Luprintol Multifunction SL-S MSDS

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Safety Data Sheet in accordance with

Regulation (EU) No.453/2010

Luprintol Multifunction SL-S

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Substance key: B0174 Revision Date: 25.06.2015 Version : 1 - 1 / EU Date of printing : 16.11.2015

SECTION 1: Identification of the substance/mixture and of the

company/undertaking

1.1. Product identifier Trade name

Luprintol Multifunction SL-S Material number: 281301

1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses of the substance or mixture

Industry sector : Textile processing industry Type of use : Auxiliary for the textile industry

1.3. Details of the supplier of the safety data sheet Identification of the company

Archroma Management GmbH

Neuhofstrasse 11

4153 Reinach, Switzerland Telephone no. : +41 61 716 3401

Information about the substance/mixture

Product Stewardship +41 61 716 3401 e-mail: [email protected]

1.4. Emergency telephone number

+44 (0) 1235 239 670 (24 h)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according CLP regulation (Regulation (EC) No. 1272/2008, as amended)

Not a dangerous substance according to GHS.

2.2. Label elements

Labelling according CLP regulation (Regulation (EC) No. 1272/2008, as amended)

Not a dangerous substance according to GHS.

Sensitizing components / contains :

Formaldehyde

May produce an allergic reaction.

2.3. Other hazards

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SECTION 3: Composition/information on ingredients

3.2. Mixtures Chemical characterization in aqueous/organic dispersion Polycondensed Nonionic surfactants Hazardous ingredients Diethylene glycol Concentration : >= 1 - < 3 % CAS number : 111-46-6 EC number: 203-872-2 Index Number 603-140-00-6 Classification hazard substance EC

Xn Harmful R22

GHS classification EC

Acute toxicity Category 4 H302

Specific target organ toxicity - repeated exposure Category 2 H373 Propan-2-ol Concentration : >= 0,1 - < 1 % CAS number : 67-63-0 EC number: 200-661-7 Index Number 603-117-00-0 Classification hazard substance EC

F Highly flammable R11

Xi Irritant R36

R67 GHS classification EC

Flammable liquids Category 2 H225

Eye irritation Category 2 H319

Specific target organ toxicity - single exposure

Category 3 H336 Methanol Concentration : > 0,1 - < 1 % CAS number : 67-56-1 EC number: 200-659-6 Index Number 603-001-00-X Classification hazard substance EC

F Highly flammable R11

T Toxic R23/24/25

R39/23/24/25 GHS classification EC

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Specific target organ toxicity - single exposure

Category 1 H370 Formaldehyde Concentration : < 0,1 % CAS number : 50-00-0 EC number: 200-001-8 Index Number 605-001-00-5 Classification hazard substance EC

Carc.Cat.3 Carcinogenic Category 3 R40

T Toxic R23/24/25

C Corrosive R34

R43 GHS classification EC

Skin corrosion Category 1B H314

Skin sensitisation Category 1 H317

Carcinogenicity Category 2 H351

The text of the R-phrases is shown in section 16. The text of the H-phrases is shown in section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures General information

Remove/Take off immediately all contaminated clothing.

After inhalation

Remove person to fresh air. If signs/symptoms continue, get medical attention.

After contact with skin

After contact with skin, wash immediately with plenty of soap and water. Get medical attention immediately if irritation persists.

After contact with eyes

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If eye irritation persists, consult a specialist.

After ingestion

Rinse out mouth and give plenty of water to drink.

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Symptoms

The possible symptoms known are those derived from the labelling (see section 2). No symptoms known currently.

Hazards

No additional hazards are known except those derived from the labelling.

4.3. Indication of any immediate medical attention and spe cial treatment needed Treatment

There is no specific antidote available.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

Water spray Dry powder Foam

5.2. Special hazards arising from the substance or mixture

In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO) Carbon dioxide (CO2)

Nitrogen oxides (NOx)

5.3. Advice for firefighters Further information

The degree of risk is governed by the burning substance and the fire conditions Extinguishing water is to be disposed of in accordance with local aut hority regulations

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Self-contained breathing apparatus

6.2. Environmental precautions

The product should not be allowed to enter drains, water courses or the soil.

