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Engineering a Library of Anisotropic Building Blocks for DNA-Programmed Colloidal Self-Assembly

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Figure

Figure 1.1:The current method for obtaining open structures is to increase thehydrodynamic radius relative to the radius of the core particle.A 10 nm goldnanoparticle with a 70 nm DNA brush (a) can form a close-packed crystal witha particle volume-fraction
Figure 1.2:Tunable Parameters for Binary System.
Figure 2.1:Method for designing DNA sequences developed by Nadrian Seeman.DNA sequences designed using this method are generally devoid of unwanted in-teractions such as hairpins, and preferentially bind to their complement.Eachthree-base sequence listed above is used a maximum of one time to minimize thepresence of unwanted secondary structures.
Figure 3.1:A system of two particle species (Pare rare, the correspondingtemperature, releasing ”1 + 12 clusters” formed of single(c,d) which compete with thePP,P ′) is thermally quenched (a)to form large crystals with an FCC structure due to identically a
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