Safety Data Sheet acc. to OSHA HCS

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· Product identifier

· Trade name: SODIUM METHOXIDE, ANHYDROUS · Article number:21200 · CAS Number: 124-41-4 · EC number: 204-699-5 · Index number: 603-040-00-2

· Relevant identified uses of the substance or mixture and uses advised against No further relevant information available.

· Application of the substance / the mixtureLaboratory chemicals · Details of the supplier of the safety data sheet

· Manufacturer/Supplier: Electron Microscopy Sciences 1560 Industry Road

USA-Hatfield, PA 19440

Tel: 215-412-8400 Fax: 215-412-8450 email: sgkcck@aol.com

www.emsdiasum.com

· Information department:Product safety department · Emergency telephone number:

ChemTrec 1-800-424-9300 Contract CCN7661 1-703-527-3887

2 Hazard(s) identification

· Classification of the substance or mixture GHS02 Flame

Self-heat. 1 H251 Self-heating: may catch fire.

GHS05 Corrosion

Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage.

GHS07

Acute Tox. 4 H302 Harmful if swallowed. · Label elements

· GHS label elementsThe substance is classified and labeled according to the Globally Harmonized System (GHS).

(Contd. on page 2)

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(Contd. of page 1)

· Hazard pictograms

GHS02 GHS05 GHS07 · Signal wordDanger

· Hazard-determining components of labeling: sodium methanolate

· Hazard statements

Self-heating: may catch fire. Harmful if swallowed.

Causes severe skin burns and eye damage. · Precautionary statements

Do not breathe dusts or mists.

Wear protective gloves / eye protection / face protection. Wear eye protection / face protection.

Keep cool. Protect from sunlight. Wash thoroughly after handling.

Do not eat, drink or smoke when using this product.

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Immediately call a poison center/doctor. Specific treatment (see on this label).

If swallowed: Call a poison center/doctor if you feel unwell.

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Wash contaminated clothing before reuse.

If swallowed: Rinse mouth. Do NOT induce vomiting. Store locked up.

Store away from other materials. Maintain air gap between stacks/pallets.

Dispose of contents/container in accordance with local/regional/national/international regulations. · Classification system:

· NFPA ratings (scale 0 - 4)

4

2

W

—

Health = 4 Fire = 4 Reactivity = 2

The substance demonstrates unusual reactivity with water. · HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY 4 4 2 Health = 4 Fire = 4 Reactivity = 2 · Other hazards

· Results of PBT and vPvB assessment · PBT:Not applicable.

(Contd. on page 3)

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(Contd. of page 2)

· vPvB:Not applicable.

3 Composition/information on ingredients

· Chemical characterization: Substances

· CAS No. Description

124-41-4 sodium methanolate · Identification number(s) · EC number:204-699-5 · Index number:603-040-00-2

4 First-aid measures

· Description of first aid measures · General information:

Immediately remove any clothing soiled by the product.

Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.

· After inhalation:In case of unconsciousness place patient stably in side position for transportation. · After skin contact:Immediately wash with water and soap and rinse thoroughly.

· After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing:

Immediately call a doctor.

Drink copious amounts of water and provide fresh air. Immediately call a doctor. · Information for doctor:

· Most important symptoms and effects, both acute and delayedNo further relevant information available. · Indication of any immediate medical attention and special treatment needed

No further relevant information available.

5 Fire-fighting measures

· Extinguishing media

· Suitable extinguishing agents:

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents:Water with full jet

· Special hazards arising from the substance or mixtureNo further relevant information available. · Advice for firefighters

· Protective equipment:No special measures required.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away.

· Environmental precautions:Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up:

Use neutralizing agent.

Dispose contaminated material as waste according to item 13. Ensure adequate ventilation.

Do not flush with water or aqueous cleansing agents · Reference to other sections

See Section 7 for information on safe handling.

(Contd. on page 4)

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(Contd. of page 3)

See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

7 Handling and storage

· Handling:

· Precautions for safe handling Thorough dedusting.

Open and handle receptacle with care.

· Information about protection against explosions and fires: Keep ignition sources away - Do not smoke.

Protect against electrostatic charges.

· Conditions for safe storage, including any incompatibilities · Storage:

· Requirements to be met by storerooms and receptacles:Store in a cool location. · Information about storage in one common storage facility:Not required. · Further information about storage conditions:

Keep receptacle tightly sealed. Do not gas tight seal receptacle.

Store in cool, dry conditions in well sealed receptacles. Protect from heat and direct sunlight.

