C O A L T A R S O L U T I O N
1 . I D E N T I FI C A T I O N O F T H E S U B ST A N C E /P R E P A R A T I O N A N D T H E C O M P A N Y :
P R O D U C T N A M E : COAL TAR SOLUTION
P A R T N o .: RM080
S U P P L IE R : J M Loveridge plc
Southbrook Road, Southampton Hampshire SO15 1BH Tel: 023 8022 2008 Fax: 023 8022 2117
2 . C O M P O S IT IO N /I N F O R M A T I O N O N IN G R E D I E N T S :
NAME EINECS Nr.: CAS No.: CONTENT CLASSIFICATION ETHANOL 200-578-6 F R-11 64-17-5 60-100 % METHANOL 200-659-6 T ,F R-11, 23/24/25, 39/23/24/25 67-56-1 1-5 % COAL TAR 266-018-8 T R-45 Carc2 65996-84-1 10-30 %The Full Text for all R-Phrases are Displayed in Section 16
C O M P O SI T IO N C O M M E N TS : Coal tar component is a complex mixture of aromatic hydrocarbons, phenolic compounds and coal tar pitch. The mixture may also contain benzo[a]-pyrene and benzo[b+j+k]-fluoranthene.
3 . H A Z A R D S ID E N T IF I C A T I O N :
Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. May cause cancer. Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed. Carcinogen Category 2. Mutagen Category 3.
Coal tar component of the preparation is classified as Carcinogen Category 2.
IN H A LA T IO N : Remove affected person from exposure, rest and keep warm. If recovery not rapid or complete seek medical attention.
IN G E ST I O N : DO NOT INDUCE VOMITING. In case of spontaneous vomiting, be sure that vomit
can freely drain because of danger of suffocation. Only when conscious, rinse mouth with plenty of water and give plenty of water to drink - (approx 500ml).
Keep patient at rest and obtain medical attention.
S K IN : Remove contaminated clothing. Wash affected area with plenty of soap and water. Do
not use solvents. Obtain medical attention. Launder clothing before re-use.
E Y E S : Rinse immediately with plenty of water for at least 5 minutes while lifting the eye lids.
Seek medical attention. Continue to rinse.
5 . F I R E FI G H T I N G M E A S U R E S :
E X T IN G U IS H IN G M E D I A : Water spray, fog or mist, carbon dioxide (CO2), alcohol resistant foam, dry chemicals, sand, dolomite etc.
S P EC IA L F IR E F I G H T IN G P R O C E D U R E S :
Take measures to retain water used for extinguishing. Do not release contaminated water into drains, soil and surface water. Dispose of contaminated water and soil according to local regulations.
H A ZA R D O U S C O M B U ST I O N P R O D U C T S:
Burning may release oxides of carbon and other hazardous gases or vapours.
P R O TE C T IV E M E A SU R E S I N F I R E : Fire fighters should wear self-contained breathing apparatus.
6 . A C C I D E N T A L R E L E A S E M E A S U R E S:
P E R S O N A L P R E C A U TI O N I N S P IL L : Wear appropriate protective clothing. Eliminate all sources of ignition. Avoid direct contact with skin, eyes and clothing.
Ventilate area to dispel residual vapour or fumes.
P R EC A U T IO N S T O P R O TE C T E N V IR O N M E N T:
Prevent material from entering drains or water courses. Advise the Environment Agency or relevant local authority if contamination of soil or water systems occurs.
S P IL L C L E A N U P M E T H O D S: Take-up spillage with absorbent, inert material and place in a suitable and closable labelled container for recovery or disposal.
7 . H A N D L I N G A N D S T O R A G E :
U S A G E P R E C A U T IO N S : HANDLING - Product should be used in accordance with good industrial principles for handling and storing of hazardous chemicals.
Avoid vapour formation and ignition sources. Avoid contact with skin or eyes. Avoid vapour inhalation.
S TO R A G E P R E C A U T IO N S : Store in a cool, dry, well ventilated place, in securely closed original container. Store away from sources of heat or ignition.
S TO R A G E C R I T ER IA : Flammable liquid storage.
8 . E X PO S U R E C O N T R O L S A N D P E R S O N A L PR O T E C T I O N :
INGREDIENT NAME: CAS No.: STD LT EXP 8 Hrs ST EXP 15 Min
OES 1000 ppm
ETHANOL 64-17-5 No std.
OES 200 ppm(Sk)
R E S P IR A T O R S: Respiratory protection required in insufficiently ventilated working areas.
For short periods of work, a suitable RPE fitted with a combination charcoal or organic vapour cartridge is recommended.
P R O TE C T IV E G L O V ES : Use impervious gloves.
E Y E P R O T EC T IO N : Approved chemical safety goggles or face protection.
