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Synthesis of ZIF 93/11 hybrid nanoparticles via post synthetic modification of ZIF 93 and their use for H2/CO2 separation

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Figure

Figure 1. Solid-state 13C CP MAS NMR spectra of ZIF-93 (bottom), hybridmaterials synthesised in DMAc and MeOH (middle) and ZIF-11 (top)
Figure 3. TGA curves and derivatives (inset) in flowing air. From bottom to top: ZIF-93 (black), ZIF-93/11 hybrid (DMAc) (red), ZIF-93/11 hybrid (MeOH) (blue) and ZIF-11 (green)
Figure 4. SEM images of ZIF-93 (a), ZIF-93/11 hybrid material (DMAc, b), ZIF-93/11 hybrid (MeOH, d) and ZIF-11 (e)
Figure 5. N2 (77 K, a) and CO2 adsorption (0 °C, b) isotherms of ZIF-93 (black),
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