· Specific end use(s)No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical systems:No further data; see item 7. · Control parameters

· Components with limit values that require monitoring at the workplace:Not required. · Additional information:The lists that were valid during the creation were used as basis. · Exposure controls

· Personal protective equipment:

· General protective and hygienic measures: Keep away from foodstuffs, beverages and feed.

Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes.

Avoid contact with the eyes and skin. · Breathing equipment:Not required. · Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves

The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.

(Contd. on page 5)

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(Contd. of page 4)

· Penetration time of glove material

The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

· Eye protection:

Tightly sealed goggles

9 Physical and chemical properties

· Information on basic physical and chemical properties · General Information

· Appearance:

Form: Powder

Color: White

· Odor: Characteristic

· Odour threshold: Not determined.

· pH-value: Not applicable.

· Change in condition

Melting point/Melting range: Undetermined. Boiling point/Boiling range: Undetermined.

· Flash point: 12 °C (54 °F)

· Flammability (solid, gaseous): Product is not flammable. · Ignition temperature: 70 °C (158 °F)

· Decomposition temperature: Not determined.

· Auto igniting: Not determined.

· Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible.

· Explosion limits:

Lower: Not determined.

Upper: Not determined.

· Vapor pressure: Not applicable.

· Density at 20 °C (68 °F): 0.97 g/cm³ (8.095 lbs/gal) · Relative density Not determined.

· Vapour density Not applicable.

· Evaporation rate Not applicable. · Solubility in / Miscibility with

Water: Insoluble.

· Partition coefficient (n-octanol/water):Not determined. · Viscosity:

Dynamic: Not applicable.

Kinematic: Not applicable.

Organic solvents: 0.0 %

(Contd. on page 6)

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(Contd. of page 5)

Solids content: 100.0 %

· Other information No further relevant information available.

10 Stability and reactivity

· Reactivity

· Chemical stability

· Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. · Possibility of hazardous reactionsNo dangerous reactions known.

· Conditions to avoidNo further relevant information available. · Incompatible materials:No further relevant information available.

· Hazardous decomposition products:No dangerous decomposition products known.

11 Toxicological information

· Information on toxicological effects · Acute toxicity:

· Primary irritant effect:

· on the skin:Strong caustic effect on skin and mucous membranes. · on the eye:

Strong caustic effect.

Strong irritant with the danger of severe eye injury. · Sensitization:No sensitizing effects known. · Additional toxicological information:

Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach.

· Carcinogenic categories

· IARC (International Agency for Research on Cancer) Substance is not listed.

· NTP (National Toxicology Program) Substance is not listed.

· OSHA-Ca (Occupational Safety Health Administration) Substance is not listed.

12 Ecological information

· Toxicity

· Aquatic toxicity:No further relevant information available.

· Persistence and degradabilityNo further relevant information available. · Behavior in environmental systems:

· Bioaccumulative potentialNo further relevant information available. · Mobility in soilNo further relevant information available.

· Additional ecological information: · General notes:

Water hazard class 1 (Self-assessment): slightly hazardous for water

Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.

(Contd. on page 7)

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(Contd. of page 6)

Must not reach bodies of water or drainage ditch undiluted or unneutralized.

Rinse off of bigger amounts into drains or the aquatic environment may lead to increased values. A high pH-value harms aquatic organisms. In the dilution of the use-level the pH-pH-value is considerably reduced, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous.

· Other adverse effectsNo further relevant information available.

13 Disposal considerations

· Waste treatment methods · Recommendation:

Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings:

· Recommendation:Disposal must be made according to official regulations.

14 Transport information

· UN-Number

· DOT, ADR, IMDG UN1431

· UN proper shipping name

· DOT Sodium methylate

· ADR 1431 Sodium methylate

· IMDG SODIUM METHYLATE

· Transport hazard class(es) · DOT

· Class 4.2 Substances liable to spontaneous combustion

· Label 4.2, 8

· ADR

· Label 4.2+8

· IMDG

(Contd. on page 8)

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(Contd. of page 7)

· Label 4.2/8

· IATA

· Label 4.2 (8)

· Packing group

· DOT, ADR, IMDG, IATA II

· Environmental hazards:

· Marine pollutant: No

· Special precautions for user Warning: Substances liable to spontaneous combustion

· Danger code (Kemler): 48

· EMS Number: F-A,S-L

· Transport in bulk according to Annex II of

MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information:

· DOT

· Quantity limitations On passenger aircraft/rail: 15 kg On cargo aircraft only: 50 kg · Hazardous substance: 1000 lbs, 454 kg

· ADR

· Excepted quantities (EQ) Code: E2

Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g · IMDG

· Limited quantities (LQ) 0 · Excepted quantities (EQ) Code: E2

Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g · UN "Model Regulation": UN1431, Sodium methylate, 4.2 (8), II

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara

· Section 355 (extremely hazardous substances): Substance is not listed.