O T H E R P R O T E C T IO N : Wear personal protective equipment appropriate to the quantity of material handled.
H Y G IE N IC W O R K P R A C T IC E S: SKIN PROTECTION - apply barrier cream to hands and exposed skin.
Apply good personnal hygiene principles, such as washing of hands, arms and face.
9 . P H Y S I C A L A N D C H E M I C A L PR O P E R T I E S :
A P P EA R A N C E : Dark brown to black mobile liquid.
O D O U R /T A S T E: Characteristic pitch/tar odour.
~ 0 .83 - 0 .85 T em pera tu re (°C ): 2 0
D E N SI T Y /S P E C I F IC G R A V I TY (g/ m l):
18 °C M eth od :
F L A S H P O I N T (°C ):
1 0 . S T A B I L I T Y A N D R E A C T I V I T Y :
S TA B IL I TY : Stable under normal conditions of use.
M A TE R IA LS T O A V O ID : Oxidising agents.
H A ZA R D O U S D E C O M P . P R O D U C TS : Thermal decomposition or burning may release oxides of carbon or other hazardous gases, acrid smoke and irritating fumes.
1 1 . T O X I C O L O G I C A L I N F O R M A T I O N :
T O X I C O L O G I C A L IN F O R M A T IO N : Prolonged or repeated contact with skin may result in the occurrence of tar warts, which may develop into skin cancer.
IN H A LA T IO N : Irritating to mucous membranes.
IN G E ST I O N : May cause nausea, vomiting, abdominal pain, drowsiness.
High ethanol content may cause intoxication.
S K IN : Prolonged or repeated exposure may cause severe irritation.
E Y E S : Irritating to eyes.
H E A L T H W A R N I N G S : Acute effects include headache and nausea.
O T H E R H E A L TH E F F E C TS : Chronic effects - exposure to high concentrations may result in damage to internal organs.
1 3 . D IS P O S A L C O N S I D E R A T I O N S :
D I S P O SA L M E T H O D S: This material and/or its container must be disposed of as hazardous waste according to Special Waste Regulations 1996 or according to local regulations, in compliance with Duty of Care Regulations and Special Waste Regulations.
W A S T E C L A S S: WASTE CODE: 0705** HAZARDOUS PROPETY: H7, H14
1 4 . T R A N SP O R T I N F O R M A T I O N :
LABEL FOR CONVEYANCE:
U K R O A D P A C K G R .: III
A D R C L A S S N o .: 3
A D R C L A S S: Class 3: Flammable liquids.
A D R I T EM N o .: 5°(c)
H A ZA R D N o . (A D R ): 33 Highly flammable liquid (flash-point below 23°C).
A D R M A R G I N A L : 2301
H A ZC H E M C O D E : 3YE
P R O P E R SH IP P I N G N A M E I: FLAMMABLE LIQUID, NOS
P R O P E R SH IP P I N G N A M E II : TECHNICAL NAME - (contains ethanol)
U N N o . S EA : UN 1993
IM D G C L A SS : 3
IM D G P A G E N o .: 3345
IM D G P A C K G R .: III
M A R IN E P O L L U T A N T : Yes.
S EA T R A N S P O R T N O TE S : Contains marine pollutant (P).
U N N o ., A I R : UN-ID 1993
IC A O C L A S S: 3
A I R P A C K G R .: III
LABEL FOR SUPPLY:
R I S K P H R A SE S : R-11 Highly flammable.
R-20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R-45 May cause cancer.
R-68/20/21/22 Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed.
S A F E T Y P H R A S E S: P-11 Restricted to professional users.
S-36/37 Wear suitable protective clothing and gloves.
S-38 In case of insufficient ventilation, wear suitable respiratory equipment. S-45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S-53 Avoid exposure - obtain special instructions before use.
S-60 This material and its container must be disposed of as hazardous waste.
U K R E G U L A T O R Y R E F E R E N C E S: Chemicals (Hazard Information & Packaging) Regulations 1993. Classification, Packaging and Labelling Regulations 1984.
1 6 . O T H E R I N F O R M A T I O N :
IN F O R M A T IO N SO U R C E S: This product has been classified in accordance with CHIP3 regulations.
R E V IS IO N C O M M E N TS : Edition 01; Revised item(s):
IS S U E D B Y : MK
S D S N o .: 129
D A T E : 12/07/02
D I S C L A I M E R : The foregoing data has been compiled for safety information only and does not form
part of any selling specification. Information contained in this Data Sheet is to the best of JMLs knowledge correct at the time of publication. Customers should always satisfy themselves, that the product which they have selected is entirely suitable for their purpose under their conditions of use and in compliance with current regulations. For any further information, please contact the supplier.
R -P H R A S E S (F u ll T ex t): R-45 May cause cancer. R-11 Highly flammable. R-23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R-39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
