Annex to the Accreditation Certificate D-PL according to DIN EN ISO/IEC 17025:2005

22 

Loading....

Loading....

Loading....

Loading....

Loading....

Full text

(1)

Deutsche Akkreditierungsstelle GmbH

Annex to the Accreditation Certificate D-PL-14237-01-00

according to DIN EN ISO/IEC 17025:2005

Period of validity: 29.05.2012 to 28.05.2017 Date of issue: 05.06.2014

Holder of certificate:

K-UTEC AG Salt Technologies

Physico-Chemical Analytics Department

Am Petersenschacht 7, 99706 Sondershausen

Tests in the fields:

physical, physico-chemical and chemical investigations of water, waste water, surface water, groundwater, sewage sludge, soil used for agricultural purposes, biowaste and waste for deposition; analysis of salts and salt saline solutions;

sampling of waste water;

specialised module water, specialised module waste products

(2)

Annex to the accreditation certificate D-PL-14237-01-00

1 List of test procedures for the Specialised Module WATER Status: 06.04.2005

Explanations:

Ww: relevant for waste water (including waste disposal site seepage) Sw: relevant for surface water

NGw: relevant for natural water and groundwater Part 1: Sampling and general parameters

Parameter Test method Ww Sw NGw

Waste water sampling DIN 38402-A 11: 1995-12 Flowing water sampling DIN 38402-A 15: 1986-07 Sampling of groundwater aquifiers DIN 38402-A 13: 1985-12 Sampling of standing water DIN 38402-A 12: 1985-06 Homogenisation of the samples DIN 38402-A 30: 1998-07

Temperature DIN 38404-C 4: 1976-12

pH value DIN 38404-C 5: 1984-01

Conductivity (25°C) DIN EN 27888: 1993-11 (C 8)

Odour DEV B 1/2: 1971- 6th delivery

Colour DIN EN ISO 7887: 1994-12 (C 1),

Section 2

Turbidity DIN EN ISO 7027: 2000-04 (C 2)

Redox potential DIN 38404-C 6: 1984-05

Part 2: Photometry, ion chromatography and mass analysis

Parameter Test method Ww Sw NGw

UV absorption at 254 nm (SAK 254) DIN 38404-C 3: 1976-12 UV absorption at 436 nm (SAK 436) DIN EN ISO 7887: 1994-12 (C 1)

Ammonium nitrogen DIN EN ISO 11732: 1997-09 (E 23) DIN 38406-E 5: 1983-10 DIN EN ISO 14911: 1999-12 (E 34) DIN 38406-E 23: 1993-12 Nitrite nitrogen DIN EN 26777: 1993-04 (D 10) DIN EN ISO 10304-1: 1995-04 (D 19) DIN EN ISO 10304-2: 1996-11 (D 20) DIN EN ISO 13395: 1996-12 (D 28). Nitrate nitrogen DIN EN ISO 10304-1: 1995-04 (D 19) DIN EN ISO 10304-2: 1996-11 (D 20) DIN EN ISO 13395: 1996-12 (D 28) DIN 38405-D 9-2 / 9-3: 1979-05 DIN 38405-D 29: 1994-11

(3)

Annex to the accreditation certificate D-PL-14237-01-00

Parameter Test method Ww Sw NGw

Total phosphorus DIN EN ISO 11885: 1998-04 (E 22) DIN EN 1189: 1996-12 (D 11) Orthophosphate

DIN EN ISO 10304-1: 1995-04 (D 19) DIN EN ISO 10304-2: 1996-11 (D 20) DIN EN 1189: 1996-12 (D 11) Fluoride (dissolved and total) DIN 38405-D 4: 1985-07

DIN EN ISO 10304-1: 1995-04 (D 19) Chloride DIN 38405-D 1: 1985-12 DIN EN ISO 10304-1: 1995-04 (D 19) DIN EN ISO 10304-2: 1996-11 (D 20) DIN EN ISO 10304-4: 1999-07 (D 25) DIN EN ISO 15682: 2002-01 (D 31) Sulfate DIN EN ISO 10304-1: 1995-04 (D 19) DIN EN ISO 10304-2: 1996-11 (D 20) DIN 38405-D 5: 1985-01

Sulfite DIN EN ISO 10304-3: 1997-11 (D 22),

Section 5

Sulfide (easily liberated) DIN 38405-D 27: 1992-07

Cyanide (easily liberated)

DIN 38405-D 13-2: 1981-02 DIN 38405-D 14-2: 1988-12 DIN EN ISO 14403: 2002-07 (D 6) DIN 38405-D 7: 2002-04 Cyanide (total) DIN 38405-D 13-1: 1981-02 DIN 38405-D 14-1: 1988-12 DIN EN ISO 14403: 2002-07 (D 6) DIN 38405-D 7: 2002-04 Chromium VI DIN 38405-D 24: 1987-05 DIN EN ISO 10304-3: 1997-11 (D 22), Section 5 (dissolved chromate)

Oxygen DIN EN 25814: 1992-11 (G 22)

Part 3: Elemental analysis

Parameter Test method Ww Sw NGw

Aluminium DIN EN ISO 11885: 1998-04 (E 22) DIN EN ISO 12020: 2000-05 (E 25) DIN 38406-E 29: 1999-05 DIN EN ISO 15586: 2004-02 (E 4) Arsenic DIN EN ISO 11969: 1996-11 (D 18) DIN EN ISO 11885: 1998-04 (E 22) DIN 38406-E 29: 1999-05 DIN EN ISO 15586: 2004-02 (E 4)

(4)