6.3. Methods and material for containment and cleaning up

Pump up larger quantities.

Pick up rest with absorbent material (e.g. sand, sawdust). Dispose of absorbed material in accordance with the regulations.

6.4. Reference to other sections Additional information

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SECTION 7: Handling and storage

7.1. Precautions for safe handling Advice on safe handling

No special measures necessary if stored and handled as prescribed.

Hygiene measures

Do not eat, drink or smoke when using this product.

7.2. Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers

Keep containers tightly closed in a cool, well-ventilated place. Should not be released into the environment.

Advice on storage compatibility

Keep away from food, drink and animal feeding stuffs.

Further information on storage conditions

Keep tightly closed in a dry, cool and well-ventilated place.

Storage stability

Storage temperature: 5 - 40 °C

7.3. Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters Exposure limit values

methanol

EC number: 200-659-6 CAS number : 67-56-1

Regulatory basis / Regulatory list Revision Type of value Values Remarks

Europe. Indicative occupational exposure limit values

EU. Commission Directive 2006/15/EC

2006-02-09 Limit Value - eight hours 260 mg/m3 200 ppm DNEL/DMEL values Formaldehyde EC number: 200-001-8 CAS number : 50-00-0

Route of exposure Personnel Exposure time/Effect Value Remarks

Inhalation Workers Acute systemic effects 1 mg/m3

0,8 ppm

DNEL

Inhalation Workers Acute local effects 1 mg/m3

0,8 ppm

DNEL

Inhalation Workers Long-term systemic effects 0 mg/m3

0,4 ppm

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Inhalation Workers Long-term local effects 0 mg/m3

0,4 ppm

DNEL

Dermal Workers Long-term systemic effects 240 mg/kg DNEL

Dermal Consumers Long-term systemic effects 102 mg/kg DNEL

Oral Consumers Long-term systemic effects 4,1 mg/kg DNEL

Dermal Consumers Long-term local effects 0,012 mg/cm2 DNEL

Inhalation Consumers Long-term systemic effects 3,2 mg/l DNEL

Inhalation Consumers Long-term local effects 0,1 mg/m3 DNEL

PNEC values Formaldehyde EC number: 200-001-8 CAS number : 50-00-0 Environmental compartment

Personnel/Exposure time/Effect Value

Fresh water 0,47 mg/l salt water 0,47 mg/l Water (intermittent release) 4,7 mg/l Fresh water sediment 2,44 mg/l Marine sediment 2,44 mg/l Soil 0,21 mg/l Sewage treatment plant 0,19 mg/l 8.2. Exposure controls

Respiratory protection : Protection necessary if aerosols or vapors should develop. P2 filter

Hand protection : Chemical resistant gloves

Take note of the information given by the producer concerning permeability and break through times, and of special

workplace conditions (mechanical strain, duration of contact).

Eye protection : Safety glasses with side-shields conforming to EN166

Body protection : The choice of skin protection should be based on the job activity and potential for exposure to the skin.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties Physical state : liquid ( 20 °C )

Form : liquid

Particle size : not applicable

Colour : white yellowish

Odour : Product specific

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pH value : approx. 8 - 10 (20 °C) (undiluted)

Melting point : not applicable

Boiling point : not determined

Sublimation point : not applicable

Flash point : > 100 °C

Method : DIN 51758

Evaporation rate : Value can be approximated from Henry's Law Constant or vapor pressure.

Flammability : The product is not flammable. Method : Flash point

Lower explosion limit : Not relevant

The lower explosion point may be 5 - 15 °C below the flash point.

Upper explosive limit : Not relevant

Combustion number : not applicable

Minimum ignition energy : not tested.

Vapour pressure : not applicable

Solubility in water : soluble

Octanol/water partition coefficient (log Pow) :

Study scientifically not justified.

