermic.

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