Annex to the accreditation certificate D-PL-14237-01-00

Parameter Test method Ww Sw NGw

Lead

DIN 38406-E 6: 1998-07

DIN EN ISO 11885: 1998-04 (E 22) DIN 38406-E 16: 1990-03

DIN 38406-E 29: 1999-05 DIN EN ISO 15586: 2004-02 (E4)

Cadmium

DIN EN ISO 5961: 1995-05 (E19) DIN EN ISO 11885: 1998-04 (E22) DIN 38406-E 16: 1990-03 DIN 38406-E 29: 1999-05 DIN EN ISO 15586: 2004-02 (E 4) Calcium DIN EN ISO 11885: 1998-04 (E 22) DIN 38406-E 3: 2002-03

DIN EN ISO 7980: 2000-07 (E 3a) DIN 38406-E 29: 1999-05 DIN EN ISO 14911: 1999-12 (E 34) Chromium DIN EN ISO 11885: 1998-04 (E 22) DIN EN 1233: 1996-08 (E 10) DIN 38406-E 29: 1999-05 DIN 38406-E 22: 1988-03 DIN EN ISO 15586: 2004-02 (E 4) Iron DIN EN ISO 11885: 1998-04 (E 22) DIN 38406-E 1: 1983-05 DIN 38406-E32: 2000-05 DIN EN ISO 15586: 2004-02 (E 4) Potassium DIN 38406-E 13: 1992-07 DIN EN ISO 11885: 1998-04 (E 22) DIN 38406-E 29: 1999-05 DIN EN ISO 14911: 1999-12 (E 34) Copper DIN EN ISO 11885: 1998-04 (E 22) DIN 38406-E 7: 1991-09 DIN 38406-E 16: 1990-03 DIN 38406-E 29: 1999-05 DIN EN ISO 15586: 2004-02 (E 4) Manganese DIN EN ISO 11885: 1998-04 (E 22) DIN 38406- E 29: 1999-05 DIN 38406-E33: 2000-06 DIN EN ISO 15586: 2004-02 (E 4) DIN EN ISO 14911: 1999-12 (E 34) Sodium DIN 38406-E 14: 1992-07 DIN EN ISO 11885: 1998-04 (E 22) DIN 38406-E 29: 1999-05 DIN EN ISO 14911: 1999-12 (E 34)

(5)

Annex to the accreditation certificate D-PL-14237-01-00

Parameter Test method Ww Sw NGw

Nickel DIN EN ISO 11885: 1998-04 (E 22) DIN 38406-E 11: 1991-09 DIN 38406-E 29: 1999-05 DIN 38406-E 16: 1990-03 DIN EN ISO 15586: 2004-02 (E 4) Mercury DIN EN 1483: 1997-08 (E 12) DIN EN 12338: 1998-10 (E 31) DIN EN 13506: 2002-04 (E 35) Zinc DIN EN ISO 11885: 1998-04 (E 22) DIN 38406-E 8-1: 1980-10 DIN 38406-E 16: 1990-03 DIN 38406-E 29: 1999-05 DIN EN ISO 15586: 2004-02 (E 4) Tin DIN EN ISO 11885: 1998-04 (E 22) corresponds to: DIN EN ISO 5961: 1995-05 (Section 3) (E 19)

corresponds to: DIN EN ISO 11969: 1996-11 (D 18) (chemical digestion according to Section 8.3.1)

DIN 38406-E 29: 1999-05 Boron

DIN EN ISO 11885: 1998-04 (E22) DIN 38405-D 17: 1981-03

DIN 38406-E 29: 1999-05

Magnesium

DIN EN ISO 11885: 1998-04 (E22) DIN 38406-E 3: 2002-03

DIN EN ISO 7980: 2000-07 (E 3a) DIN 38406-E 29: 1999-05

DIN EN ISO 14911: 1999-12 (E 34)

Part 4: Group and sum parameters (section 1)

Parameter Test method Ww Sw NGw

Biochemical oxygen demand BOD5 DIN EN 1899-1: 1998-05 (H 51)

Chemical oxygen demand COD

DIN 38409-H 41: 1980-12 DIN 38409-H 44: 1992-05 DIN ISO 15705: 2003-01 (H 45) Non-volatile lipophilic matter DEV H 56 (46the delivery 2000) Phenol index

(with and without distillation)

DIN 38409-H 16: 1984-06

DIN EN ISO 14402: 1999-12 (H 37)

Filterable matter DIN 38409-H 2: 1987-03

DIN EN 872: 1996-03 (H 33) Acid-base capacity DIN 38409-H 7: 2004-03

(6)

Annex to the accreditation certificate D-PL-14237-01-00

Part 5: Group and sum parameters (section 2)

Parameter Test method Ww Sw NGw

Total organic carbon (TOC) DIN EN 1484: 1997-08 (H 3) Dissolved organic carbon (DOC) DIN EN 1484: 1997-08 (H 3)

Total bound nitrogen (TNb)

DIN ENV 12260: 1996-06 (H 34) DIN EN 12260: 2003-12 (H 34) DIN 38409-H 27: 1992-07

DIN EN ISO 11905-1: 1998-08 (H 36) Carbohydrates (CH) DIN EN ISO 9377-2: 2001-07 (H 53) Adsorbable organic halogens (AOX) DIN EN 1485: 1996-11 (H 14)

DIN 38409-H 22: 2001-02

Part 6: Gas chromatographic methods

Parameter Test method Ww Sw NGw

Highly volatile halogenated hydrocarbons

(halogenated VOC) DIN EN ISO 10301: 1997-08 (F 4)* Benzene and derivatives (BTEX) DIN 38407-F 9: 1991-05*

Organochlorine pesticides (OCP) DIN EN ISO 6468: 1997-02 (F 1)* DIN 38407-F 2: 1993-02* Polychlorinated biphenyls (PCB)