Ignition temperature : not determined

Self-ignition temperature : not auto-flammable

Thermal decomposition : No decomposition if used as directed.

Viscosity (dynamic) : not determined

Explosive properties : Explosive according to EU supply regulations : Not explosive Explosive according transport regulation : Not explosive

Oxidizing properties : Type of oxidizing effect : not oxidizing

9.2. Other information

Density : approx. 1,1 g/cm3 (20 °C)

SECTION 10: Stability and reactivity

10.1. Reactivity

No dangerous reaction known under conditions of normal use.

10.2. Chemical stability

Stable under normal conditions.

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No dangerous reaction known under conditions of normal use.

10.4. Conditions to avoid

Avoid Heat, Open Flames And Sparks.

10.5. Incompatible materials

Strong acids Strong bases

Strong oxidizing agents

10.6. Hazardous decomposition products

No hazardous decomposition products are known.

SECTION 11: Toxicological information

11.1. Information on toxicological effects Information related to the product itself:

Acute oral toxicity : LD50 > 2.000 mg/kg (rat)

Acute dermal toxicity : not tested.

Acute inhalation toxicity : not tested.

Irritant effect on skin : No skin irritation (rabbit)

Method : OECD Test Guideline 404

Irritant effect on eyes : No eye irritation (rabbit)

Method : OECD Test Guideline 405

Sensitization : not tested.

Repeated dose toxicity: not tested.

Genetic toxicity in vitro : not tested.

Assessment of mutagenicity : Based on the ingredients, there is no suspicion of a mutagenic

effect.

Assessment of carcinogenicity :

The whole of the information assessable provides no indication of a carcinogenic effect.

Specific target organ toxicity (STOT) - repeated exposure :

According to experience and to the information available, the product has no harmful effects on health if used correctly and for the intended purpose.

The product has not been tested. The information is derived from the properties of the individual components.

Aspiration hazard :

No aspiration toxicity classification

Remarks

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Information related to the component: Propan-2-ol Acute oral toxicity : LD50 5.280 mg/kg (rat)

Acute dermal toxicity : LD50 12.800 mg/kg (rabbit)

Acute inhalation toxicity : LC50 72,6 mg/l (4 h, rat)

Information related to the component: Methanol

Acute oral toxicity : LD0 428 mg/kg (Humans)

Acute toxicity estimate 100 mg/kg

Method : Converted acute toxicity point estimate

Acute dermal toxicity : Acute toxicity estimate 300 mg/kg

Information related to the component: Formaldehyde Acute oral toxicity : LD50 800 mg/kg (rat)

Acute toxicity estimate 100 mg/kg

SECTION 12: Ecological information

12.1. Toxicity

Information related to the product itself:

Fish toxicity : LC50 > 100 mg/l (96 h, Leuciscus idus (Golden orfe))

Daphnia toxicity : not tested.

Algae toxicity : not tested.

Bacteria toxicity : not tested.

Information related to the component: Propan-2-ol

Fish toxicity : Test data for the substance are not available.

Fish toxicity : LC50 19.000 mg/l (96 h, Oncorhynchus mykiss (rainbow trout))

Daphnia toxicity : LC50 > 10.000 mg/l (24 h)

Bacteria toxicity : IC50 > 1.000 mg/l (3 h, activated sludge)

12.2. Persistence and degradability

Information related to the product itself: Biodegradability : 20 - 70 % (28 d)

Moderately/partially eliminated from water. Method : Zahn-Wellens Test

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Biodegradability : 95 %

Readily biodegradable.

Information related to the component: Methanol Biodegradability : 99 % (28 d)

Method : OECD Test Guideline 301D

12.3. Bioaccumulative potential

Information related to the product itself: Bioaccumulation: not tested.

Bioaccumulation: Test data for the substance are not available.

Bioaccumulation: Due to the low logPow bioaccumulation is not expected

12.4. Mobility in soil

Information related to the product itself: Behaviour in environmental compartments

no data available

Information related to the component: Propan-2-ol Transport and distribution

between environmental compartments :

Test data for the substance are not available.

