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Vogt Power Emission Control Solutions

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(1)

ONE SOURCE ONE PURPOSE MANY SOLUTIONS

Kelly Flannery

Chief Thermal Engineer

Kristen Cooper

Simple Cycle Design Lead

Andrew Heid

Emission Catalyst Design Lead

(2)

Vogt Power History

•1880 Founded by Henry Vogt

•1962 First HRSG

•1972 First 3 pressure HRSG

•1988 First Re-heat HRSG

•1988 First F-class HRSG

•2010 Fast Start Capabilities

•2011 Simple Cycle Exhaust Systems

•2013 Once Through Steam Generator

Vogt logo circa 1940

An Industry Leader with a Tradition

of Innovation and Excellence

(3)

Emission Control Solutions

• Simple Cycle Exhaust Catalyst System

Options for Gas Turbine Emission Control

• Combined Cycle HRSG Installation with Catalyst

• Steam Injection for NOx Control

(4)

Simple Cycle Emission Control Solutions

Carbon Monoxide (CO) Catalyst System

• The CO Catalyst system uses a precious metal oxidation catalyst to covert CO into CO2

• CO Catalyst Requirements:

• Uniform velocity distribution within 15% rms

• Exhaust gas temperature entering at no greater than ±50°F

• CO Catalyst can achieve 2-5 ppmvd@15%O2, based on 95% reduction

• CO Catalyst tolerate temperatures 425°F to 1150°F

• Increased oxidation (greater reactivity) at higher temperature

• Increased contamination rate below 650°F

2 2

CO

O

2

1

CO

+

(5)

Simple Cycle Emission Control Solutions

De-NOx Selective Catalytic Reduction (SCR) Catalyst System

• The SCR Catalyst system employs a catalytic reaction to convert ammonia (NH3) and NOx into harmless water (H2O) and nitrogen (N2)

• SCR Catalyst Requirements:

• Uniform velocity distribution within 15% rms

• Exhaust gas temperature entering at no greater than ±50°F

• SCR Catalyst can achieve 2-5 ppmvd@15%O2, based on 95% reduction

O

H

12

N

7

8NH

6NO

O

H

3

N

2

2NH

NO

NO

O

H

6

N

4

O

4NH

4NO

2 2 3 2 2 2 3 2 2 2 2 3

+

+

+

+

+

+

+

+

(6)

Simple Cycle Emission Control Solutions

• SCR Catalyst cost and durability are sensitive to operative temperature

(7)

Simple Cycle Emission Control Solutions

• Ammonia systems for anhydrous or aqueous supply

• Aqueous ammonia (19% typical) requires larger equipment, greater power consumption, and more constant supply deliveries

• Anhydrous ammonia requires increased safety measures and risk management

• Ammonia vaporization systems designed for exhaust gas recirculation or ambient air electric heaters

• Ammonia Injection Grid design influences NOx reduction and ammonia slip

• Ammonia slip of 2-10 ppmvd@15%O2

(8)

Simple Cycle Emission Control Solutions

Flow Modeling Critical to Project Success

• VPI CFD Engineering uses Fluent software for flow analysis • Turbine exhaust flow profile

• Duct design and distribution grid requirements

• Focus on reducing gas side pressure drop

• Dilution Air mixing • Ammonia Mixing

Axial Velocity

(ft/s)

(9)

Simple Cycle Emission Control Solutions

(10)

Combined Cycle Emission Control Solutions

New CT and HRSG Installation

• Vogt Power has over 500 HRSG installations operating in 35 countries around the globe, both utility and industrial

• Design for combustion turbines 25 MW to 290 MW

(11)

Combined Cycle Emission Control Solutions

Adding Steam Cycle to Simple Cycle CTs

• Design experience for sighting HRSG into existing plants

(12)

Combined Cycle Emission Control Solutions

Existing Combined Cycle Installation Without Emission Catalysts

• Vogt Power Aftermarket provides parts and service to all OEM units

• Expertise in HRSG thermal re-rating due to CT upgrade/rerate

(13)

Steam Injection for CT Emission Control Solution

Existing CT Installation

• Can provide heating surface for generating steam to be injection to CT for NOx control and power augmentation

• Can also integrate emission catalyst as necessary

(14)

Emission Control Durability

CO and SCR System Maintenance Concerns

• Poor quality NH3 fouling the control skid, vaporizer, AIG

• Catalyst poisoning due to high sulfur in CT exhaust, impurities in fuel supply or evaporative cooling water, or CT ingestion of dirty air

• Catalyst damage due to over-temperature, water washing, or casing insulation failure

References

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