DIN EN ISO 6468: 1997-02 (F 1)* DIN 38407-F 2: 1993-02* DIN 38407-F 3: 1998-07

Mono- and dichlorobenzenes DIN EN ISO 10301: 1997-08 (F 4)* Tri- to hexachlorbenzene DIN EN ISO 6468: 1997-02 (F 1)*

DIN 38407-F 2: 1993-02*

Chlorophenols DIN EN ISO 12673: 1999-05 (F 15) Organic phosphorus and organic nitrogen

compounds DIN EN ISO 10695: 2000-11 (F 6) *

* mass spectrometric detection is permissible

Part 7: HPLC methods

not requested

Part 8: Microbiological methods

not requested

Part 9: Biological methods and biotests

(7)

Annex to the accreditation certificate D-PL-14237-01-00

2 List of Test Procedures for the Specialised Module WASTE Status: 01.08.2005

Fields of testing 1: Sewage sludge Parts/

Parameters

Bases/

Test methods

AbfKlärV

1.1 Sampling Annex 1 AbfKlärV

Sewage sludge sampling DIN 38414-S 1 (11.86)

Bulk sample preparation and sample splitting Annex 1, No. 1.1 AbfKlärV Sample preparation, homogenisation,

centrifugation and freeze-drying Annex 1, No. 1.2 AbfKlärV

1.2 Heavy metals Section 3, Paragraph 5 AbfKlärV

Aqua regia digestion DIN 38414-S 7 (01.83)

DIN EN 13346 S 7a (04.01) Lead

(from aqua regia digestion)

DIN 38406-E 6 (05.81) DIN 38406-E 22 (03.88) DIN EN ISO 11885 E 22 (04.98) DIN 38406-E 6 (07.98)

Cadmium

(from aqua regia digestion)

DIN 38406-E 19 (07.80) DIN 38406-E 22 (03.88) DIN EN ISO 11885 E 22 (04.98) DIN EN ISO 5961 E 19 (05.95) Chromium

(from aqua regia digestion)

DIN 38406-E 10 (06.85) DIN 38406-E 22 (03.88) DIN EN ISO 11885 E 22 (04.98) DIN EN 1233 E 10 (08.96) Copper

(from aqua regia digestion)

DIN 38406-E 22 (03.88) DIN 38406-E 7 (09.91)

DIN EN ISO 11885 E 22 (04.98) Nickel

(from aqua regia digestion)

DIN 38406-E 22 (03.88) DIN 38406-E 11 (09.91) DIN EN ISO 11885 E 22 (04.98) Mercury (from aqua regia digestion) DIN 38406-E 12 (07.80)

DIN EN 1483 E 12 (08.97) Zinc

(from aqua regia digestion)

DIN 38406-E 8 (10.80) DIN 38406-E 22 (03.88) DIN EN ISO 11885 E 22 (04.98)

1.3 Adsorbable organically bound halogens Section 3, Paragraph 5 AbfKlärV

AOX (from dry residue) DIN 38 414-S 18 (11.89)

1.4 Physical parameters, nutrients Section 3, Paragraph 5 AbfKlärV

Dry residue DIN 38414-S 2 ( 11.85 )

(8)

Annex to the accreditation certificate D-PL-14237-01-00

Parts/

Parameters

Bases/

Test methods Organic substance as loss on ignition

(from dry residue)

DIN 38414-S 3 ( 11.85 ) DIN EN 12879 S 3a (02.01)

pH DIN 38414-S 5 ( 09.81 )

DIN EN 12176 S 5 (06.98)

Aqua regia digestion DIN 38414-S 7 (01.83)

DIN EN 13346 S 7a (04.01) Alkaline matter as CaO

Annex 1 AbfKlärV Calculated according to % CaO = (50-x-2y) • 1.402 Ammonium nitrogen (NH4-N ) DIN 38406-E 5 (10.83)

Total nitrogen (Ntotal)

DIN 19684-4 (02.77) Distillation procedure DIN ISO 11261 b (05.97) Phosphorus as P2O5

(from aqua regia digestion)

DIN 38414-S 12 (11.86) DIN 38406-E 22 (03.88) DIN EN ISO 11885 E 22 (04.98) Potassium as K2O

(from aqua regia digestion)

DEV E 13 (5.Lfg 68) DIN 38406-E 22 (03.88) DIN EN ISO 11885 E 22 (04.98) DIN 38406-E 13 (07.92) Magnesium

(from aqua regia digestion)

DIN 38406-E 3 (09.82) DIN 38406-E 22 (03.88) DIN EN ISO 11885 E 22 (04.98) DIN EN ISO 7980 E 3a (07.00)

Persistent toxic organic substances Section 3, Paragraph 6 AbfKlärV 1.5 Polychlorinated biphenyls (PCB) Annex 1, No. 1.3.3.1 AbfKlärV

DIN 38414-S 20 (01.96)

1.6 Polychlorated bibenzodoxins/-furans (PCDD/PCDF) Annex 1, No. 1.3.3.2 AbfKlärV

Fields of testing 2: Soil Parts/

Parameters

Bases/

Test methods

AbfKlärV and BioAbfV

2.1 Sampling and preparation Section 3, Paragraph 2 AbfKlärV and Section 9 BioabfV

Sampling and preparation of the average sample Annex 1, No. 2.1 AbfKlärV

Sample preparation Annex 1, No. 2.1 AbfKlärV

Filtration < 2 mm Annex 1, No. 2.1 AbfKlärV

Crushing < 0.1 mm

Annex 1, No. 2.1 AbfKlärV in conjunction with DIN 38414-S 7 (01.83)

(9)