12.5. Results of PBT and vPvB assessment Information related to the product itself:

According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH):The product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or t he vPvB (very persistent/very bioaccumulative) criteria.

no data available

12.6. Other adverse effects

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Additional ecotoxicological remarks

Product must not be released into water without pre-treatment. If handled correctly it causes no disturbance in treatment plants.

Information related to the component: Propan-2-ol Additional ecotoxicological remarks

slightly water endangering

SECTION 13: Disposal considerations

13.1. Waste treatment methods Product

Product should be be taken to a suitable and authorized waste disposal site in

accordance with relevant regulations and if necessary after consultation with the waste disposal operator and/or the competent Authorities

Uncleaned packaging

Uncontaminated packaging may be reused

Packaging material which cannot be cleaned is to be disposed of in the same way as the substance.

SECTION 14: Transport information

Section 14.1. to 14.5.

ADR not restricted

ADN not restricted

RID not restricted

IATA not restricted

IMDG not restricted

14.6. Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code (International Bulk Chemicals Code)

No transport as bulk according IBC - Code.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

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Other regulations

Apart from the data/regulations specified in this chapter, no further information is available concerning safety, health and environmental protection.

15.2. Chemical safety assessment

No Chemical Safety Assessment (CSA) is yet available for the substance, or for the component substances, contained in this product.

SECTION 16: Other information

Product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with legal regulations. The information contained herein is based on the present state of our knowledge and is intended to describe our produc ts from the point of view of safety requirements. It should therefor not be construed as garanteeing specific properties.

Text of the R-phrases assigned to the ingredients/components mentioned in section 3 :

R11 Highly flammable. R22 Harmful if swallowed.

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R34 Causes burns.

R36 Irritating to eyes.

R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.

R40 Limited evidence of a carcinogenic effect. R43 May cause sensitisation by skin contact. R67 Vapours may cause drowsiness and dizziness.

List of the text of the hazard statements mentioned section 3 (H-phrases) :

H225 Highly flammable liquid and vapour. H301 Toxic if swallowed.

H302 Harmful if swallowed. H311 Toxic in contact with skin.

H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation. H331 Toxic if inhaled.

H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H370 Causes damage to organs.

H373 May cause damage to organs through prolonged or repeated exposure if swallowed.

Legend

ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways

ADR European Agreement concerning the International Carriage of Dangerous Goods by Road

AOX Adsorbable organic bound halogens CAS Chemical Abstracts Service

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DNEL Derived No Effect Level

EC50 Half maximal effective concentration GHS Globally Harmonized System

IATA International Air Transport Association IMDG International Maritime Dangerous Goods LC50 Lethal Concentration 50%

LD50 Lethal Dose 50%

MARPOL International Convention for the Prevention of Pollution From Ships NOAEC No Observed Adverse Effect Concentration

NOAEL No Observed Adverse Effect Level NOEC Non Observed Effect Concentration OEL Occupational Exposure Limit PBT Persistent, Bioaccumulative, Toxic PEC Predicted Environmental Concentration PNEC Predicted No Effect Concentration

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals RID International Rule for Transport of Dangerous Substances by Railway SVHC Substances of Very High Concern

vPvB very Persistent and very Bioaccumulative

This information corresponds to the present state of our knowledge and is intended as a general description of our products and their possible applications. Archroma makes no warranties, express or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and assumes no liability in connection with any use of this information. Any user of this product is responsible for determining the suitability of Archroma's products for its particular application. Nothing included in this information waives any of Archroma's General Terms and Conditions of Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial property rights must be observed. Due to possible changes in our products and applicable nat ional and international regulations and laws, the status of our products could change. Material Safety Data Sheets providing safety precautions, that should be observed when handling or storing Archroma products, are available upon request and are provided in compliance with applicable law. You should obtain and review the applicable Material Safety Data Sheet information before handling any of these products. For additional information, please contact Archroma.