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Cycloaddition Reactions of (Di)tetrelenes

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Figure

Figure 2.1 Thermal ellipsoid plot of 2.9a (30% probability surface). Selected bond lengths (Å) and angles (deg): Ge1-C1 = 1.994(3); Ge1-C5 = 1.963(3); Ge1-C31 = 1.971(3); Ge1-C22 = 1.984(3); C1-C2 = 1.490(5); C2-C3 = 1.380(5); C3-C4 = 1.499(5); C4-C5 = 1.3
Figure 2.3 Highest occupied and lowest unoccupied molecular orbitals of (A) butadiene, (B) 1-germabutadiene, (C) phenylacetylene, and (D) ethoxyacetylene
Table 2.1: Crystallographic data of compounds 2.9a and 2.9b
Table 3.1: Crystallographic data of compound 3.5c
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