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Kinetics of lithium peroxide oxidation by redox mediators and consequences for the lithium–oxygen cell

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Figure

Fig. 2 TOF-SIMS of LiLi1 M LiTFSI in tetraglyme. Both Li2O2 disks before and after treating with electrolyte of2O2 disks show signal of Li2O2+ and2CO3+ whereas the Li2CO3 disk shows little signal of Li2O2+, confirmingthe presence of Li2O2 on the surface of disk after treating with theelectrolyte
Fig. 3 Dependence of the apparent rate constant,heterogeneous electron transfer rate constant, kapp, on the ko, of the mediators.Amines, nitroxy and thiol compounds are marked in blue, red and green

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