: 3-Chloro-4-methoxybenzoic acid

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1.IDENTIFICATIONOFTHESUBSTANCE/MIXTUREANDOFTHECOMPANY/UNDERTAKING Productname :

3-Chloro-4-methoxybenzoic acid

ProductNumber :

^EX-002387

Brand : Exir

Company : Exir GmbH

Flotowgasse 18-22/2/1 1190 WIEN

AUSTRIA

Telefon : +43 (0) 19463937

Fax : +43 (0) 19462797

Email-Adress : [email protected] Emergency Phone # : +43 (0) 14064343

2.HAZARDSIDENTIFICATION

Classificationofthesubstanceormixture AccordingtoRegulation(EC)No1272/2008 Acutetoxicity,Oral(Category3)

Eyeirritation(Category2)

Acuteaquatictoxicity(Category1)

AccordingtoEuropeanDirective67/548/EECasamended.

Harmfulifswallowed.Verytoxictoaquaticorganisms.

Labelelements Pictogram

Signalword Danger

Hazardstatement(s)

H301 Toxicifswallowed.

H319 Causesseriouseyeirritation.

H400 Verytoxictoaquaticlife.

Precautionarystatement(s)

P273 Avoidreleasetotheenvironment.

P301+P310 IFSWALLOWED:ImmediatelycallaPOISONCENTERor doctor/physician.

P305+P351+P338 IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Remove contactlenses,ifpresentandeasytodo.Continuerinsing.

Hazardsymbol(s)

Xn Harmful

N Dangerousfortheenvironment

R-phrase(s)

R22 Harmfulifswallowed.

R50 Verytoxictoaquaticorganisms.

S-phrase(s)

S60 Thismaterialanditscontainermustbedisposedofashazardouswaste.

S61 Avoidreleasetotheenvironment.Refertospecialinstructions/Safetydata

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ForthefulltextoftheH-StatementsmentionedinthisSection,seeSection16.

sheets.

Otherhazards-none

3.COMPOSITION/INFORMATIONONINGREDIENTS

Synonyms : 3-Chloro-p-anisic acid

MDL : MFCD00016512

Formula : C8H7ClO3

Molecular Weight : 186,59 g/mol

Beilstein : 2087584

4.FIRSTAIDMEASURES Generaladvice

Consultaphysician.Showthissafetydatasheettothedoctorinattendance.

Ifinhaled

Ifbreathedin,movepersonintofreshair.IfnotbreathinggiveartificialrespirationConsultaphysician.

Incaseofskincontact

Washoffwithsoapandplentyofwater.Consultaphysician.

Incaseofeyecontact

Rinsethoroughlywithplentyofwaterforatleast15minutesandconsultaphysician.

Ifswallowed

Nevergiveanythingbymouthtoanunconsciousperson.Rinsemouthwithwater.Consultaphysician.

5.FIRE-FIGHTINGMEASURES Suitableextinguishingmedia

Usewaterspray,alcohol-resistantfoam,drychemicalorcarbondioxide.

Specialprotectiveequipmentforfire-fighters

Wearselfcontainedbreathingapparatusforfirefightingifnecessary.

6.ACCIDENTALRELEASEMEASURES Personalprecautions

Usepersonalprotectiveequipment.Avoiddustformation.Avoidbreathingdust.Ensureadequateventilation.

Environmentalprecautions

Preventfurtherleakageorspillageifsafetodoso.Donotletproductenterdrains.Dischargeintothe environmentmustbeavoided.

Methodsandmaterialsforcontainmentandcleaningup

Pickupandarrangedisposalwithoutcreatingdust.Keepinsuitable,closedcontainersfordisposal.

7.HANDLINGANDSTORAGE Precautionsforsafehandling Avoidformationofdustandaerosols.

Provideappropriateexhaustventilationatplaceswheredustisformed.Normalmeasuresforpreventivefire

CAS-No. EC-No. Index-No. Classification Concentration

3-Chloro-p-anisicacid

37908-96-6 253-708-9 - AcuteTox.3;EyeIrrit.2;

AquaticAcute1;H301,H319, H400

Xn,N,R22-R50

-

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Conditionsforsafestorage

Storeincoolplace.Keepcontainertightlyclosedinadryandwell-ventilatedplace.

