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Morozova, Varvara Alexandrovna (2018): Stereoselective preparation of chiral polyfunctional secondary alkyllithiums and alkylcoppers and their application towards natural product synthesis. Dissertation, LMU München: Fakultät für Chemie und Pharm

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Figure

Figure 1. X-Ray structure of syn-boronic ester (syn-59a).
Table 1. Diastereoselective reactions of anti- and syn- acyclic secondary alkyllithiums 55a with electrophiles leading
Table 2. Diastereoselective synthesis of anti- and syn-ethyl-2,3-dimethyl carboxylates 57b-f from the alkyl iodides 56b-f via I/Li-exchange and following trapping with ClCO2Et after 5 sec
Table 3. Enantioselective synthesis of esters 75a-h starting from optically enriched alcohols (73a-h) via iodination, I/Li-exchange and quench with ClCO2Et
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