Annex to the accreditation certificate D-PL-14237-01-00

Parts/

Parameters

Bases/

Test methods

2.2 Heavy metals, pH and soil type Section 3, Paragraph 2 AbfKlärV Section 9, Paragraph 2 BioAbfV

Aqua regia digestion DIN 38414-S 7 (01.83)

DIN ISO 11466 (06.97) Lead

(from aqua regia digestion)

DIN 38406-E 22 (03.88) DIN EN ISO 11885 E 22 (04.98) DIN 38406-E 6 (07.98)

DIN ISO 11047 (05.03) Cadmium

(from aqua regia digestion)

DIN 38406-E 22 (03.88) DIN EN ISO 11885 E 22 (04.98) DIN EN ISO 5961 E 19 (05.95) DIN ISO 11047 (05.03) Chromium

(from aqua regia digestion)

DIN 38406-E 22 (03.88) DIN EN ISO 11885 E 22 (04.98) DIN EN 1233 E 10 (08.96) DIN ISO 11047 (05.03) Copper

(from aqua regia digestion)

DIN 38406-E 22 (03.88) DIN EN ISO 11885 E 22 (04.98) DIN 38406-E 7 (09.91)

DIN ISO 11047 (05.03) Nickel

(from aqua regia digestion)

DIN 38406-E 22 (03.88) DIN EN ISO 11885 E 22 (04.98) DIN 38406-E 11 (09.91) DIN ISO 11047 (05.03) Mercury

(from aqua regia digestion)

DIN 38406-E 12 (07.80) DIN EN 1483 E 12 (08.97) Zinc

(from aqua regia digestion)

DIN 38406-E 22 (03.88) DIN EN ISO 11885 E 22 (04.98) DIN 38406-E 8 (10.80) DIN ISO 11047 (05.03) Soil type DIN 18123 (1983) DIN 18123 (11.96)

VDLUFA Book of methods I D 2.1 (1991)

pH value

DIN 19684-1 (02.77) DIN ISO 10390 (05.97) VDLUFA Book of methods I A 5.1.1 (1991)

(10)

Annex to the accreditation certificate D-PL-14237-01-00

Parts/

Parameters

Bases/

Test methods

2.3 Physical parameters, nutrients Section 3, Paragraph 4 AbfKlärV, Section 9, Paragraph 2 BioabfV

pH-Wert

DIN 19684-1 (02.77) DIN ISO 10390 (05.97) VDLUFA Book of methods I A 5.1.1 (1991)

Clay content /soil type

DIN 18123 (1983) DIN 18123 (11.96)

VDLUFA Book of methods I D 2.1 (1991)

* Phosphorus as P2O5CA/DL

VDLUFA Book of methods A 6.2.1.1. and A 6.2.1.2 (1991) * Potassium as K2O CA/DL

VDLUFA Book of methods A 6.2.1.1. and 6.2.1.2 (1991) * Magnesium Mg CaCl2

VDLUFA Book of methods 6.2.4.1 (1991)

* only withAbfKlärV, not obligatory with BioAbfV

Fields of testing 3: Biowaste Parts/

Parameters

Bases/

Test methods

3.1 Sampling Section 4, Paragraph 45 BioAbfV, Annex 3 BioAbfV

Sampling of solid biowaste Book of methods Compost (1994) Sampling of liquid, pasty and sludge type wastes

LAGA RL PN 2/78 (12.83) LAGA RL PN 2/78 K (12.83) LAGA PN 98 (12.01) Sample preparation and sample splitting , filtration

< 10 mm, crushing < 0.25 mm Annex 3, No. 1.2 BioAbfV

Dry matter DIN 38414-S 2 (11.85)

3.2 Heavy metals Section 4 , Paragraph 5 BioAbfV

Aqua regia digestion DIN 38414-S 7 (01.83)

DIN EN 13657 (01.03)

Lead

(from aqua regia digestion)

DIN 38406-E 6 (05.81) DIN 38406-E 22 (03.88) DIN ISO 11047 (06.95) DIN 38406-E 6 (07.98) DIN ISO 11047 (05.03) DIN EN ISO 11885 E 22 (04.98)

(11)

Annex to the accreditation certificate D-PL-14237-01-00 Parts/ Parameters Bases/ Test methods Cadmium

(from aqua regia digestion)

DIN EN ISO 5961 E 19 (05.95) DIN 38406-E 22 (03.88) DIN ISO 11047 (06.95) DIN ISO 11047 (05.03) DIN EN ISO 11885 E 22 (04.98) Chromium

(from aqua regia digestion)

DIN EN 1233 E 10 (08.96) DIN 38406-E 22 (03.88) DIN ISO 11047 (06.95) DIN ISO 11047 (05.03) DIN EN ISO 11885 E 22 (04.98) Copper

(from aqua regia digestion)

DIN 38406-E 7 (09.91) DIN 38406-E 22 (03.88) DIN ISO 11047 (06.95) DIN ISO 11047 (05.03) DIN EN ISO 11885 E 22 (04.98) Nickel

(from aqua regia digestion)

DIN 38406-E 11 (09.91) DIN 38406-E 22 (03.88) DIN ISO 11047 (06.95) DIN ISO 11047 (05.03)

DIN EN ISO 11885 E 22 (04.98) Mercury (from aqua regia digestion) DIN 38406-E 12 (07.80)

DIN EN 1483 E 12 (08.97)

Zinc

(from aqua regia digestion)

DIN 38406-E 8 (10.80) DIN 38406-E 22 (03.88) DIN ISO 11047 (06.95) DIN ISO 11047 (05.03)

DIN EN ISO 11885 E 22 (04.98)

3.3 Physical parameters, foreign matter Section 4 , Paragraph 5 BioAbfV

Dry residue DIN ISO 11465 (12.96)

pH value

VDLUFA Book of methods, Volume I

A 5.1.1 (1991)

DIN ISO 10390 (05.97) Salinity level

Annex 3, No. 1.3.4 BioAbfV VDLUFA Book of methods, Volume I (1991)

Organic substance as loss on ignition (from dry residue)

DIN 19684-3 (02.77) DIN 19684-3 (08.00)

Foreign matter (stones, glass, plastic, metal)

Annex 3, No. 1.3.3 BioAbfV Book of methods Compost Federal Quality Assurance Association for Compost

(12)

Annex to the accreditation certificate D-PL-14237-01-00

Parts/

Parameters

Bases/

Test methods

3.4 Hygienic control of epidemics Section 3, Paragraph 4 BioAbfV

Salmonella (product testing) Annex 2, No. 2.3.1.2 BioAbfV

Salmonella senftenberg W 775 (H2S-neg.)

