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(1)

MANAGEMENT OF METALLIC WASTE

ENRESA

Jose Luis Leganes Nieto, ENRESA

JLEN@enresa.es

(2)

Inputs

Transformation

process

Outputs

+

+

RESOURCES

MATERIALS

1

2

3

4

5

6

DISMANTLING is not only

DEMOLITION, but an INDUSTRIAL

PROCESS

1

2

3

4

5

6

7

(3)

15/02/2021 3

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 945098.

In situ activities in Nuclear Installation/Waste volume optimization

Segregation

Cutting

Decontamination

o

Mechanical

o

Chemical

Classification by kind of metal and by level of activity

Releasable

VLLW

LLW

(4)

In case of being released:

valuable and recoverable for non nuclear industry

o

Stainless steel

o

Carbon steel

o

Aluminium

o

Cupper…

Official Release Forms

(5)

15/02/2021 5

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 945098.

In case of VLLW

Large items for direct disposal

o

No internal voids, if any, to be filled with granulometric

waste

o

If required, plates to weigh distribution in disposal cell

o

Current radiological (ETM, DTM, dose rate…) and physical

data (mass, volume…).

Items directly introduced in cubic metallic container

o

voids have to be filled with granulometric waste

o

Current radiological and physical data

(6)

In case of LLW

No large items allowed for direct disposal

Items introduced in cubic metallic container

o

Voids finally filled with fluid mortar

o

Current radiological and physical data

Mortar block in bigger concrete container in disposal center

Concrete container finally disposed in vault/cell

In both cases VLLW and LLW

(7)

15/02/2021 7

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 945098.

LLW DISPOSAL

(8)

In Situ Waste

Classification

Volume

Reduction

Decontamination

LILW & VLLW

Selection Cutting

Technique

New Containers

Decontamination

Chemical & Blasting

for LILW Metals

Melting

VLLW Soil Washing

Optimize

Packaging

Conditioning

Compacting

Shredding

Clearance

Very Low Level

Waste Disposal

Require Licensing

New Methodologies

(9)

15/02/2021 9

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 945098.

Aluminium as the main reactive metal

In case of water intrusion in LLW disposal, alkaline medium

Amphoteric reaction and hydrogen production

Risk of concrete container cracks and release of activity

Research to analyse

o

Maximum Surface of Aluminium by package using

Portland cement that would produce the stablished

threshold release rate of hydrogen, in real non

conservative conditions.

o

New Phosphate Magnesium matrices that would inhibit

the increase of pH.

(10)
(11)

T4.5. CHARACTERIZATION OF METALLIC WASTE

DECONTAMINATION-RELEASE

Jose Luis Leganes Nieto, ENRESA

JLEN@enresa.es

(12)

Inputs

Transformation

process

Outputs

+

+

RESOURCES

MATERIALS

1

2

3

4

5

6

DISMANTLING is not only

DEMOLITION, but an INDUSTRIAL

PROCESS

1

2

3

4

5

6

7

(13)

15/02/2021 3

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 945098.

Site&Facility Characterization: the objective is to obtain a

radiological image of the whole Installation (site and

facility) or at least the locations where it is possible to be

accessed for characterization.

In situ Characterization for Classification: it can be

considered as an operational, and sometimes rough,

characterization for disassembles, cleaning or remediation

activities that allow a quick and therefore an operative way

of classifying the materials.

Characterization for Final Assignment/Assessment: it is an

as thorough as possible characterization that would define

the final destination of the materials, or the release

objective fulfillment.

(14)

Site&Facility

Characterization

Modifications

Disassembles

Demolitions

Site Restoration

Materials Management

Initial status

Final Status:

Green Field,

Brown/Gray field

In situ

Characterization

for Classification

(15)

15/02/2021 5

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 945098.

PERFORM A COMPLETE RADIOLOGICAL MAP OF THE

INSTALLATION

Using mobile instrumentation

Contact dose rate measurement

Contact Beta

Contact Alfa

Other in situ devices

COLLECT SAMPLES (FOR RADIOCHEMICAL ANALYSIS) AS A

FUNCTION OF

Lower or higher values of dose rate?

Lower or higher values of Alfa, Beta?

THE

CHARACTERIZATION

DESIGN SHOULD BE

PLANNED IN ORDER

TO OBTAIN

REPRESENTATIVE

SCALING FACTORS

(16)
(17)

15/02/2021 7

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 945098.

In Situ Waste

Classification

Volume

Reduction

Decontamination

LILW & VLLW

Selection Cutting

Technique

New Containers

Decontamination

Chemical & Blasting

for LILW Metals

Melting

VLLW Soil Washing

Optimize

Packaging

Conditioning

Compacting

Shredding

Clearance

Very Low Level

Waste Disposal

Require Licensing

New Methodologies

(18)

34 33 32 31

38 37 36 35

Digitalize de Large Piece in Items of easy geometry.

Determine the influence of each item on the rest of segments, in order

to determine the intrinsic contribution of the Item itself discarding the

influence of the rest of the Items.

Simplify the model leaving null the contribution of the far Items which

influence can be considered negligible in relation to the nearest ones.

Determine the activity of each Item, and the total activity by summing

all.

(19)

15/02/2021 9

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 945098.

(20)

CLEARANCE: INDUSTRIAL PROCESS

BOX COUNTER (gamma spectroscopy system)

Activity of each radionuclide Cj in

the material (Bq/g & Bq/cm2)

To confirm a mixture of

radionuclides is below the

clearance level

UR =

Σ

Cj/Lj ≤ 1

Cj= specific activity in the material of

radionuclide j (Bq/g)

Lj= the clearance level of radionuclide

j (Bq/g)

Scaling

Factors

Clearance Level

N1: general levels

(Bq/g)

N2: specific levels

(Bq/g & Bq/cm2)

Metals

Rubble

(21)

15/02/2021 11

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 945098.

(22)

Cont ainer movement

Det 1

Det 2

Det 3

Det 4

9

5

1

2

6

10

11

7

3

4

8

12

Posit ion 1

Posit ion 2

Posit ion 3

(23)

15/02/2021 13

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 945098.

(24)

The development of Gamma cameras to obtain a

distribution of the activity in the container or large

component.

Determination of mass distribution or changes of density

in the container/large item in a passive way.

The improvements of portable devices for the

characterization process of metallic waste in controlled

areas with significant background

The use of solid substances for chemical decontamination

to avoid liquids and facilitate subsequent treatment

(25)

15/02/2021 15

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 945098.

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