Trimethylolpropane Monoallyl Ether

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1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

Product identifier

Product Name

Trimethylolpropane Monoallyl Ether

Chemical Name CAS No

2-Allyloxymethyl-2-ethylpropanediol 682-11-1

Other means of identification

Pure substance/mixture Substance

Recommended use of the chemical and restrictions on use

Application Chemical intermediate.

Uses advised against Formation of acrolein (very toxic) can occur in oxidative drying systems catalyzed by metal salts, for example alkyd paints.

Details of the supplier of the safety data sheet

E-mail address [email protected]

Emergency telephone number

Europe (+)1 760 476 3961 (contract no: 334101)

Americas (+)1 760 476 3962 (contract no: 334101)

Middle East and Africa (+)1 760 476 3959 (contact no: 334101)

Asia Pacific (+)1 760 476 3960 (contract no: 334101)

2. HAZARDS IDENTIFICATION

Hazards description

In contact with air/oxygen the product will slowly form peroxides.

Classification of the substance or mixture

Acute toxicity - Oral Category 5 - (H303)

Label elements

Symbols/Pictograms Not applicable Signal word Warning Hazard statements

H303 - May be harmful if swallowed

Precautionary statements

P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Contains: 2-Allyloxymethyl-2-ethylpropanediol

Other hazards

Manufacturer

Perstorp Specialty Chemicals AB

SE-284 80 Perstorp, Sweden Tel. +46 435 380 00

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None known.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance

Chemical Name CAS No Weight-%

2-Allyloxymethyl-2-ethylpropanediol 682-11-1 90-100

4. FIRST AID MEASURES

Description of first aid measures

Inhalation First aid measures not required, but get fresh air for personal comfort.

Skin contact First aid measures not required, but wash exposed skin with soap and water for hygienic reasons.

Eye contact Rinse thoroughly with plenty of water, also under the eyelids. Use lukewarm water if possible.

Ingestion Rinse mouth then drink plenty of water. If a large quantity has been ingested or if you feel unwell, get medical advice/attention.

Most important symptoms and effects, both acute and delayed

None known.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment

Unsuitable extinguishing media

High volume water jet.

Specific hazards arising from the chemical

Thermal decomposition can lead to release of irritating and toxic gases and vapors.

Hazardous combustion products

Carbon monoxide (CO). Carbon dioxide (CO2). May emit small amounts of toxic fumes under fire conditions: Allyl alcohol and acrolein.

Protective equipment and precautions for firefighters

Wear self-contained breathing apparatus and protective suit.

Additional information

Cool containers with flooding quantities of water until well after fire is out.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Wear safety glasses, gloves, protective clothing and rubber boots for hygienic reasons.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Minimize the area spreading and cover the drains. Do not allow to enter sewers/ surface or ground water. See Section 12 for additional ecological information.

Methods and material for containment and cleaning up

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Small spill Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Take up mechanically, placing in appropriate containers for disposal. Large spill Pump up the product into a spare container suitably labelled.

Methods for cleaning up

Clean contaminated surface thoroughly. Use: Water (with cleaning agent).

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin, eyes or clothing. Use personal protection recommended in Section 8.

General Hygiene Considerations

Handle in accordance with good industrial hygiene and safety practice.

Conditions for safe storage, including any incompatibilities

Keep/store only in original container. Keep tightly closed in a dry and cool place. Hygroscopic. Keep away from heat. Protect from direct sunlight. In contact with air/oxygen the product will slowly form peroxides. Can form peroxides when stored in opened, unsealed containers. For additional information regarding peroxide formation, see Perstorp Technical information, Leaflets TI 1120 and TI 1110.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Users are advised to consider national Occupational Exposure Limits or other equivalent values, (if existing).

Appropriate engineering controls

No specific measures identified.

Individual protection measures, such as personal protective equipment

Eye/face protection If handled where risk of splashes may occur, use safety goggles.

Hand Protection Recommendation(s): Wear protective gloves. Butyl rubber, Chloroprene rubber, CR, Nitrile rubber, NBR. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on breakthrough time for specific gloves.

Skin and body protection Normal work clothes for the chemical industry (long-legged pants and sleeves). Respiratory protection None under normal use conditions.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance

Physical state liquid

Appearance viscous

Color colorless

Odor Slight

Odor threshold No data available

Property Value Remarks • Method

pH 6.9 solution (10 %)

Melting point / freezing point < -20 °C / -4 °F

Boiling point / boiling range 272 °C / 522 °F ASTM E 537-02

Flash point 140 °C / 284 °F ASTM D 7094-04

Evaporation rate No information available

Flammability (solid, gas) Not applicable

Explosive limits

Upper explosive limits No information available Lower explosive limits No information available

Vapor pressure 0.035 Pa Calculation method SPARC, @25°C

Vapor density No information available

Relative density 1.01 OECD Test No. 109: Density of Liquids and Solids

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Other Information

Hygroscopic

10. STABILITY AND REACTIVITY

Reactivity

There exists no specific test data for this product. For further information, see the subsequent subsections of this chapter.

Chemical stability

In contact with air/oxygen the product will slowly form peroxides.

Possibility of Hazardous Reactions

In contact with air/oxygen the product will slowly form peroxides. Formation of acrolein (very toxic) can occur in oxidative drying systems catalyzed by metal salts, for example alkyd paints.

Conditions to avoid

None under normal use conditions.

Incompatible materials

Oxidizing substances including air (oxygen).

Hazardous decomposition products

Thermal decomposition can lead to release of irritating and toxic gases and vapors: Allyl alcohol and acrolein, Carbon monoxide (CO), Carbon dioxide (CO2).

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Inhalation. Dermal.