(process testing)

Annex 2, No. 2.3.1.1 BioAbfV with 2ml plastic ampoules Annex 2, No. 2.3.1.1 BioAbfV With diffusion germ carriers according to RAPP

3.5 Phytohygiene Section 3, Paragraph 4 BioAbfV

Germinable seed and bud-bearing plant parts (product testing)

Annex 2, No. 2.3.2 and 2.3.2.5 BioAbfV

Including saline level

Book of methods Compost Federal Quality Assurance Association for Compost Plasmodiophora brassicae (clubroot) (process

testing)

Annex 2, No. 2.3.2.1 and 2.3.2.3 BioAbfV , testing according to BRUNS and KNOLL et.al. (1990, 1994)

Tomato seeds (process testing)

Annex 2, No. 2.3.2.1 and 2.3.2.4 BioAbfV, testing according to POLLMANN and STEINER (1994)

Fields of testing 4: Used oil, insulating liquids

not requested

Fields of testing 5: Waste for deposition Parts/

Parameters

Bases/

Test methods

Section 8, Paragraph 3 DepV 5.1 Sampling and sample preparation Annex 4, No. 2 and No. 3.1.1

DepV

Sampling of liquid, pasty and sludge type wastes LAGA PN 98 (12.01) Sample preparation: reduction, crushing and

pulverising of solid samples for a laboratory sample Annex 4, No. 3.1.1 DepV Sample preparation: reduction, grinding of pasty

and sludge-type samples for the laboratory sample Annex 4, No. 3.1.1 DepV

5.2 Sample preparation –general parameters Annex 4, No. 3 DepV

Digestion procedure (aqua regia)

E DIN EN 13657 (10.99) DIN EN 13657 (01.03) DIN EN 13346 S 7a (04.01) Eluate preparation

DIN EN 12457-4 (01.03) in

conjunction with Annex 4, No. 2.4 AbfAblV

(13)

Annex to the accreditation certificate D-PL-14237-01-00

Parts/

Parameters

Bases/

Test methods

pH value (soil quality) DIN ISO 10390 (05.97)

pH value of eluate DIN 38404-C 5 (01.84)

Conductivity of eluate DIN EN 27888 C 8 (11.93)

Dry residue (soil quality) DIN ISO 11465 (12.96) Dry residue (waste products) E DIN EN 14346 (02.02)

DIN EN 12880 S 2a (02.01) Water-soluble fraction of dry residue from the

original substance (determined by dry residue from the eluate filtration)

DIN 38409-H 1-2 (01.87) Loss on ignition of the dry residue from the original

substance

DIN 38414-S 3 (11.85) DIN EN 12879 ( 02.01)

Total cyanide E DIN ISO 11262 (06.94)

ISO 11262 (09.03)

Easily liberated cyanide (from the eluate)

DIN 38405-D 14-2 (12.88) For waste products containing sulfides:

DIN 38405-D 13-2 (02.81) DIN EN ISO 14403 D 6 (07.02) Fluoride (from the eluate) DIN 38405-D 4-1 (07.85)

DIN EN ISO 10304-1 D 19 (04.95) Ammonium nitrogen (NH4-N) (from the eluate)

DIN 38406-E 5-1 (10.83) DIN EN ISO 11732 E 23 (09.97) DIN EN ISO 11732 E 23 (05.05)

5.3 Arsenic and other heavy metals Annex 4, No. 3 DepV

Arsenic

(from aqua regia digestion)

DIN EN ISO 11969 D 18 (11.96) DIN ISO 11047 (06.95)

DIN ISO 11047 (05.03)

DIN EN ISO 11885 E 22 (04.98) Arsenic

(from the eluate)

DIN EN ISO 11969 D 18 (11.96) DIN EN ISO 11885 E 22 (04.98) Lead

(from aqua regia digestion)

DIN ISO 11047 (06.95) DIN ISO 11047 (05.03) DIN 38406-E 6 (07.98)

DIN EN ISO 11885 E 22 (04.98) Lead (from the eluate)

DIN 38406-E 2 (07.98)

DIN EN ISO 11885 E 22 (04.98) DIN 38406-E 6 (07.98)

Cadmium

(from aqua regia digestion)

DIN ISO 11047 (06.95) DIN ISO 11047 (05.03) Cadmium (from the eluate) DIN EN ISO 5961 E 19 (05.98)

(14)

Annex to the accreditation certificate D-PL-14237-01-00 Parts/ Parameters Bases/ Test methods Chromium

(from aqua regia digestion)

DIN ISO 11047 (06.95) DIN ISO 11047 (05.03)

DIN EN ISO 11885 E 22 (04.98) Chromium VI (from the eluate) DIN 38405-D 24 (05.87) Copper (from aqua regia digestion)

DIN ISO 11047 (06.95) DIN ISO 11047 (05.03)

DIN EN ISO 11885 E 22 (04.98) Copper (from the eluate) DIN 38406-E 7 (09.91)