· Section 313 (Specific toxic chemical listings): Substance is not listed.

· TSCA (Toxic Substances Control Act): Substance is listed.

(Contd. on page 9)

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(Contd. of page 8)

· Proposition 65

· Chemicals known to cause cancer: Substance is not listed.

· Chemicals known to cause reproductive toxicity for females: Substance is not listed.

· Chemicals known to cause reproductive toxicity for males: Substance is not listed.

· Chemicals known to cause developmental toxicity: Substance is not listed.

· EPA (Environmental Protection Agency) Substance is not listed.

· TLV (Threshold Limit Value established by ACGIH) Substance is not listed.

· NIOSH-Ca (National Institute for Occupational Safety and Health) Substance is not listed.

· GHS label elementsThe substance is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms

· Hazard-determining components of labeling: sodium methanolate

Do not breathe dusts or mists.

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Immediately call a poison center/doctor. Specific treatment (see on this label).

If swallowed: Call a poison center/doctor if you feel unwell.

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Wash contaminated clothing before reuse.

If swallowed: Rinse mouth. Do NOT induce vomiting. Store locked up.

Store away from other materials.

(Contd. on page 10)

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(Contd. of page 9)

Maintain air gap between stacks/pallets.

Dispose of contents/container in accordance with local/regional/national/international regulations. · Chemical safety assessment:A Chemical Safety Assessment has not been carried out.

16 Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

· Date of preparation / last revision12/08/2015 / -· Abbreviations and acronyms:

ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)

IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation

IATA: International Air Transport Association

ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA)

HMIS: Hazardous Materials Identification System (USA)

Self-heat. 1: Self-Heating Substances and Mixtures, Hazard Category 1 Acute Tox. 4: Acute toxicity, Hazard Category 4

Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1

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· Manufacturer/Supplier: Electron Microscopy Sciences 1560 Industry Road USA-Hatfield, PA 19440 Tel: 215-412-8400 Fax: 215-412-8450 email: sgkcck@aol.com www.emsdiasum.com ProSciTech Pty Ltd

11 Carlton Street, Kirwan QLD 4817 Australia

Telephone Number: (07) 4773 9444 - 8:30am - 5:00pm, Monday to Friday (excluding Public Holidays) Emergency Contact: (07) 4773 9444 - 8:30am - 5:00pm, Monday to Friday (excluding Public Holidays) Emgrid Australia Pty. Ltd.

P.O. Box 118 The Patch VIC 3792 Australia

Tel: 03 9752 1785 Fax: 03 9752 1784

Website: www.emgrid.com.au

· Further information obtainable from:Product safety department · Emergency telephone number:

2 Hazards identification

· Classification of the substance or mixture GHS02 flame

GHS05 corrosion

(Contd. on page 2)

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(Contd. of page 1)

GHS07

Acute Tox. 4 H302 Harmful if swallowed. · Label elements

· GHS label elements

The substance is classified and labelled according to the Globally Harmonised System (GHS). · Hazard pictograms

· Hazard-determining components of labelling: sodium methanolate

IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Immediately call a POISON CENTER/doctor. Specific treatment (see on this label).

IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.

IF INHALED: Remove person to fresh air and keep comfortable for breathing. Wash contaminated clothing before reuse.

IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Store locked up.

Dispose of contents/container in accordance with local/regional/national/international regulations. · Additional information:

Reacts violently with water. · Other hazards

AU

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3 Composition/information on ingredients

· Chemical characterisation: Substances

4 First aid measures

Call for a doctor immediately.

Drink plenty of water and provide fresh air. Call for a doctor immediately. · Information for doctor:

5 Firefighting measures

CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents:Water with full jet

6 Accidental release measures

Use neutralising agent.

See Section 8 for information on personal protection equipment.

(Contd. on page 4)

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(Contd. of page 3)

See Section 13 for disposal information.

7 Handling and storage

· Handling:

· Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. Protect against electrostatic charges.

Keep container tightly sealed. Do not seal receptacle gas tight.

