Product code: 1010-2-071
Print date: 13.06.2013 Page 1 of 5
SECTION 1: Identification of the substance/mixture and of the company/undertaking 6% AFFF DC-6
1.1. Product identifier
1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture
Fire extinguishing agent, AFFF 1.3. Details of the supplier of the safety data sheet
TYCO Fire Protection Products Company name:
Marinette, WI, USA One Stanton Street Street: USA Marinette, WI 541 43-2542 Place: Telephone: +1-715-735-7411 Telefax: +1-715-732-3579 https://www.ansul.com Internet:
Department for Health, Safety and Environment Responsible Department:
+1-800-424-9300 1.4. Emergency telephone
number:
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
This mixture is not classified as dangerous according to Directive 1999/45/EC. GHS classification
Hazard categories:
Serious eye damage/eye irritation: Eye Irrit. 2 Hazard Statements:
Causes serious eye irritation. 2.2. Label elements
Signal word: Warning
Pictograms: GHS07
H319 Causes serious eye irritation. Hazard statements
P264 Wash with water thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention. Precautionary statements
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Aqueous surfactant solution. Chemical characterization
Hazardous components GHS classification Quantity Classification CAS No REACH No Index No EC No Chemical name 15 - 20 % 2-(2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether
203-961-6 Xi - Irritant R36 112-34-5 Eye Irrit. 2; H319 603-096-00-8 1 - 5 % Magnesium Sulfate (Heptahydrate)
231-298-2 10034-99-8
Acute Tox. 4, Acute Tox. 4, Acute Tox. 4; H302 H312 H332
1 - 5 % Perfluorinated Amphoteric Surfactant
Proprietary
Skin Irrit. 2, Eye Irrit. 2A; H315 H319
< 1 % Perfluoro Telomer
R20-36/37 Proprietary
Acute Tox. 4, Skin Irrit. 3, Eye Irrit. 2, STOT SE 3; H332 H316 H319 H335
Full text of R and H phrases: see Section 16. SECTION 4: First aid measures
4.1. Description of first aid measures Provide fresh air. After inhalation
In case of skin irritation, seek medical treatment. After contact with skin
Rinse immediately carefully and thoroughly with eye-bath or water. After contact with eyes
Rinse mouth thoroughly with water. After ingestion
SECTION 5: Firefighting measures
5.1. Extinguishing media
Extinguishing materials should be selected according to the surrounding area. Suitable extinguishing media
none/none
Unsuitable extinguishing media
5.2. Special hazards arising from the substance or mixture none/none
SECTION 6: Accidental release measures Provide adequate ventilation.
6.1. Personal precautions, protective equipment and emergency procedures
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the assimilated material according to the section on waste disposal.
Product code: 1010-2-071
Print date: 13.06.2013 Page 3 of 5
SECTION 7: Handling and storage
7.1. Precautions for safe handling Avoid contact with skin. Advice on safe handling
7.2. Conditions for safe storage, including any incompatibilities Keep container tightly closed.
Requirements for storage rooms and vessels
SECTION 8: Exposure controls/personal protection
8.1. Control parameters Exposure limits (EH40)
Category fibres/ml mg/m³ ppm Substance CAS No Origin TWA (8 h) 10 2-(2-Butoxyethoxy)ethanol 112-34-5 67.5 WEL STEL (15 min) 15 101.2 WEL 8.2. Exposure controls
Tightly sealed safety glasses. Eye/face protection
Wear protective gloves. Hand protection
Skin protection: not required. Skin protection
With correct and proper use, and under normal conditions, breathing protection is not required. Respiratory protection
light yellow liquid Physical state:
Colour:
9.1. Information on basic physical and chemical properties
SECTION 9: Physical and chemical properties
characteristic Odour:
Test method Changes in the physical state
SECTION 10: Stability and reactivity
10.3. Possibility of hazardous reactions none/none
none/none 10.4. Conditions to avoid
Alkali metals. 10.5. Incompatible materials
Nitrogen oxides (NOx). Sulfur oxides. Carbon dioxide. Carbon monoxide. 10.6. Hazardous decomposition products
11.1. Information on toxicological effects Toxicocinetics, metabolism and distribution
Mixture not tested.
Mixture not tested. Acute toxicity Chemical name CAS No Species Dose Method
Exposure routes Source
112-34-5 2-(2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether Rat LD50 5660 mg/kg oral Rabbit LD50 4120 mg/kg dermal
10034-99-8 Magnesium Sulfate (Heptahydrate)
ATE 500 mg/kg oral
ATE 1100 mg/kg dermal
inhalative vapour ATE 11 mg/l inhalative aerosol ATE 1.5 mg/l Proprietary Perfluoro Telomer
inhalative vapour ATE 11 mg/l inhalative aerosol ATE 1.5 mg/l
Mixture not tested. Irritation and corrosivity
Mixture not tested. Sensitising effects
Mixture not tested.
Severe effects after repeated or prolonged exposure Carcinogenic/mutagenic/toxic effects for reproduction
Mixture not tested.
Mixture not tested.
Specific effects in experiment on an animal
SECTION 12: Ecological information Mixture not tested. 12.1. Toxicity
CAS No Chemical name
h
Aquatic toxicity Method Dose Species Source
2-(2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether 112-34-5
Acute algae toxicity ErC50 > 100 mg/l Scenedesmus sp. Acute crustacea toxicity EC50 > 100 mg/l 48 Daphnia magna
Mixture not tested. 12.2. Persistence and degradability
Mixture not tested. 12.3. Bioaccumulative potential
Product code: 1010-2-071
Print date: 13.06.2013 Page 5 of 5
Partition coefficient n-octanol/water
Log Pow CAS No Chemical name
112-34-5 2-(2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether 0,56 (25°C)
Mixture not tested. 12.4. Mobility in soil
No special environmental protection measures are necessary. Further information
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal according to official state regulations. Contaminated packaging
SECTION 14: Transport information
Land transport (ADR/RID)
Not dangerous goods 14.1. UN number:
Inland waterways transport (ADN)
Not dangerous goods 14.1. UN number:
Marine transport (IMDG)
Not dangerous goods 14.1. UN number:
Air transport (ICAO)
Not dangerous goods 14.1. UN number:
14.5. Environmental hazards
no Dangerous for the environment:
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture National regulatory information
SECTION 16: Other information
Full text of R phrases referred to under Sections 2 and 3 20 Harmful by inhalation.
36 Irritating to eyes.
36/37 Irritating to eyes and respiratory system. Full text of H statements referred to under Sections 2 and 3
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H316 Causes mild skin irritation. H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)