DIN EN ISO 11885 E 22 (04.98) Nickel

(from aqua regia digestion)

DIN ISO 11047 (06.95) DIN ISO 11047 (05.03)

DIN EN ISO 11885 E 22 (04.98) Nickel (from the eluate)

DIN 38406-E 11 (09.91) DIN 38406-E 22 (03.88) DIN EN ISO 11885 E 22 (04.98) Mercury

(from aqua regia digestion)

DIN EN 1483 E 12 (08.97) DIN EN 12338 E 31 (10.98) Mercury (from the eluate)

DIN EN 1483 E 12 (08.97) DIN 38406-E 12 (07.80) DIN EN 12338 E 31 (10.98) Zinc

(from aqua regia digestion)

DIN ISO 11047 (06.95) DIN ISO 11047 (05.03)

DIN EN ISO 11885 E 22 (04.98)

Zinc (from the eluate) DIN 38406-E 8-1 (10.80)

DIN EN ISO 11885 E 22 (04.98)

5.4 Group and sum parameters Annex 4, No. 3 DepV

Extractable organically bound halogens (EOX) DIN 38414-S 17 (11.89) Adsorbable organically bound halogens (AOX)

(from the eluate) DIN EN 1485-H 14 (11.96)

Total carbon (TOC) of the dry residue from the original substance

Annex 4, No. 2.2.2 AbfAblV DIN 38409-H 3 (06.83) DIN EN 1484 H 3 (08.97) DIN EN 13137 (12.01) Total carbon (TOC) (from the eluate) DIN EN 1484 H 3 (08.97) Extractable lipophilic matter Annex 4, No. 2.3 AbfAblV Phenols (from the eluate) DIN 38409-H 16-3 (06.84)

DIN EN ISO 14402 H 37 (12.99)

Hydrocarbons

E DIN EN 14039 (12.00) in conjunction with LAGA KW/04 (11.04)

(15)

Annex to the accreditation certificate D-PL-14237-01-00

Parts/

Parameters

Bases/

Test methods

5.5 Individual organic substances Annex 4, No. 3 DepV

Polycyclic aromatic hydrocarbons (PAH)

Manual Contaminated Sites, Volume 7 HLUG (1998) Leaflet 1 LUA NRW (1994) DIN 38414-S 21 (02.96) DIN 38414-S 23 (02.02) Highly volatile halogenated hydrocarbons

(halogenated VOC) DIN EN ISO 10301 F 4 (08.97)

Benzene and derivatives, volatile monoaromatic

hydrocarbons and derivatives (BTEX) DIN 38407-F 9 (05.91) Polychlorinated biphenyls (PCB) DIN 38414-S 20 (01.96)

5.6 Strength Annex 4, No. 3 DepV

Vane shear strength DIN 4096 (05.80)

Axial deformation DIN 18136 (08.96)

Uniaxial compressive strength DIN 18136 (08.96)

5.7 Biodegradability Section 6, Paragraph 4 DepV

Breathability over 4 days (AT 4) Annex 4, No. 2.5 AbfAblV

Rate of gas formation in the fermentation test over 21 days (GF 21)

Annex 4, No. 2.6 AbfAblV in conjunction with DIN 38414-S 8 (06.85)

Fields of testing 6: Wood waste not requested 3 Investigation of Water 3.1 Physico-chemical investigations DIN 38404-C 5 2009-09 Determination of pH value 3.2 Chemical investigations 3.2.1 Anions DIN EN ISO 10304-1 (D 20) 2009-07

Water quality - Determination of dissolved anions by liquid chromatography of ions - Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate

(16)

Annex to the accreditation certificate D-PL-14237-01-00

3.2.2 Cations

DIN EN ISO 11885 (E 22) 2009-09

Water quality - Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES)

4 Investigation of Waste Products DIN EN ISO 11885 (E 22)

2009-09

Water quality - Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES)

5 Analysis of Salts and Saline solutions

5.1 Analysis of saline solutions (up to > 300 g/l salt) for the following parameters K-UTEC 2

2008-03

Bestimmung von AOX nach DIN 38409-H 22

(Determination of AOX in accordance with DIN 38409-H 22) K-UTEC 5

2008-03

Bestimmung von Nitrat-Stickstoff mit Phenol unter Berücksich-tigung hoher Chloridgehalte (photometrisch)

(Determination of nitrate nitrogen with phenol taking into account high chloride concentrations) (photometric) K-UTEC 15

2011-06

Bestimmung des CSB in stark salzhaltigen Lösungen und Wässern analog DIN 38409-H 41-2

(Determination of the COD in salt-rich solutions and waters analogously to DIN 38409-H 41-2)

K-UTEC 57 2008-03

Bestimmung von TNb analog DIN EN ISO 11905 (H 36) nach

Mikrowelleninduzierter Druckaufschluss; Detektion als Nitrat entsprechend K-UTEC 5)

(Determination of the total nitrogen analogously to DIN EN ISO 11905 (H 36) by microwave-induced digestion;

detection as nitrate corresponding to K-UTEC 5)

K-UTEC 82 2008-03

Bestimmung der abfiltrierbaren Stoffe analog DIN 38409-H 2 (Determination of filterable substances analogously to DIN 38409-H 2)

(17)

Annex to the accreditation certificate D-PL-14237-01-00

K-UTEC 104 2008-03

Bestimmung von Sulfat analog DIN 38405-D 5 nach Anpassung des Anwendungsvolumens an die Sulfat-Konzentration

(Determination of sulfate analogously to DIN 38405-D 5 following adaptation of the application volume to the sulfate

concentration)