Symptoms related to the physical, chemical and toxicological characteristics

Most important symptoms and effects, both acute and delayed

None known.

Numerical measures of toxicity

Acute toxicity

2-Allyloxymethyl-2-ethylpropanediol (682-11-1)

Method Species Exposure route Effective dose Remarks no guideline Rat Oral 4930 mg/kg LD50 (lethal

dose) no guideline rabbit Dermal >15800 mg/kg LD50 (lethal

dose)

Skin corrosion/irritation

Non-irritating to the skin.

Solubility(ies) soluble in: Alcohols, Ketone.

Partition coefficient 1.4 OECD Test No. 117: Partition Coefficient (n-octanol/water), HPLC Method

Autoignition temperature 285 °C / 545 °F @101.3 kPa, Regulation (EC) No. 440/2008, Annex, A.15

Decomposition temperature No information available

Kinematic viscosity No information available

Dynamic viscosity 173 mPa s @ 20 °C OECD Test No. 114: Viscosity of Liquids

Explosive properties Not explosive. May form explosive peroxides.

Oxidizing properties Not oxidizing.

Density No information available

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Method Species Exposure route Results: OECD Test No. 404: Acute Dermal

Irritation/Corrosion

rabbit Dermal Non-irritating to the skin

Serious eye damage/eye irritation

Slightly irritating but not relevant for classification.

Method Species Exposure route Results: OECD Test No. 405: Acute Eye

Irritation/Corrosion

rabbit Eye Slightly irritating but not relevant for classification

Respiratory or skin sensitization

No sensitising effects known.

Method Species Exposure route Results: OECD Test No. 406: Skin

Sensitization

Guinea pig Skin Not a skin sensitizer

Germ cell mutagenicity

Not mutagenic.

Method Species Results:

OECD Test No. 471: Bacterial Reverse Mutation Test

in vitro Negative

OECD Test No. 476: In vitro Mammalian Cell Gene Mutation Test

in vitro Positive; read-across from supporting substance (structural analogue) OECD Test No. 474: Mammalian Erythrocyte

Micronucleus Test

Mouse Negative

Carcinogenicity

Not considered to be carcinogen.

Reproductive toxicity

Is not considered hazardous to the reproduction.

Method Species Exposure route Effective dose Remarks OECD Test No. 414: Prenatal

Development Toxicity Study

Rat Oral 800 mg/kg bw/day NOEL (No observed effect level) No embryotoxic

or teratogenic effects have been observed. read-across from supporting substance

(structural analogue)

STOT - single exposure No information available

STOT - repeated exposure

Method Species Exposure route Effective dose Remarks OECD Test No. 408:

Repeated Dose 90-Day Oral Toxicity Study in Rodents

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(structural analogue) OECD Test No. 407:

Repeated Dose 28-day Oral Toxicity Study in Rodents

Rat Oral 40 mg/kg bw/day NOAEL

Aspiration hazard

No hazard identified.

12. ECOLOGICAL INFORMATION

Toxicity

Low toxicity to aquatic organisms.

Method Species Exposure route Effective dose Exposure time Remarks OECD Test No. 203: Fish,

Acute Toxicity Test

Brachydanio rerio Freshwater 1200 96h mg/l; LC50 (lethal concentration) OECD Test No. 202:

Daphnia sp. Acute Immobilization Test

Daphnia magna Freshwater 1530 48h mg/l EC50 (effective concentration) OECD Test No. 201:

Freshwater Alga and Cyanobacteria, Growth Inhibition Test Pseudokirchneriell a subcapitata Freshwater 610 72h mg/l; EC50 (effective concentration)

OECD Test No. 201: Freshwater Alga and Cyanobacteria, Growth

Inhibition Test

Pseudokirchneriell a subcapitata

Freshwater 125 72h mg/l NOEC

OECD Test No. 209: Activated Sludge, Respiration Inhibition Test

(Carbon and Ammonium Oxidation) Microorganisms in sewage treatment Freshwater >1000 3h mg/l EC50 (effective concentration); read-across from supporting substance (structural analogue)

Persistence and degradability

Not readily biodegradable. The substance is inherently biodegradable and therefore has no potential to persist.

Method Value Exposure time Results: OECD Test No. 302B: Inherent

Biodegradability: Zahn-Wellens/ EVPA Test

31% 28d Inherently biodegradable

OECD Test No. 301A: Ready Biodegradability: DOC Die-Away

Test (TG 301 A)

4% 14d Not readily biodegradable

Bioaccumulative potential

No bioaccumulation potential.

Chemical Name Partition coefficient Bioconcentration factor (BCF)

2-Allyloxymethyl-2-ethylpropanediol 1.4

Mobility in soil

The substance is not expected to adsorb to a high degree to suspended solids and sediment based upon the log Pow.

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None known

13. DISPOSAL CONSIDERATIONS

Disposal methods

Waste from residues/unused products

Disposal should be in accordance with applicable regional, national and local laws and regulations

Contaminated packaging

Thoroughly emptied and clean packaging may be recycled. Contaminated packaging materials must be disposed of in the same manner as the product.

14. TRANSPORT INFORMATION

ADR Road transport

Not regulated

RID Rail transport

Not regulated

IMDG Sea transport

Not regulated

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

No information available

IATA Air transport

Not regulated

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

International Regulations Not applicable. National Regulations Argentina Not applicable Malaysia Not applicable Russia Not applicable Singapore Not applicable Thailand Not applicable Vietnam No information available

16. OTHER INFORMATION

Key or legend to abbreviations and acronyms used in the safety data sheet

Not applicable

Issue Date 23-Jun-2021

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Revision Note SDS sections updated: 2 Precautionary statements

This safety data sheet complies with the requirements of: Globally Harmonized System (GHS). Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text