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Synthesis and Biological Activity of Anticoagulant Heparan Sulfate Glycopolymers

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Figure

Figure 1.1: Structures of glycosaminoglycans. R = H or SO3-; R’ = Ac or SO3- .
Figure 1.2: Proteoglycans consist of a protein core (brown) and covalently linked GAG chains (HS in blue; CS/DS in yellow)
Figure 1.3: The biosynthesis of HS, heparin, and CS is initiated by the formation of a core protein linkage region tetrasaccharide.2
Figure 1.4: Scheme of HS chain biosynthesis. Structural domains (NA, NA/NS, NS) are defined with regards to the distribution of GlcN N-substituents as indicated
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O benzyl L idopyranuronate (15) Compound 14 (mg, mmol) was dissolved in 90% aqueous trifluoroacetic acid (mL) and stirred at ambient temperature for 35 min The 2: Types of olefin metathesis reactions. 4 Polymerization reaction using bis-pyridine Grubbs 2 nd generation catalyst. 5: Hydrogenation of HS glycopolymer series.

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