K-UTEC 108 2008-03

Bestimmung des pH-Werts analog zu DIN 38404-C 5

(Determination of the pH value analogously to DIN 38404-C 5) K-UTEC 109

2008-03

Bestimmung der elektrischen Leitfähigkeit analog zu DIN EN 27888 (C 8)

(Determination of the electrical conductivity analogously to DIN EN 27888 (C 8))

K-UTEC 110

2008-03

Bestimmung von Natrium und Kalium analog zu DIN ISO 9964-3 nach Verdünnung der Salzlösungen bis zu Gehalten

< 200 mg/l Natrium und Kalium)

(Determination of sodium and potassium analogously to DIN ISO 9964-3 following dilution of the saline solutions to concentrations

of < 200 mg/l sodium and potassium)

K-UTEC 111 2008-03

Bestimmung von 33 Metallen analog DIN EN ISO 11885 nach

Verdünnung der Salzlösungen 1:10 - 1:100; Messung nach dem Standardadditionsverfahren

(Determination of 33 metals analogously to DIN EN ISO 11885 following dilution of the saline solutions by 1:10 - 1:10;

Measurement by the standard addition method)

K-UTEC 112 2008-03

Bestimmung von Magnesium und Calcium analog DIN 38406-E 3 Nach Verdünnung der Salzlösungen bis zu Gehalten

< 100 mg/l Magnesium und Calcium

(Determination of magnesium and calcium analogously to DIN 38406-E 3 following dilution of the saline solutions to

concentrations of < 100 mg/l magnesium and calcium)

K-UTEC 113

2008-03

Berechnung der Gesamthärte aus dem Calcium- und Magnesium-Gehalt

(Determination of the total hardness of the calcium and magnesium contents)

K-UTEC 114 2008-03

Bestimmung von Chlorid analog DIN 38405-D 1 nach Verdünnung der Salzlösungen bis zu Gehalten < 150 mg/l Cl

(Determination of chloride analogously to DIN 38405-D 1 following dilution of the saline solutions to concentrations of

(18)

Annex to the accreditation certificate D-PL-14237-01-00

K-UTEC 115 2008-03

Bestimmung von Nitrit-Stickstoff analog DIN EN 26777 (D 10) nach Verdünnung der Salzlösungen bis zu Gehalten

< 0,25 mg/l Nitrit)

(Determination of nitrite nitrogen analogously to DIN EN 2677 (D10) following dilution of the saline solutions to concentrations

of < 25 mg/l nitrite)

K-UTEC 116 2011-04

Bestimmung von Ammonium-Stickstoff analog DIN 38406- E 5-1 nach Verdünnung der Salzlösungen bis zu Gehalten < 1 mg/l Ammonium; Einsatz des Destillationsverfahrens zur Abtrennung von Störungen

(Determination of ammonium nitrogen analogously to DIN 38406-E 5-1 following dilution of the saline solutions to concentrations of < 1 mg/l ammonium; Use of the distillation

method for the separation of interfering substances)

K-UTEC 117 2008-03

Bestimmung von P-ges. und ortho-PO4-P analog

DIN EN ISO 6878 (D 11) nach Verdünnung der Salzlösungen bis zu Gehalten < 0,8 mg/l Phosphor

Determination of total phosphorus concentration and ortho-PO4-P analogously to DIN EN ISO 6878 (D11) following

dilution of the saline solutions to concentrations of < 0.8 mg/l

phosphorus)

K-UTEC 118 2008-03

Bestimmung von Arsen analog EN ISO 11969 (D 18) nach

Verdünnung der Salzlösung bis zu Gehalten < 10 µg/l Arsen; < 100 mg/l Nitrat; < 250 mg/l Sulfat

(Determination of arsenic analogously to EN ISO 11969 (D 18) following dilution of the saline solution to concentrations of < 100 mg/l nitrate and < 250 mg/l sulfate)

K-UTEC 120 2008-03

Bestimmung von Chrom(VI) analog DIN 38405-D 24 nach

Verdünnung der Salzlösung bis zu 3 mg/l Chrom(VI)

(Determination of chromium(VI) analogously to DIN 38405-D 24 following dilution of the saline solution to concentrations of up to 3 mg/l chromium(VI)

K-UTEC 121 2008-03

Bestimmung von Quecksilber analog DIN EN 1483 (E 12) nach Verdünnung der Salzlösung bis zu 10 µg/l Quecksilber, 100 mg/l Iodid

(Determination of mercury analogously to DIN EN 1483 (E 12) following dilution of the saline solution to concentrations of up to 10 mg/l mercury and up to 100 mg/l iodide)

(19)

Annex to the accreditation certificate D-PL-14237-01-00

K-UTEC 122 2008-03

Bestimmung von TOC analog DIN EN 1484 (H 3)

(Determination of TOC analogously to DIN EN 1484 (H 3)) K-UTEC 123

2008-03

Bestimmung von Cyanid, gesamt, analog DIN 38405-D 13-1-3 nach Abtrennung des Cyanids von der Matrix durch Erhitzen und Absorption

(Determination of total cyanide analogously to

DIN 38405-D 13-1-13 following separation of the cyanide from

the matrix by heating and absorption)

K-UTEC 124 2008-03

Bestimmung des Phenolindex analog DIN 38409-H 16 nach

Verdünnung der Salzlösung bis zu < 10 mg/l Phenol

(Determination of the phenol index analogously to DIN 38409-H 16 following dilution of the saline solution to a concentration of < 10 mg/l phenol)

K-UTEC 125 2008-03

Bestimmung von Sulfid, gesamt, potentiometrisch

(Determination of total sulfide by the potentiometric method) K-UTEC 126

2008-03

Bestimmung von CaSO4, CaCl2, MgSO4, MgCl2, KCl, NaCl,

Na2SO4 durch Berechnung aus den Einzelionen

(Determination of CaSO4, CaCl2, MgSO4, MgCl2, KCl, NaCl and

Na2SO4 by calculation from the individual ions)