8 Exposure controls/personal protection

· Additional information about design of technical facilities:No further data; see item 7. · Control parameters

· Ingredients with limit values that require monitoring at the workplace:Not required. · Additional information:The lists valid during the making were used as basis.

· Exposure controls

Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes.

Avoid contact with the eyes and skin. · Respiratory protection:Not required. · Protection of hands:

Protective gloves

(Contd. on page 5)

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(Contd. of page 4)

9 Physical and chemical properties

· Appearance:

Form: Powder

Colour: White

· Odour: Characteristic

· Flash point: 12 °C

· Flammability (solid, gaseous): Product is not flammable. · Ignition temperature: 70 °C

· Self-igniting: Not determined.

· Danger of explosion: Product is not explosive. However, formation of explosive air/vapour mixtures are possible.

· Vapour pressure: Not applicable.

· Density at 20 °C: 0.97 g/cm³

· Relative density Not determined.

water: Insoluble.

(Contd. on page 6)

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(Contd. of page 5)

· Solvent content:

VOC (EC) 0.00 %

10 Stability and reactivity

· Reactivity

11 Toxicological information

· Information on toxicological effects · Acute toxicity

· Skin corrosion/irritationStrong caustic effect on skin and mucous membranes. · Serious eye damage/irritation

Strong irritant with the danger of severe eye injury.

· Respiratory or skin sensitisationNo sensitising effects known. · Additional toxicological information:

12 Ecological information

· Toxicity

· Persistence and degradabilityNo further relevant information available. · Behaviour in environmental systems:

Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water

Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Must not reach sewage water or drainage ditch undiluted or unneutralised.

(Contd. on page 7)

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(Contd. of page 6)

13 Disposal considerations

· Waste treatment methods · Recommendation

Must not be disposed together with household garbage. Do not allow product to reach sewage system. · Uncleaned packaging:

14 Transport information

· UN-Number

· ADG, IMDG UN1431

· ADG 1431 SODIUM METHYLATE

· Transport hazard class(es) · ADG

· Class 4.2 Substances liable to spontaneous combustion.

· Label 4.2+8

· IMDG

· Label 4.2/8

· IATA

· Label 4.2 (8)

· Packing group

· ADG, IMDG, IATA II

· Special precautions for user Warning: Substances liable to spontaneous combustion.

(Contd. on page 8)

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(Contd. of page 7)

· ADG

Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g

· Transport category 2

· Tunnel restriction code D/E

· IMDG

Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g · UN "Model Regulation": UN1431, SODIUM METHYLATE, 4.2 (8), II

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture · Australian Inventory of Chemical Substances

Substance is listed.

· Standard for the Uniform Scheduling of Medicines and Poisons Substance is not listed.

· GHS label elements

The substance is classified and labelled according to the Globally Harmonised System (GHS). · Hazard pictograms

(Contd. on page 9)

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(Contd. of page 8)

IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Immediately call a POISON CENTER/doctor. Specific treatment (see on this label).

IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.

IF INHALED: Remove person to fresh air and keep comfortable for breathing. Wash contaminated clothing before reuse.

IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Store locked up.

Dispose of contents/container in accordance with local/regional/national/international regulations. · Directive 2012/18/EU

· Named dangerous substances - ANNEX ISubstance is not listed.

· Chemical safety assessment:A Chemical Safety Assessment has not been carried out.

16 Other information

· Abbreviations and acronyms:

ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)

IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association

EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU)

Self-heat. 1: Self-Heating Substances and Mixtures, Hazard Category 1 Acute Tox. 4: Acute toxicity, Hazard Category 4

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www.emsdiasum.com

· Information department:Product safety department · Emergency telephone number:

2 Hazard(s) identification

· Classification of the substance or mixture GHS02 Flame

GHS05 Corrosion

GHS07

Acute Tox. 4 H302 Harmful if swallowed.

· Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable.

Corrosive Causes severe burns.

Harmful Harmful if swallowed.

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(Contd. of page 1)

Irritant

Risk of serious damage to eyes. Extremely flammable Extremely flammable. Reacts violently with water.

· Information concerning particular hazards for human and environment:Not applicable. · Label elements

· Labelling according to EU guidelines:

The product has been classified and marked in accordance with directives on hazardous materials. · Code letter and hazard designation of product:

Corrosive Extremely flammable · Risk phrases: Extremely flammable. Reacts violently with water. Harmful if swallowed. Causes severe burns.

Risk of serious damage to eyes. · Safety phrases:

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection.

In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste.