8.EXPOSURECONTROLS/PERSONALPROTECTION Personalprotectiveequipment

Respiratoryprotection

Whereriskassessmentshowsair-purifyingrespiratorsareappropriateuseadustmasktypeN95(US)or typeP1(EN143)respirator.Userespiratorsandcomponentstestedandapprovedunderappropriate governmentstandardssuchasNIOSH(US)orCEN(EU).

Handprotection

TheselectedprotectivegloveshavetosatisfythespecificationsofEUDirective89/686/EECandthe standardEN374derivedfromit.

Handlewithgloves.

Eyeprotection

Faceshieldandsafetyglasses Skinandbodyprotection

Choosebodyprotectionaccordingtotheamountandconcentrationofthedangeroussubstanceatthe workplace.

Hygienemeasures

Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Washhandsbeforebreaksandat theendofworkday.

9.PHYSICALANDCHEMICALPROPERTIES Appearance

Form solid

Safetydata

pH nodataavailable

Meltingpoint 216-218°C-lit.

Boilingpoint nodataavailable Flashpoint nodataavailable Ignitiontemperature nodataavailable Lowerexplosionlimit nodataavailable Upperexplosionlimit nodataavailable Watersolubility nodataavailable

Partitioncoefficient: logPow:2,322 n-octanol/water

10.STABILITYANDREACTIVITY Chemicalstability

Stableunderrecommendedstorageconditions.

Conditionstoavoid nodataavailable Materialstoavoid Strongoxidizingagents

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Hazardousdecompositionproducts

Hazardousdecompositionproductsformedunderfireconditions.-Carbonoxides,Hydrogenchloridegas

11.TOXICOLOGICALINFORMATION Acutetoxicity

nodataavailable Skincorrosion/irritation nodataavailable

Seriouseyedamage/eyeirritation nodataavailable

Respiratoryorskinsensitization nodataavailable

Germcellmutagenicity nodataavailable Carcinogenicity

IARC: Nocomponentofthisproductpresentatlevelsgreaterthanorequalto0.1%isidentifiedas probable,possibleorconfirmedhumancarcinogenbyIARC.

Reproductivetoxicity nodataavailable

Specifictargetorgantoxicity-singleexposure nodataavailable

Specifictargetorgantoxicity-repeatedexposure nodataavailable

Aspirationhazard nodataavailable Potentialhealtheffects

Inhalation Maybeharmfulifinhaled.Maycauserespiratorytractirritation.

Ingestion Harmfulifswallowed.

Skin Maybeharmfulifabsorbedthroughskin.Maycauseskinirritation.

Eyes Maycauseeyeirritation.

SignsandSymptomsofExposure

Tothebestofourknowledge,thechemical,physical,andtoxicologicalpropertieshavenotbeenthoroughly investigated.

AdditionalInformation RTECS:nodataavailable

12.ECOLOGICALINFORMATION Toxicity

nodataavailable

Persistenceanddegradability nodataavailable

Bioaccumulativepotential nodataavailable

Mobilityinsoil nodataavailable

PBTandvPvBassessment

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Verytoxictoaquaticorganisms.

13.DISPOSALCONSIDERATIONS Product

Observeallfederal,state,andlocalenvironmentalregulations.Contactalicensedprofessionalwaste disposalservicetodisposeofthismaterial.Dissolveormixthematerialwithacombustiblesolventandburn inachemicalincineratorequippedwithanafterburnerandscrubber.

Contaminatedpackaging Disposeofasunusedproduct.

14.TRANSPORTINFORMATION ADR/RID

UN-Number:3077 Class:9 Packinggroup:III

Propershippingname:ENVIRONMENTALLYHAZARDOUSSUBSTANCE,SOLID,N.O.S.(3-Chloro-p-anisic acid)

IMDG

UN-Number:3077 Class:9 Packinggroup:III EMS-No:F-A,S-F

Propershippingname:ENVIRONMENTALLYHAZARDOUSSUBSTANCE,SOLID,N.O.S.(3-Chloro-p-anisic acid)

Marinepollutant:No IATA

UN-Number:3077 Class:9 Packinggroup:III

Propershippingname:Environmentallyhazardoussubstance,solid,n.o.s.(3-Chloro-p-anisicacid)

15.REGULATORYINFORMATION

ThissafetydatasheetcomplieswiththerequirementsofRegulation(EC)No.1907/2006.

16.OTHERINFORMATION

TextofH-code(s)andR-phrase(s)mentionedinSection3 AcuteTox. Acutetoxicity

AquaticAcute Acuteaquatictoxicity EyeIrrit. Eyeirritation