K-UTEC 167 2012-03

Bestimmung des Volumenanteils der absetzbaren Stoffe nach DIN 38409-H 9

(Determination of the volume fraction of settleable solids according to DIN 38409-H 9)

5.2 Analysis of salts (NaCl, MgCl2, KCl etc.) for the following parameters

ISO 8165-2 1999-07

Water quality - Determination of selected phenols - Part 2: Method by derivatization and gas chromatography

(Variation: Application for salts) DIN ISO 9964-3 (E 27)

1996-08

Water quality - Determination of sodium and potassium - Part 3: Determination of sodium and potassium by flame emission spectrometry

(Variation: Application for salts) DIN ISO 10693

1997-05

Soil quality - Determination of carbonate content - Volumetric method

(20)

Annex to the accreditation certificate D-PL-14237-01-00

DIN ISO 10694 1996-08

Soil quality - Determination of organic and total carbon after dry combustion (elementary analysis)

(Variation: Application for salts) DIN ISO 11261

1997-05

Soil quality - Determination of total nitrogen - Modified Kjeldahl method

(Variation: Application for salts) DIN EN ISO 10304-1 (D 20)

2009-07

Water quality - Determination of dissolved anions by liquid chromatography of ions - Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate (Variation: Application for salts – here determination of:

Cl and SO4)

DIN EN ISO 11885 (E 22) 2009-09

Water quality - Determination of selected elements by

inductively coupled plasma optical emission spectrometry (ICP-OES)

(Variation: Application for salts - here determination of:

Cu, Cr, Ni, Pb, Zn, Cd, Na, K, Mg, Ca, Al2O3, Fe2O3, W and Co

and: KAlF4 and NaF in conjunction with DIN 38405-D 4-1)

DIN EN ISO 11969 (D 18) 1996-11

Water quality - Determination of arsenic - Atomic absorption spectrometric method (hydride technique)

(Variation: Application for salts) DIN EN 1483 (E 12)

2007-07

Water quality - Determination of mercury (Variation: Application for salts)

DIN EN 1484 (H 3) 1997-08

Water analysis - Guidelines for the determination of total organic carbon (TOC) and dissolved organic carbon (DOC) (Variation: Application for salts)

DIN EN 12879 (S 3a) 2001-02

Characterization of sludges - Determination of the loss on ignition of dry mass

(Variation: Application for salts) DIN EN 12880 (S 2a)

2001-02

Characterization of sludges - Determination of dry residue and water content

(Variation: Application for salts) DIN EN 13346 (S 7a)

2001-04

Characterization of sludges - Determination of trace elements and phosphorus - Aqua regia extraction methods

(21)

Annex to the accreditation certificate D-PL-14237-01-00

DIN EN 13657 2003-01

Characterization of waste - Digestion for subsequent determination of aqua regia soluble portion of elements in waste

(Variation: Application for salts) DIN EN 26777 (D 10)

1993-04

Water quality; determination of nitrite; molecular absorption spectrometric method

(Variation: Application for salts) DIN EN 27888 (C 8)

1993-11

Water quality; determination of electrical conductivity (Variation: Application for salts)

DIN 38404-C 5 2009-09

Determination of pH value (Variation: Application for salts) DIN 38405-D 1-2

1985-12

Determination of chloride ions (Variation: Application for salts) DIN 38405-D 5-2

1985-01

Determination of sulfate ions (Variation: Application for salts) DIN 38405-D 9-2

1979-05

Determination of nitrate ions

(Variation: Application for salts - take salt matrix into

consideration with high salt level)

DIN 38405-D 13-1-3 1981-02

Determination of total cyanide by separation of hydrogen cyanide followed by photometric determination of cyanide ions with barbituric acid-pyridine

(Variation: Application for salts) DIN 38406-E 3

2002-03

Determination of calcium and magnesium, complexometric method

(Variation: Application for salts) DIN 38406-E 5

1983-10

Determination of ammonium nitrogen (following distillation) (Variation: Application for salts)

DIN 38409-H 16 1984-06

Determination of the phenol index (Variation: Application for salts) DIN 38414-S 17

1989-11

Determination of strippable and extractable organically bound halogens

(22)

Annex to the accreditation certificate D-PL-14237-01-00

Potash mine dump guidelines

Annex 8 2002-05

Total nitrogen (calculation)

Abbreviations used:

AbfKlärV Klärschlamm-Verordnung (Sewage Sludge Ordinance) BioAbfV Bioabfallverordnung (Biowaste Ordinance)

DepV Deponieverordnung (Waste Disposal Ordinance) DEV Deutsche Einheitsverfahren der Wasseruntersuchung

(German Standard Methods for the Examination of Water, Wastewater and Sludge)

DIN Deutsches Institut für Normung e. V. (German Standards Institute)

E DIN DIN standard draft

EN European Standard

HLUG Hessisches Landesamt für Umwelt and Geologie

(Hessian Regional Environmental and Geological Authority) ISO International Organization for Standardization

K-UTEC Internal standard of K-UTEC Salt Technologies LAGA Länderarbeitsgemeinschaft Abfall

(Regional Waste Management Association) LUA NRW Landesamt für Umwelt- und Arbeitsschutz

Nordrhein-Westfalen (North Rhine-Westphalian Regional Office of Environmental Protection and Occupational Safety

VDLUFA Verband deutscher landwirtschaftlicher Untersuchungs- und

Forschungsanstalten (Association of German Agricultural Testing and Research Institutes)

Figure

Updating...

References

Updating...

Related subjects :