· Hazard description: · WHMIS-symbols:

B6 - Reactive flammable material

D2B - Toxic material causing other toxic effects E - Corrosive material

· Classification system: · NFPA ratings (scale 0 - 4)

4

2

W

—

Health = 4 Fire = 4 Reactivity = 2

The substance demonstrates unusual reactivity with water. · HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY 4 4 2 Health = 4 Fire = 4 Reactivity = 2 (Contd. on page 3) CA

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(Contd. of page 2)

· Other hazards

3 Composition/information on ingredients

· Chemical characterization: Substances

4 First-aid measures

Immediately call a doctor.

Drink copious amounts of water and provide fresh air. Immediately call a doctor. · Information for doctor:

5 Fire-fighting measures

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents:Water with full jet

6 Accidental release measures

Use neutralizing agent.

(Contd. on page 4)

(23)

(Contd. of page 3)

7 Handling and storage

· Handling:

· Information about protection against explosions and fires: Keep ignition sources away - Do not smoke.

Protect against electrostatic charges.

Keep receptacle tightly sealed. Do not gas tight seal receptacle.

8 Exposure controls/personal protection

· Additional information about design of technical systems:No further data; see item 7. · Control parameters

· Components with limit values that require monitoring at the workplace:Not required. · Additional information:The lists that were valid during the creation were used as basis. · Exposure controls

Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes.

Avoid contact with the eyes and skin. · Breathing equipment:Not required. · Protection of hands:

Protective gloves

Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

(Contd. on page 5)

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(Contd. of page 4)

· Material of gloves

9 Physical and chemical properties

· Appearance:

Form: Powder

Color: White

· Odor: Characteristic

· Auto igniting: Not determined.

· Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible.

· Vapor pressure: Not applicable.

· Density at 20 °C: 0.97 g/cm³

Water: Insoluble.

(Contd. on page 6)

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(Contd. of page 5)

10 Stability and reactivity

· Reactivity

11 Toxicological information

· Information on toxicological effects · Acute toxicity:

· on the skin:Strong caustic effect on skin and mucous membranes. · on the eye:

Strong irritant with the danger of severe eye injury. · Sensitization:No sensitizing effects known. · Additional toxicological information:

· IARC (International Agency for Research on Cancer) Substance is not listed.

· NTP (National Toxicology Program) Substance is not listed.

· OSHA-Ca (Occupational Safety Health Administration) Substance is not listed.

12 Ecological information

· Toxicity

· Persistence and degradabilityNo further relevant information available. · Behavior in environmental systems:

Water hazard class 1 (Self-assessment): slightly hazardous for water

Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.

(Contd. on page 7)

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(Contd. of page 6)

Must not reach bodies of water or drainage ditch undiluted or unneutralized.

13 Disposal considerations

· Waste treatment methods · Recommendation:

Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings:

14 Transport information

· UN-Number

· DOT, TDG, IMDG UN1431

· DOT Sodium methylate

· TDG 1431 Sodium methylate

· Transport hazard class(es) · DOT

· Label 4.2, 8

· TDG (Transport dangerous goods):

· Label 4.2+8

· IMDG

(Contd. on page 8)

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(Contd. of page 7)

· Label 4.2/8

· IATA

· Label 4.2 (8)

· Packing group

· DOT, TDG, IMDG, IATA II

· Special precautions for user Warning: Substances liable to spontaneous combustion

· DOT

· Quantity limitations On passenger aircraft/rail: 15 kg On cargo aircraft only: 50 kg · Hazardous substance: 1000 lbs, 454 kg

· TDG

· Excepted quantities (EQ) Code: E2

Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g · IMDG

Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g · UN "Model Regulation": UN1431, Sodium methylate, 4.2 (8), II

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara

· Section 355 (extremely hazardous substances): Substance is not listed.

· Section 313 (Specific toxic chemical listings): Substance is not listed.

· TSCA (Toxic Substances Control Act): Substance is listed.

(Contd. on page 9)

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(Contd. of page 8)

· Proposition 65

· Chemicals known to cause cancer: Substance is not listed.

· Chemicals known to cause reproductive toxicity for females: Substance is not listed.

· Chemicals known to cause reproductive toxicity for males: Substance is not listed.

· Chemicals known to cause developmental toxicity: Substance is not listed.

· EPA (Environmental Protection Agency) Substance is not listed.

· TLV (Threshold Limit Value established by ACGIH) Substance is not listed.

· NIOSH-Ca (National Institute for Occupational Safety and Health) Substance is not listed.

· Canadian substance listings:

· Canadian Domestic Substances List (DSL) Substance is listed.

· Canadian Ingredient Disclosure list (limit 0.1%) Substance is not listed.

· Canadian Ingredient Disclosure list (limit 1%) Substance is not listed.

· Product related hazard informations:

The product has been classified and marked in accordance with directives on hazardous materials. · Hazard symbols: Corrosive Extremely flammable · Risk phrases: Extremely flammable. Reacts violently with water. Harmful if swallowed. Causes severe burns.

Risk of serious damage to eyes. · Safety phrases:

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection.

In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste.

· Chemical safety assessment:A Chemical Safety Assessment has not been carried out.

CA

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16 Other information

· Date of preparation / last revision12/08/2015 / -· Abbreviations and acronyms:

IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation

IATA: International Air Transport Association

ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA)

HMIS: Hazardous Materials Identification System (USA)

WHMIS: Workplace Hazardous Materials Information System (Canada) Self-heat. 1: Self-Heating Substances and Mixtures, Hazard Category 1 Acute Tox. 4: Acute toxicity, Hazard Category 4

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· 1.1 Product identifier

· 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available.

· Application of the substance / the mixtureLaboratory chemicals · 1.3 Details of the supplier of the safety data sheet

www.emsdiasum.com

· Further information obtainable from:Product safety department · 1.4 Emergency telephone number:

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture

· Classification according to Regulation (EC) No 1272/2008 GHS02 flame

GHS05 corrosion

GHS07

Acute Tox. 4 H302 Harmful if swallowed. · 2.2 Label elements

· Labelling according to Regulation (EC) No 1272/2008

The substance is classified and labelled according to the CLP regulation.

(Contd. on page 2)

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(Contd. of page 1)

· Hazard pictograms

H251 Self-heating: may catch fire. H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage. · Precautionary statements

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER/doctor. P321 Specific treatment (see on this label).

P405 Store locked up.

P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

· Additional information:

EUH014 Reacts violently with water. · 2.3 Other hazards

SECTION 3: Composition/information on ingredients

· 3.1 Chemical characterisation: Substances

SECTION 4: First aid measures

· 4.1 Description of first aid measures · General information:

Call for a doctor immediately.

(Contd. on page 3)

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(Contd. of page 2)

Drink plenty of water and provide fresh air. Call for a doctor immediately.

· 4.2 Most important symptoms and effects, both acute and delayedNo further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed

SECTION 5: Firefighting measures

· 5.1 Extinguishing media

CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents:Water with full jet

· 5.2 Special hazards arising from the substance or mixtureNo further relevant information available. · 5.3 Advice for firefighters

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away.

· 6.2 Environmental precautions:Do not allow to enter sewers/ surface or ground water. · 6.3 Methods and material for containment and cleaning up:

Use neutralising agent.

Do not flush with water or aqueous cleansing agents · 6.4 Reference to other sections

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling

Thorough dedusting.

· Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. Protect against electrostatic charges.

· 7.2 Conditions for safe storage, including any incompatibilities · Storage:

Keep container tightly sealed. Do not seal receptacle gas tight.

· 7.3 Specific end use(s)No further relevant information available.

GB

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SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities:No further data; see item 7. · 8.1 Control parameters

· Ingredients with limit values that require monitoring at the workplace:Not required. · Additional information:The lists valid during the making were used as basis.

· 8.2 Exposure controls

Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes.

Avoid contact with the eyes and skin. · Respiratory protection:Not required. · Protection of hands:

Protective gloves

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties · General Information

· Appearance:

Form: Powder

Colour: White

· Odour: Characteristic

Melting point/Melting range: Undetermined.

(Contd. on page 5)

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(Contd. of page 4)

Boiling point/Boiling range: Undetermined.

· Self-igniting: Not determined.

· Danger of explosion: Product is not explosive. However, formation of explosive air/vapour mixtures are possible.

· Vapour pressure: Not applicable.

· Density at 20 °C: 0.97 g/cm³

water: Insoluble.

· Solvent content:

VOC (EC) 0.00 %

· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity

· 10.2 Chemical stability

· Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactionsNo dangerous reactions known.

· 10.4 Conditions to avoidNo further relevant information available. · 10.5 Incompatible materials:No further relevant information available.

· 10.6 Hazardous decomposition products:No dangerous decomposition products known.

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects

· Acute toxicity

· Skin corrosion/irritationStrong caustic effect on skin and mucous membranes.

(Contd. on page 6)